The invention provides methods of preparing carbon/sulfur composites. In certain embodiments, the composites comprise multidimensional carbon tubular and/or spherical networks loaded with elemental sulfur, as well as compositions comprising such composites.

The invention provides methods of preparing carbon/sulfur composites. In certain embodiments, the composites comprise multidimensional carbon tubular and/or spherical networks loaded with elemental sulfur, as well as compositions comprising such composites.

Provided is a method for preparing a needle-like sulfide-based solid electrolyte. The method may include: preparing a solid electrolyte admixture comprising an organic solvent, Li.sub.2S, P.sub.2S.sub.5, and LiCl; synthesizing a solid electrolyte by stirring the solid electrolyte admixture at a temperature of about 30 to 60 C. for about 22 to 26 hours; first stirring the solid electrolyte at a speed of about 80 to 120 rpm for about 5 to 10 minutes; after the first stirring, second stirring the first stirred solid electrolyte at a speed of about 250 to 300 rpm; vacuum-drying the second stirred solid electrolyte for about 12 to 24 hours; and heat-treating the vacuum-dried solid electrolyte at a temperature of about 350 to 550 C. for about 1 to 5 hours.

Provided is a method for preparing a needle-like sulfide-based solid electrolyte. The method may include: preparing a solid electrolyte admixture comprising an organic solvent, Li.sub.2S, P.sub.2S.sub.5, and LiCl; synthesizing a solid electrolyte by stirring the solid electrolyte admixture at a temperature of about 30 to 60 C. for about 22 to 26 hours; first stirring the solid electrolyte at a speed of about 80 to 120 rpm for about 5 to 10 minutes; after the first stirring, second stirring the first stirred solid electrolyte at a speed of about 250 to 300 rpm; vacuum-drying the second stirred solid electrolyte for about 12 to 24 hours; and heat-treating the vacuum-dried solid electrolyte at a temperature of about 350 to 550 C. for about 1 to 5 hours.

The invention provides methods of preparing carbon/sulfur composites. In certain embodiments, the composites comprise multidimensional carbon tubular and/or spherical networks loaded with elemental sulfur, as well as compositions comprising such composites.

The invention provides methods of preparing carbon/sulfur composites. In certain embodiments, the composites comprise multidimensional carbon tubular and/or spherical networks loaded with elemental sulfur, as well as compositions comprising such composites.

A method for producing complexed particles including obtaining a good solvent solution, by dissolving Li.sub.2S, and LiX (X is at least one selected from a group consisting of F, Cl, Br, and I) in a good solvent, and precipitating particles by contacting the good solvent solution with a poor solvent having a temperature at least 165 C. higher than the boiling point of the good solvent, to evaporate off the good solvent. The method further satisfies at least one of the following: (i) the good solvent solution being obtained by further dissolving H.sub.2S in the good solvent, and (ii) H.sub.2S being dissolved in the poor solvent.

A method for producing complexed particles including obtaining a good solvent solution, by dissolving Li.sub.2S, and LiX (X is at least one selected from a group consisting of F, Cl, Br, and I) in a good solvent, and precipitating particles by contacting the good solvent solution with a poor solvent having a temperature at least 165 C. higher than the boiling point of the good solvent, to evaporate off the good solvent. The method further satisfies at least one of the following: (i) the good solvent solution being obtained by further dissolving H.sub.2S in the good solvent, and (ii) H.sub.2S being dissolved in the poor solvent.

Provided is a method for preparing a needle-like sulfide-based solid electrolyte. The method may include: preparing a solid electrolyte admixture comprising an organic solvent, Li.sub.2S, P.sub.2S.sub.5, and LiCl; synthesizing a solid electrolyte by stirring the solid electrolyte admixture at a temperature of about 30 to 60 C. for about 22 to 26 hours; first stirring the solid electrolyte at a speed of about 80 to 120 rpm for about 5 to 10 minutes; after the first stirring, second stirring the first stirred solid electrolyte at a speed of about 250 to 300 rpm; vacuum-drying the second stirred solid electrolyte for about 12 to 24 hours; and heat-treating the vacuum-dried solid electrolyte at a temperature of about 350 to 550 C. for about 1 to 5 hours.

The present disclosure relates to a method of producing a solid electrolyte with a uniform particle size distribution and a spherical shape. The method includes preparing a raw material comprising one or more of a lithium (Li) element, a phosphorus (P) element, or a sulfur(S) element, preparing a starting material comprising the raw material and a solvent, obtaining an intermediate in powder form by spray drying the starting material, and obtaining a sulfide-based solid electrolyte by heat treating the intermediate.