C01B21/083

Process of Fluorinating Inorganic or Organic Compounds by Direct Fluorination

The invention relates to a use of a fluorination gas, and the elemental fluorine (F.sub.2) is present in a high concentration, for example, in a concentration of elemental fluorine (F.sub.2), especially of equal to much higher than 15 or even 20% by volume, and to a process for the manufacture of a fluorinated compound by direct fluorination employing a fluorination gas, wherein the elemental fluorine (F.sub.2) is present in a high concentration. The process of the invention is directed to the manufacture of a fluorinated compound, for the exception of fluorinated benzene, by direct fluorination. Especially the invention is of interest in the preparation of fluorinated organic compounds, final products and as well intermediates, for usage in agro-, pharma-, electronics-, catalyst, solvent and other functional chemical applications. The fluorination process of the invention may be performed batch-wise or in a continuous manner.

METHOD FOR MANUFACTURING ELECTROLYTE SOLUTION MATERIAL

An electrolytic solution comprising N-(fluorosulfonyl)-N-(fluoroalkylsulfonyl)imide or di(fluorosulfonyl)imide, from which a residual solvent that affects the properties of the electrolyte solution material is reduced, is provided. A method for producing an electrolyte solution material containing fluorosulfonyl imide salt represented by the following general formula (1) and an electrolyte solution preparation solvent comprises decompressing and/or heating a solution containing the fluorosulfonyl imide salt and the electrolyte solution preparation solvent to volatilize a production solvent for the fluorosulfonyl imide salt.

##STR00001##

In general formula (1), R.sub.1 represents a fluorine atom or a fluorinated alkyl group having 1 to 6 carbon atoms, R.sub.2 represents an alkali metal ion.

METHOD FOR MANUFACTURING ELECTROLYTE SOLUTION MATERIAL

An electrolytic solution comprising N-(fluorosulfonyl)-N-(fluoroalkylsulfonyl)imide or di(fluorosulfonyl)imide, from which a residual solvent that affects the properties of the electrolyte solution material is reduced, is provided. A method for producing an electrolyte solution material containing fluorosulfonyl imide salt represented by the following general formula (1) and an electrolyte solution preparation solvent comprises decompressing and/or heating a solution containing the fluorosulfonyl imide salt and the electrolyte solution preparation solvent to volatilize a production solvent for the fluorosulfonyl imide salt.

##STR00001##

In general formula (1), R.sub.1 represents a fluorine atom or a fluorinated alkyl group having 1 to 6 carbon atoms, R.sub.2 represents an alkali metal ion.

Compounds with mixed anions as solid Li-ion conductors

A solid-state lithium ion electrolyte is provided which contains a composite material having at least 94 mole % lithium ions as cation component and multiple anions in an anionic framework capable of conducting lithium ions. An activation energy for lithium ion migration in the solid state lithium ion electrolyte is 0.5 eV or less. Composites of specific formulae are provided. A lithium battery containing the composite lithium ion electrolyte is also provided.

Compounds with mixed anions as solid Li-ion conductors

A solid-state lithium ion electrolyte is provided which contains a composite material having at least 94 mole % lithium ions as cation component and multiple anions in an anionic framework capable of conducting lithium ions. An activation energy for lithium ion migration in the solid state lithium ion electrolyte is 0.5 eV or less. Composites of specific formulae are provided. A lithium battery containing the composite lithium ion electrolyte is also provided.

COMPOUNDS WITH MIXED ANIONS AS SOLID Li-ION CONDUCTORS

A solid-state lithium ion electrolyte is provided which contains a composite material having at least 94 mole % lithium ions as cation component and multiple anions in an anionic framework capable of conducting lithium ions. An activation energy for lithium ion migration in the solid state lithium ion electrolyte is 0.5 eV or less. Composites of specific formulae are provided. A lithium battery containing the composite lithium ion electrolyte is also provided.

COMPOUNDS WITH MIXED ANIONS AS SOLID Li-ION CONDUCTORS

A solid-state lithium ion electrolyte is provided which contains a composite material having at least 94 mole % lithium ions as cation component and multiple anions in an anionic framework capable of conducting lithium ions. An activation energy for lithium ion migration in the solid state lithium ion electrolyte is 0.5 eV or less. Composites of specific formulae are provided. A lithium battery containing the composite lithium ion electrolyte is also provided.

Methods To Prepare Haloamines Using At Least One Solid Reactant And Products Made Therefrom

A method to prepare a haloamine, such as a monochloramine in solution, from a solid halogen releaser(s) is described. Also described is a process to form a haloamine in solution using solid reactants. Also, an aqueous haloamine, such as a monochloramine solution, is further described that has a haloamine in solution and a dehalogenated organic compound present. Methods of use are also described.

Methods To Prepare Haloamines Using At Least One Solid Reactant And Products Made Therefrom

A method to prepare a haloamine, such as a monochloramine in solution, from a solid halogen releaser(s) is described. Also described is a process to form a haloamine in solution using solid reactants. Also, an aqueous haloamine, such as a monochloramine solution, is further described that has a haloamine in solution and a dehalogenated organic compound present. Methods of use are also described.

Scalable process for producing exfoliated defect-free, non-oxidised 2-dimensional materials in large quantities

A process for exfoliating untreated 3-dimensional material to produce a 2-dimensional material, said process comprising the steps of mixing the untreated 3-dimensional material in a liquid to provide a mixture; applying shear force to said mixture to exfoliate the 3-dimensional material and produce dispersed exfoliated 2-dimensional material in solution; and removing the shear force applied to said mixture, such that the dispersed exfoliated 2-dimensional material remains free and unaggregated in solution.