Patent classifications
C01B21/38
Method for removing N.SUB.2.O and NO.SUB.x .from the nitric acid production process, and an installation suitable for same
An apparatus is provided for treatment of process gas formed during nitric acid production by catalytic oxidation of NH.sub.3. The apparatus includes a reactor, a first catalyst bed for N.sub.2O decomposition, an absorption tower to react the NO.sub.x formed with an absorption medium downstream of the first catalyst bed, a device for adding NH.sub.3 added to tailgas entering the second catalyst bed, and a second catalyst bed for NO.sub.x reduction and further decrease in N.sub.2O in the tailgas exiting the absorption tower. The second catalyst bed contains at least one iron-loaded zeolite catalyst. N.sub.2O removal in the first catalyst bed is limited such that the process gas exiting the first catalyst bed exhibits a N.sub.2O content of >100 ppmv and a molar N.sub.2O/NO.sub.x ratio of >0.25. Treated gas exiting the second catalyst bed has a NO.sub.x concentration of <40 ppmv and a N.sub.2O concentration of <200 ppmv.
Method for removing N.SUB.2.O and NO.SUB.x .from the nitric acid production process, and an installation suitable for same
An apparatus is provided for treatment of process gas formed during nitric acid production by catalytic oxidation of NH.sub.3. The apparatus includes a reactor, a first catalyst bed for N.sub.2O decomposition, an absorption tower to react the NO.sub.x formed with an absorption medium downstream of the first catalyst bed, a device for adding NH.sub.3 added to tailgas entering the second catalyst bed, and a second catalyst bed for NO.sub.x reduction and further decrease in N.sub.2O in the tailgas exiting the absorption tower. The second catalyst bed contains at least one iron-loaded zeolite catalyst. N.sub.2O removal in the first catalyst bed is limited such that the process gas exiting the first catalyst bed exhibits a N.sub.2O content of >100 ppmv and a molar N.sub.2O/NO.sub.x ratio of >0.25. Treated gas exiting the second catalyst bed has a NO.sub.x concentration of <40 ppmv and a N.sub.2O concentration of <200 ppmv.
PROCESS FOR PREPARATION OF NITROGEN OXIDES AND NITRIC ACID FROM NITROUS OXIDE
Described herein is an improved conversion of nitrous oxide (N.sub.2O) present as a by-product in a chemical process to NO.sub.x which can be further converted to a useful compound or material, such as nitric acid.
PROCESS FOR PREPARATION OF NITROGEN OXIDES AND NITRIC ACID FROM NITROUS OXIDE
Described herein is an improved conversion of nitrous oxide (N.sub.2O) present as a by-product in a chemical process to NO.sub.x which can be further converted to a useful compound or material, such as nitric acid.
Process for preparation of nitrogen oxides and nitric acid from nitrous oxide
Described herein is an improved conversion of nitrous oxide (N.sub.2O) present as a by-product in a chemical process to NO.sub.x which can be further converted to a useful compound or material, such as nitric acid.
Process for preparation of nitrogen oxides and nitric acid from nitrous oxide
Described herein is an improved conversion of nitrous oxide (N.sub.2O) present as a by-product in a chemical process to NO.sub.x which can be further converted to a useful compound or material, such as nitric acid.
PROCESS FOR REGENERATING A BATH FOR CHEMICAL ETCHING OF TITANIUM PARTS
Disclosed is a method of regenerating a nitric and hydrofluoric acid bath contained in a machining vessel, the method including, when the etching bath is spent, performing steps of: transferring a portion of the spent etching bath, referred to as the spent solution, from the machining vessel into a reactor; adding NaF and NaNO.sub.3 to the spent solution, to form HF, HNO.sub.3, and Na.sub.2TiF.sub.6; separating the resulting precipitate from the supernatant; transferring the supernatant, which is a regenerated solution, into a tank; measuring the concentrations of HF, of HNO.sub.3, and of dissolved titanium in the tank and in the machining vessel; and determining the volume of regenerated solution that can be added to the spent etching bath to obtain a regenerated bath in which the concentrations of HF, of HNO.sub.3, and of dissolved titanium lie in acceptable concentration ranges, and transferring the regenerated solution into the machining vessel.
METHOD FOR OXIDIZING AMMONIA AND SYSTEM SUITABLE THEREFOR
A system suitable for oxidizing ammonia with oxygen in the presence of catalysts is described. The system includes a reactor equipped with at least one supply line for a reactant gas mixture and at least one discharge line for a process gas; a catalyst comprising at least one transition metal oxide that is not an oxide of a platinum metal; and a device for adjusting a molar ratio of oxygen to ammonia of less than or equal to 1.75 mol/mol in the reactant gas mixture by mixing an oxygen-containing gas stream having an O.sub.2 content of <20% by volume with a chosen amount of ammonia. The oxygen-containing gas stream is produced by a device for: diluting an air stream with a gas stream comprising less than 20% by volume oxygen; or depleting oxygen from an oxygen-containing gas mixture, preferably from air; or by a combination thereof.
METHOD FOR OXIDIZING AMMONIA AND SYSTEM SUITABLE THEREFOR
A system suitable for oxidizing ammonia with oxygen in the presence of catalysts is described. The system includes a reactor equipped with at least one supply line for a reactant gas mixture and at least one discharge line for a process gas; a catalyst comprising at least one transition metal oxide that is not an oxide of a platinum metal; and a device for adjusting a molar ratio of oxygen to ammonia of less than or equal to 1.75 mol/mol in the reactant gas mixture by mixing an oxygen-containing gas stream having an O.sub.2 content of <20% by volume with a chosen amount of ammonia. The oxygen-containing gas stream is produced by a device for: diluting an air stream with a gas stream comprising less than 20% by volume oxygen; or depleting oxygen from an oxygen-containing gas mixture, preferably from air; or by a combination thereof.
Knitting of precious metal networks and a method using same
The invention relates to a method for producing large stainless steel meshes on flatbed knitting machines, comprising the steps of providing stainless steel wire and knitting a stainless steel mesh, characterized in that one stainless steel mesh each is knitted on the front and the rear needle bed of the flatbed knitting machine at the same time, and these two stainless steel meshes are linked to each other on one side by connecting stitches.