The present disclosure discloses a method for growing a crystal without annealing. The method may include compensating a weight of a reactant, introducing a flowing gas, improving a volume ratio of oxygen during a cooling process, providing a heater in a temperature field, and optimizing parameters. According to the method, problems may be solved, for example, cracking and component deviation of the crystal during a crystal growth process, and without oxygen-free vacancy. The method for growing the crystal may have excellent repeatability and crystal performance consistency.

The present invention provides a porous silicon-carbon composite, a manufacturing method therefor, and a negative electrode active material comprising same. Since the porous silicon-carbon composite of the present invention includes silicon particles, magnesium fluoride, and carbon, the initial efficiency and capacity retention ratio of a secondary battery can be further increased as well as the discharge capacity thereof.

The present invention provides a porous silicon-carbon composite, a manufacturing method therefor, and a negative electrode active material comprising same. Since the porous silicon-carbon composite of the present invention includes silicon particles, magnesium fluoride, and carbon, the initial efficiency and capacity retention ratio of a secondary battery can be further increased as well as the discharge capacity thereof.

A process for synthesizing a Mn.sup.4+ doped phosphor of formula I by electrolysis is presented. The process includes electrolyzing a reaction solution comprising a source of manganese, a source of M and a source of A. One aspect relates to a phosphor composition produced by the process. A lighting apparatus including the phosphor composition is also provided. A.sub.x[MF.sub.y]:Mn.sup.4+ (I) where, A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MF.sub.y] ion; and y is 5, 6 or 7.

A process for synthesizing a Mn.sup.4+ doped phosphor of formula I by electrolysis is presented. The process includes electrolyzing a reaction solution comprising a source of manganese, a source of M and a source of A. One aspect relates to a phosphor composition produced by the process. A lighting apparatus including the phosphor composition is also provided. A.sub.x[MF.sub.y]:Mn.sup.4+ (I) where, A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MF.sub.y] ion; and y is 5, 6 or 7.

Provided is a fluoride fluorescent material having high luminance.

The fluoride fluorescent material has a composition containing Mn, A that is at least one element or ion selected from the group consisting of alkali metal elements and NH.sub.4.sub.+, at least one element M selected from the group consisting of Group-4 elements and Group-14 elements, and F; and contains spherical fluoride particles.

A coalizing product and a method for the coalescing of oil contaminants from a water flow is described, in which the product according to the invention is arranged in an apparatus for in depth coalescing of oil contaminated water. There are also disclosed uses of the method and the product for coalescing of oil contamination in water.

A coalizing product and a method for the coalescing of oil contaminants from a water flow is described, in which the product according to the invention is arranged in an apparatus for in depth coalescing of oil contaminated water. There are also disclosed uses of the method and the product for coalescing of oil contamination in water.

The present invention relates to a process for producing a composite-fluoride fluorescent material represented by the general formula A.sub.2MF.sub.6:Mn.sup.4+ (wherein A is at least one alkali metal element including K; M is one or more metallic elements including at least Si or Ge and selected from among Si, Ge, Sn, Ti, Zr, and Hf; F is fluorine; and Mn is manganese). With the production process, it is possible to obtain a fluorescent material which is high in absorptance, internal quantum efficiency, and external quantum efficiency and has excellent optical properties.

The present invention relates to a process for producing a composite-fluoride fluorescent material represented by the general formula A.sub.2MF.sub.6:Mn.sup.4+ (wherein A is at least one alkali metal element including K; M is one or more metallic elements including at least Si or Ge and selected from among Si, Ge, Sn, Ti, Zr, and Hf; F is fluorine; and Mn is manganese). With the production process, it is possible to obtain a fluorescent material which is high in absorptance, internal quantum efficiency, and external quantum efficiency and has excellent optical properties.