A method for treating water with chlorine dioxide wherein the reactor is contained inside of the water supply line being treated and an eductor is used to draw in the chemical precursors. The method offers facilitated chlorine dioxide (ClO .sub.2) generation and safer operation over wider ClO.sub.2 mass flow capacity, thus offering a more adaptable system for CLO.sub.2 treatments. Noise reduction and ease-of-use versus traditional eductor-based ClO.sub.2 generators are additional benefits from using this method.

A system and method is provided for producing and delivering a product. The system includes a chamber having an inlet end, an outlet end and quenching points positioned therebetween. The inlet end is configured to receive a plurality of precursors and the quenching points are configured to receive water to obtain quenching of the reaction in the chamber thereby providing varying concentration of the resultant product.

A method of entrapping chlorine dioxide gas, including the steps of using an aqueous solution containing an alkaline substance and an iodide and bringing air containing the chlorine dioxide gas into contact with the aqueous solution.

Disclosed herein are methods of producing a gas at a controlled rate, the methods comprising directing air through a layered bed to produce a gas. The layered bed comprises alternating layers of a layer of dry particles comprising a precursor and a layer of dry particles comprising a proton-generating species. The gas is produced at a rate that is controlled by controlling the presence or absence of air flowing though the layered bed, the amount of time the air flows through the layered bed, the total number of layers in the layered bed, the average thickness of each of the layers of dry particles comprising the precursor in the layered bed, the average thickness of each of the layers of dry particles comprising the proton-generating species in the layered bed, the temperature the method is performed at, or a combination thereof.

New methods are disclosed for decontaminating surfaces and enclosures that avoid problems such as salt deposits, corrosion and condensation that accompany the use of known methods. The methods involve the use of chlorine dioxide solutions prepared by passing dilute chlorine gas over solid granular sodium chlorite to produce chlorine dioxide gas which is then collected to form a solution with very low levels of impurities. The chlorine dioxide gas can be introduced into an enclosure and used to disinfect a portion of the contents of the enclosure.

Stable, aqueous solutions of chlorine dioxide and methods for producing stable, aqueous solutions of chlorine dioxide are disclosed. Generally, the chlorine dioxide solutions of the invention are aqueous solutions containing about 1000 ppm by weight or less of total impurities and/or 10 ppm or less of manganese and iron combined. The aqueous chlorine dioxide solutions are storage stable for at least 90 days at 25 C. and maintain at least 75% of the initial chlorine dioxide concentration. Methods of preparing, using and transporting the chlorine dioxide solutions are also disclosed.

The invention relates to a method for producing an ultrapure, aqueous, long-term- and storage-stable, and thus transportable chlorine dioxide solution, comprising the steps of providing chlorite, providing peroxodisulfate, and combining chlorite and peroxodisulfate in an aqueous system and in a molar ratio of peroxodisulfate to chlorite [S.sub.2O.sub.8.sup.2]/[ClO.sub.2.sup.] of greater than 1, forming the aqueous chlorine dioxide solution, wherein no additional buffer is added to produce the aqueous chlorine dioxide solution. The invention further relates to a corresponding chlorine dioxide solution, to the use of said chlorine dioxide solution, and to a device for producing the chlorine dioxide solution.

Material and methods are disclosed involving the generation and containment of solutions incorporating reactive precursors and reactive treatment agents. Formulations of these materials can be applied widely as disinfectants, odor control agents, decontamination and fumigation agents, liquid, gas, and air treatment materials, respiratory agents, food and beverage processing agents, neutralization agents, and in many industrial, residential, medical and military surface treatment operations.

The present invention is for extremely pure solutions of chlorine dioxide, methods for making such solutions and to compositions and methods for storing, shipping and using such solutions. Generally, the chlorine dioxide solutions of the invention are aqueous solutions containing about 2500 ppm or less of total impurities. The chlorine dioxide solution can be prepared by passing dilute highly pure chlorine gas through a bed of substantially solid sodium chloride and contacting the resulting chlorine dioxide gas with a liquid.

Introducing chlorine dioxide solution into an agricultural soil in an amount effective to suspend weed and pathogen growth in the soil. The chlorine dioxide is allowed to decompose in the soil. Then, a crop is planted in the treated soil. The decomposed chlorine dioxide provides nutrients for the crops as they grow.