A method of removing water from a mixture of iodine (I.sub.2) and water includes providing a mixture comprising iodine and water and: contacting the mixture with an adsorbent to selectively adsorb water from the mixture, contacting the mixture with a concentrated acid to absorb water from the mixture, separating the water from mixture by distillation, contacting the mixture with a gas that is inert to iodine (I.sub.2), contacting the mixture with hydrogen iodide (HI), or combinations thereof.

A method of removing water from a mixture of iodine (I.sub.2) and water includes providing a mixture comprising iodine and water and: contacting the mixture with an adsorbent to selectively adsorb water from the mixture, contacting the mixture with a concentrated acid to absorb water from the mixture, separating the water from mixture by distillation, contacting the mixture with a gas that is inert to iodine (I.sub.2), contacting the mixture with hydrogen iodide (HI), or combinations thereof.

The present invention provides a process for separating iodine from a NaCl brine, comprising the following steps: (a) providing said NaCl brine containing iodide, (b) adjusting the pH of said NaCl brine to be no greater than 1.5, (c) adding oxidizing agent, such as chlorine containing oxidizing agent, to said NaCl brine resulting from step (b) to obtain an oxidation-reduction potential in said NaCl brine of from 560 mV to 925 mV, the combination of said pH of no greater than 1.5 and oxidation-reduction potential of 560 mV to 925 mV resulting in the formation of an iodine-chlorine anionic complex, and (d) contacting nonionic adsorption resin and said NaCl brine from step (c) one with the other to adsorb said iodine from this brine, to obtain as a result thereof NaCl brine wherein the iodine content therein is preferably no greater than 100 ppbw, more preferably no greater than 10 ppbw.

The present invention provides a process for separating iodine from a NaCl brine, comprising the following steps: (a) providing said NaCl brine containing iodide, (b) adjusting the pH of said NaCl brine to be no greater than 1.5, (c) adding oxidizing agent, such as chlorine containing oxidizing agent, to said NaCl brine resulting from step (b) to obtain an oxidation-reduction potential in said NaCl brine of from 560 mV to 925 mV, the combination of said pH of no greater than 1.5 and oxidation-reduction potential of 560 mV to 925 mV resulting in the formation of an iodine-chlorine anionic complex, and (d) contacting nonionic adsorption resin and said NaCl brine from step (c) one with the other to adsorb said iodine from this brine, to obtain as a result thereof NaCl brine wherein the iodine content therein is preferably no greater than 100 ppbw, more preferably no greater than 10 ppbw.

The present invention relates to a reactor system for extracting iodine from an aqueous brine, including: a water heater (2); a tank for storing an oxidizing agent (6); means for carrying out iodine oxidation (8); a desorber (5); an absorption column (15); a crystallizer (19); an iodine melting node (21); and a sublimator (22).

The present invention relates to a reactor system for extracting iodine from an aqueous brine, including: a water heater (2); a tank for storing an oxidizing agent (6); means for carrying out iodine oxidation (8); a desorber (5); an absorption column (15); a crystallizer (19); an iodine melting node (21); and a sublimator (22).

The present invention relates to a reactor system for extracting iodine from an aqueous brine, including: a water heater (2); a tank for storing an oxidizing agent (6); means for carrying out iodine oxidation (8); a desorber (5); an absorption column (15); a crystallizer (19); an iodine melting node (21); and a sublimator (22).

The present invention relates to a reactor system for extracting iodine from an aqueous brine, including: a water heater (2); a tank for storing an oxidizing agent (6); means for carrying out iodine oxidation (8); a desorber (5); an absorption column (15); a crystallizer (19); an iodine melting node (21); and a sublimator (22).

The present invention relates to a vertical column apparatus (1) for mass exchange processes in the chemical, oil or gas industry and in particular, for the production of iodine from formation water of oil and gas fields, comprising: a gas outlet (2) at the top and a liquid outlet (3) at the bottom of the column (1); a packed section (4) between the top and the bottom of the column (1), wherein the column (1) has a liquid inlet (5) above the packed section (4) and a gas inlet (6) below the packed section (4), wherein an upper portion (7) of the column (1) has a larger diameter (d.sub.u) compared to a diameter (d.sub.p) of the packed section (4).

The present invention relates to a vertical column apparatus (1) for mass exchange processes in the chemical, oil or gas industry and in particular, for the production of iodine from formation water of oil and gas fields, comprising: a gas outlet (2) at the top and a liquid outlet (3) at the bottom of the column (1); a packed section (4) between the top and the bottom of the column (1), wherein the column (1) has a liquid inlet (5) above the packed section (4) and a gas inlet (6) below the packed section (4), wherein an upper portion (7) of the column (1) has a larger diameter (d.sub.u) compared to a diameter (d.sub.p) of the packed section (4).