One variation of a diamond composition includes carbon: including a first amount of carbon-13 isotopes and a second amount of carbon-12 isotopes; and sourced from a hydrocarbon mixture including hydrocarbons and formed via methanation of a carbon dioxide mixture. The carbon dioxide mixture: sourced from a sample of air including carbon dioxide and impurities; conveyed through a separation unit configured to remove impurities; including carbon dioxide and impurities; conveyed through a distillation column configured to regulate amounts of carbon-13 isotopes and carbon-12 isotopes; and exhibiting a target ratio of carbon-13 isotopes to carbon-12 isotopes at an outlet of the distillation column. The diamond composition: formed via chemical vapor deposition; and exhibiting an isotopic signature defining a final ratio of the first amount of carbon-13 isotopes to the second amount of carbon-12 isotopes within a first target range corresponding to the target ratio exhibited by the carbon dioxide mixture.

One variation of a diamond composition includes carbon: including a first amount of carbon-13 isotopes and a second amount of carbon-12 isotopes; and sourced from a hydrocarbon mixture including hydrocarbons and formed via methanation of a carbon dioxide mixture. The carbon dioxide mixture: sourced from a sample of air including carbon dioxide and impurities; conveyed through a separation unit configured to remove impurities; including carbon dioxide and impurities; conveyed through a distillation column configured to regulate amounts of carbon-13 isotopes and carbon-12 isotopes; and exhibiting a target ratio of carbon-13 isotopes to carbon-12 isotopes at an outlet of the distillation column. The diamond composition: formed via chemical vapor deposition; and exhibiting an isotopic signature defining a final ratio of the first amount of carbon-13 isotopes to the second amount of carbon-12 isotopes within a first target range corresponding to the target ratio exhibited by the carbon dioxide mixture.

Provided is an explosive composition for diamond synthesis by which diamond particles having a relatively large diameter can be produced. The explosive composition for diamond synthesis contains an explosive component, a carbon raw material that may be included as the explosive component, and diamond particles. Furthermore, the total proportion of the explosive component, the carbon raw material, and the diamond particles relative to the total amount of the explosive composition for diamond synthesis is 99 mass% or greater. The crystallite diameter of primary particles of the diamond particles as determined by the XRD method is preferably 100 nm or less.

Provided is an explosive composition for diamond synthesis by which diamond particles having a relatively large diameter can be produced. The explosive composition for diamond synthesis contains an explosive component, a carbon raw material that may be included as the explosive component, and diamond particles. Furthermore, the total proportion of the explosive component, the carbon raw material, and the diamond particles relative to the total amount of the explosive composition for diamond synthesis is 99 mass% or greater. The crystallite diameter of primary particles of the diamond particles as determined by the XRD method is preferably 100 nm or less.

A method of a growing an embedded single crystal diamond structure, comprising: disposing a single crystal diamond on a non-diamond substrate, wherein the non-diamond substrate is larger than the single crystal diamond; masking a top portion of the single crystal diamond using a masking material; and using a chemical vapor deposition (CVD) growth chamber, growing polycrystalline diamond material surrounding the single crystal diamond in order to join the single crystal diamond to the polycrystalline diamond material.

A method of a growing an embedded single crystal diamond structure, comprising: disposing a single crystal diamond on a non-diamond substrate, wherein the non-diamond substrate is larger than the single crystal diamond; masking a top portion of the single crystal diamond using a masking material; and using a chemical vapor deposition (CVD) growth chamber, growing polycrystalline diamond material surrounding the single crystal diamond in order to join the single crystal diamond to the polycrystalline diamond material.

Apparatuses and methods for forming a film on a substrate are described. The film is formed on the substrate by depositing an adamantane monomer and an initiator on the substrate to form a polymerizable seed layer and curing the polymerizable seed layer to form a polyadamantane layer.

Apparatuses and methods for forming a film on a substrate are described. The film is formed on the substrate by depositing an adamantane monomer and an initiator on the substrate to form a polymerizable seed layer and curing the polymerizable seed layer to form a polyadamantane layer.

In various exemplary embodiments, the present disclosure provides a process for the conversion of certain polymers into diamond and diamond-like materials using laser pulse annealing. The process includes transforming the polymer to carbon, melting the carbon and quenching the carbon melt into to form Q-carbon, diamond, and/or graphene. The process can be applied to a polymer film such as a polytetrafluoroethylene (PTFE) tape. An object can be coated with the polymer film which can then be converted to Q-carbon, diamond, and/or graphene using laser pulse annealing. A process is also provided for making a three-dimensional object using a combination of, for example, 3D printing the polymer and converting each layer of polymer into Q-carbon, diamond and/or graphene.

In various exemplary embodiments, the present disclosure provides a process for the conversion of certain polymers into diamond and diamond-like materials using laser pulse annealing. The process includes transforming the polymer to carbon, melting the carbon and quenching the carbon melt into to form Q-carbon, diamond, and/or graphene. The process can be applied to a polymer film such as a polytetrafluoroethylene (PTFE) tape. An object can be coated with the polymer film which can then be converted to Q-carbon, diamond, and/or graphene using laser pulse annealing. A process is also provided for making a three-dimensional object using a combination of, for example, 3D printing the polymer and converting each layer of polymer into Q-carbon, diamond and/or graphene.