Patent classifications
C01B33/26
Aluminum silicate, metal ion adsorbent, and method for producing same
The aluminum silicate of the invention has: an element ratio of Si and Al, represented by Si/Al, of from 0.3 to 1.0 by molar ratio; a peak at approximately 3 ppm in a .sup.27Al-NMR spectrum; peak A at approximately −78 ppm and peak B at approximately −85 ppm in a .sup.29Si-NMR spectrum; and a peak at approximately 2θ=26.9° and a peak at approximately 2θ=40.3° in a powder X-ray diffraction spectrum. The aluminum silicate has an area ratio of peak B with respect to peak A of from 2.0 to 9.0, or does not include a tubular substance having a length of 50 nm or more as observed in a transmission electron microscope (TEM) photograph of the aluminum silicate taken at a magnification of 100,000. The aluminum silicate is produced by a method comprising: subjecting a reaction product of a silicate ion solution and an aluminum ion solution to desalting and solid separation; subjecting a resultant to a thermal treatment in an aqueous medium in the presence of an acid under concentration conditions in an aqueous medium such that a silicon atom concentration is 100 mmol/L or more and an aluminum atom concentration is 100 mmol/L or more; and subjecting a resultant to further desalting and solid separation.
Solar-Reflective Roofing Granules with Hollow Glass Spheres
The present disclosure relates to roofing granule having a base granule with at least one layer on the base granule that includes hollow glass spheres embedded in a ceramic matrix and a roofing article having a substrate and a plurality of any embodiment of roofing granules described above. The disclosure additionally relates to a roofing granule precursor mixture containing base granules, an aluminum silicate, an alkali metal silicate, and hollow glass spheres. The disclosure also relates to a method of making roofing granules including providing base granules; applying a coating containing hollow glass spheres, an aluminum silicate, an alkali metal silicate to the base granules; and heating the coated granules to a temperature between about 550° F. and about 1000° F.
Method for extending the campaign life of stabilizers for a coating line
A steel processing line includes a dip tub and a stab roll. The dip tub is filled with a quantity of molten metal. At least a portion of the stab roll is submerged in the quantity of molten metal. The stab roll includes two journals. Each journal is received by an opening defined by a roller sleeve including a ceramic or refractory material. The roller sleeve is disposed between each journal and a bearing block. An inner dimension of each roller sleeve and an outer dimension of each respective journal defines a clearance. The inner dimension of each roller sleeve and the outer dimension of each respective journal is configured such that the clearance persists as the stab roll and the pair of roller sleeves are heated by the molten metal. Alternatively, inserts are fastened to an outer surface of each journal in lieu of the roller sleeves.
Method for extending the campaign life of stabilizers for a coating line
A steel processing line includes a dip tub and a stab roll. The dip tub is filled with a quantity of molten metal. At least a portion of the stab roll is submerged in the quantity of molten metal. The stab roll includes two journals. Each journal is received by an opening defined by a roller sleeve including a ceramic or refractory material. The roller sleeve is disposed between each journal and a bearing block. An inner dimension of each roller sleeve and an outer dimension of each respective journal defines a clearance. The inner dimension of each roller sleeve and the outer dimension of each respective journal is configured such that the clearance persists as the stab roll and the pair of roller sleeves are heated by the molten metal. Alternatively, inserts are fastened to an outer surface of each journal in lieu of the roller sleeves.
Synthetic Pozzolans
Synthetic pozzolans are produced using local materials to provide a cementitious material that is uniform in chemistry and properties independent of the location where the materials are obtained. Two methods of production are described. One is a high temperature process in which materials are processed in a semi-molten or molten state. The second process is a low temperature aqueous process.
Functionalized aluminosilicate microspheres for golf ball applications
A golf ball core, mantle, and/or cover layer(s) of golf ball having a composition comprising functionalized aluminosilicate particles having a particle size of less than 50 μm is disclosed herein. The aluminosilicate microspheres with an average diameter less than 50 μm are functionalized with, but not limited to, polysulfide, vinyl, amino, epoxy, hydroxyl, carboxyl, methacryloyl, hydrocarbon, mercapto and isocyanate.
Functionalized aluminosilicate microspheres for golf ball applications
A golf ball core, mantle, and/or cover layer(s) of golf ball having a composition comprising functionalized aluminosilicate particles having a particle size of less than 50 μm is disclosed herein. The aluminosilicate microspheres with an average diameter less than 50 μm are functionalized with, but not limited to, polysulfide, vinyl, amino, epoxy, hydroxyl, carboxyl, methacryloyl, hydrocarbon, mercapto and isocyanate.
NUCLEAR FUEL PELLETS AND MANUFACTURING METHOD THEREOF
The present invention relates to nuclear fuel pellets and a manufacturing method thereof, and more particularly, to nuclear fuel pellets comprising a trapping material of fission gas and a manufacturing method thereof. A nuclear fuel pellet of the present invention comprises a nuclear fuel; and a trapping material of fission gas, wherein the trapping material of the fission gas includes an oxide containing at least one element selected from the group consisting of silicon (Si), aluminum (Al) and barium (Ba) to exhibit an excellent trapping ability selective and independent for fission gas.
PREPARATION OF RARE EARTH METALS AND OTHER CHEMICALS FROM INDUSTRIAL WASTE COAL ASH
A process disclosed herein is related to the isolation and purification of substantially pure chemicals, including silica gel, sodium silicate, aluminum silicate, iron oxide, and rare earth elements (or rare earth metals, REEs), from massive industrial waste coal ash. In one embodiment, the process includes a plurality of caustic extractions of coal ash at an elevated temperature, followed by an acidic treatment to dissolve aluminum silicate and REEs. The dissolved aluminum silicate is precipitated out by pH adjustment as a solid product while REEs remain in the solution. REEs are captured and enriched using an ion exchange column. Alternatively, the solution containing aluminum silicate and REEs is heated to produce silica gel, which is easily separated from the enriched REEs solution. REEs are then isolated and purified from the enriched solution to afford substantially pure individual REE by a ligand-assisted chromatography. Additionally, a simplified process using one caustic extraction and one acidic extraction with an ion exchange process was also investigated and optimized to afford a comparable efficiency.
PREPARATION OF RARE EARTH METALS AND OTHER CHEMICALS FROM INDUSTRIAL WASTE COAL ASH
A process disclosed herein is related to the isolation and purification of substantially pure chemicals, including silica gel, sodium silicate, aluminum silicate, iron oxide, and rare earth elements (or rare earth metals, REEs), from massive industrial waste coal ash. In one embodiment, the process includes a plurality of caustic extractions of coal ash at an elevated temperature, followed by an acidic treatment to dissolve aluminum silicate and REEs. The dissolved aluminum silicate is precipitated out by pH adjustment as a solid product while REEs remain in the solution. REEs are captured and enriched using an ion exchange column. Alternatively, the solution containing aluminum silicate and REEs is heated to produce silica gel, which is easily separated from the enriched REEs solution. REEs are then isolated and purified from the enriched solution to afford substantially pure individual REE by a ligand-assisted chromatography. Additionally, a simplified process using one caustic extraction and one acidic extraction with an ion exchange process was also investigated and optimized to afford a comparable efficiency.