Boron-based amorphous alloys and a preparation method thereof is provided. The composition formula of the alloys is B.sub.aCo.sub.bRE.sub.cX1.sub.dX2.sub.eX3.sub.f, wherein RE is any one or more of La, Ce, Pr, Nd, Sm, Gd, Dy, Er and Y; X1 is any one or more of C, Si and Al; X2 is any one or two of Fe and Ni; X3 is any one or more of Zr, Nb, Mo, Hf, Ta and W; and a, b, c, d, e and f respectively represent atomic percent of each corresponding element in the formula, where: 45≤a≤55, 25≤b≤40, 10≤c≤20, 0≤d≤10, 45≤a+d≤55, 0≤e≤20, 25≤b+e≤40, 0≤f≤3, 10≤c+f≤20 and a+b+c+d+e+f=100. The preparation method of the boron-based amorphous alloy comprises: preparing master alloy ingots using an arc furnace or an induction melting furnace; and then obtaining amorphous ribbons with different thicknesses by a single copper roller melt-spinning equipment.

A method for growing bulk boron arsenide (BA) crystals, the method comprising utilizing a seeded chemical vapor transport (CVT) growth mechanism to produce single BAs crystals which are used for further CVT growth, wherein a sparsity of nucleation centers is controlled during the further CVT growth. Also disclosed are bulk BAs crystals produced via the method.

A method for growing bulk boron arsenide (BA) crystals, the method comprising utilizing a seeded chemical vapor transport (CVT) growth mechanism to produce single BAs crystals which are used for further CVT growth, wherein a sparsity of nucleation centers is controlled during the further CVT growth. Also disclosed are bulk BAs crystals produced via the method.

The invention relates to a method for producing a non-oxide ceramic powder comprising a nitride, a carbide, a boride or at least one MAX phase with the general composition Mn+1AXn, where M=at least one element from the group of transition elements (Sc, Ti, V, Cr, Zr, Nb, Mo, Hf and Ta), A=at least one A group element from the group (Si, Al, Ga, Ge, As, Cd, In, Sn, Tl and Pb), X=carbon (C) and/or nitrogen (N) and/or boron (B), and n=1, 2 or 3. According to the invention, corresponding quantities of elementary starting materials or other precursors are mixed with at least one metal halide salt (NZ), compressed (pellet), and heated for synthesis with a metal halide salt (NZ). The compressed pellet is first enveloped with another metal halide salt, compressed again, arranged in a salt bath and heated therewith until the melting temperature of the salt is exceeded. Optionally, melted silicate can be added, which prevents the salt from evaporating at high temperatures. Advantageously, the method can be carried out in the presence of air.

In order to provide a zirconium boride that provides high caloric value at the time of its combustion with a compound having radicals such as perchlorate and can combust in a short period of time, while providing high physical stability, an amount of radical derived from lattice defect detected by ESR spectroscopy, is set to 0.1×10.sup.15 spin/mg or more.

In order to provide a zirconium boride that provides high caloric value at the time of its combustion with a compound having radicals such as perchlorate and can combust in a short period of time, while providing high physical stability, an amount of radical derived from lattice defect detected by ESR spectroscopy, is set to 0.1×10.sup.15 spin/mg or more.

Methods for providing new transparent near infrared absorptive fine particles having a wide range of near infrared absorption, which are an assembly of hexaboride fine particles, where when a particle shape of the number of particles contained in the assembly is approximately regarded as a spheroid body, there are 20% or more and less than 80% of particles having an aspect ratio [(long axis length)/(short axis length)] of 1.5 or more and less than 5.0, and there are 20% or more and less than 80% of particles having an aspect ratio of 5.0 or more and less than 20.0.

Methods for providing new transparent near infrared absorptive fine particles having a wide range of near infrared absorption, which are an assembly of hexaboride fine particles, where when a particle shape of the number of particles contained in the assembly is approximately regarded as a spheroid body, there are 20% or more and less than 80% of particles having an aspect ratio [(long axis length)/(short axis length)] of 1.5 or more and less than 5.0, and there are 20% or more and less than 80% of particles having an aspect ratio of 5.0 or more and less than 20.0.

A method of preparing a boron allotrope-organic lateral heterostructural article includes providing an article comprising a substrate comprising a portion thereof coupled to a boron allotrope comprising an elemental boron layer; generating an organic compound vapor from a solid organic compound source, said organic compound vapor having a higher enthalpy of adsorption on said substrate compared to enthalpy of adsorption on said boron allotrope; and contacting said organic compound vapor with said article to selectively deposit said organic compound on a substrate portion not coupled to said boron allotrope to provide a heterostructural article comprising said organic compound and said boron allotrope laterally adjacent one to the other and providing a lateral interface one with the other.

A method of preparing a boron allotrope-organic lateral heterostructural article includes providing an article comprising a substrate comprising a portion thereof coupled to a boron allotrope comprising an elemental boron layer; generating an organic compound vapor from a solid organic compound source, said organic compound vapor having a higher enthalpy of adsorption on said substrate compared to enthalpy of adsorption on said boron allotrope; and contacting said organic compound vapor with said article to selectively deposit said organic compound on a substrate portion not coupled to said boron allotrope to provide a heterostructural article comprising said organic compound and said boron allotrope laterally adjacent one to the other and providing a lateral interface one with the other.