Tin containing precursors and methods of forming tin-containing thin films are described. The tin precursor has a tin-diazadiene bond and is homoleptic or heteroleptic. A suitable reactant is used to provide one of a metallic tin film or a film comprising one or more of an oxide, nitride, carbide, boride and/or silicide. Methods of forming ternary materials comprising tin with two or more of oxygen, nitrogen, carbon, boron, silicon, titanium, ruthenium and/or tungsten are also described.

Tin containing precursors and methods of forming tin-containing thin films are described. The tin precursor has a tin-diazadiene bond and is homoleptic or heteroleptic. A suitable reactant is used to provide one of a metallic tin film or a film comprising one or more of an oxide, nitride, carbide, boride and/or silicide. Methods of forming ternary materials comprising tin with two or more of oxygen, nitrogen, carbon, boron, silicon, titanium, ruthenium and/or tungsten are also described.

The following two problems arise when carbon is added to a starting material powder in the process of production of an MgB.sub.2 superconductor: (1) an impurity phase increases; and (2) the degree of substitution of carbon at boron sites is spatially non-uniform. This superconductor production method comprises: a mixing step of mixing a starting material powder and an additive; and a heat treatment step of heat-treating the mixture prepared in the mixing step. The starting material powder is MgB.sub.2 powder or a mixed powder of magnesium and boron, and the additive is an MgBC compound containing three elements of magnesium, boron and carbon.

The following two problems arise when carbon is added to a starting material powder in the process of production of an MgB.sub.2 superconductor: (1) an impurity phase increases; and (2) the degree of substitution of carbon at boron sites is spatially non-uniform. This superconductor production method comprises: a mixing step of mixing a starting material powder and an additive; and a heat treatment step of heat-treating the mixture prepared in the mixing step. The starting material powder is MgB.sub.2 powder or a mixed powder of magnesium and boron, and the additive is an MgBC compound containing three elements of magnesium, boron and carbon.

The present disclosure relates to a superconductor including magnesium diboride and a production method therefor. A superconductor having a high critical current density at a certain temperature and under a certain magnetic field may be obtained by doping magnesium diboride with liquid chloroform during the production of the superconductor.

The present disclosure relates to a superconductor including magnesium diboride and a production method therefor. A superconductor having a high critical current density at a certain temperature and under a certain magnetic field may be obtained by doping magnesium diboride with liquid chloroform during the production of the superconductor.

Provided is an alumina-based thermally conductive oxide which has not only an excellent thermal conductivity but also excellent chemical resistance, water-fastness, and electrical insulation property, while exhibiting a satisfactory kneadability (miscibility) into a resin and being capable of producing materials and articles, such as a resin composition, having an excellent shapability. Specifically, the present invention is an alumina-based thermally conductive oxide which is obtained by firing a starting material mixture that contains an aluminum starting material. The aluminum starting material is at least one selected from the group consisting of boehmite, aluminum hydroxide, and alumina; the starting material mixture further contains a boric acid compound and an oxide starting material such as a tungsten compound; and the content of the boric acid compound in the starting material mixture is 0.1 to 5 parts by mass, and the content of the oxide starting material in the starting material mixture is 0.1 to 20 parts by mass each based on 100 parts by mass of the aluminum starting material.

An object of the invention is to provide: an MgB.sub.2 superconducting thin-film wire that exhibits excellent J.sub.c characteristics even under a 20 K magnetic field; and a method for producing thereof. The MgB.sub.2 superconducting thin-film wire includes a long substrate and an MgB.sub.2 thin film formed on the long substrate. The MgB.sub.2 thin film has a microtexture such that MgB.sub.2 columnar crystal grains stand densely together on the surface of the long substrate, and has T.sub.c of 30 K or higher. In grain boundary regions of the MgB.sub.2 columnar crystal grains, a predetermined transition metal element is dispersed and segregated. The predetermined transition metal element is an element having a body-centered cubic lattice structure.

An object of the invention is to provide: an MgB.sub.2 superconducting thin-film wire that exhibits excellent J.sub.c characteristics even under a 20 K magnetic field; and a method for producing thereof. The MgB.sub.2 superconducting thin-film wire includes a long substrate and an MgB.sub.2 thin film formed on the long substrate. The MgB.sub.2 thin film has a microtexture such that MgB.sub.2 columnar crystal grains stand densely together on the surface of the long substrate, and has T.sub.c of 30 K or higher. In grain boundary regions of the MgB.sub.2 columnar crystal grains, a predetermined transition metal element is dispersed and segregated. The predetermined transition metal element is an element having a body-centered cubic lattice structure.

A boron filled hybrid nanotube and a method for producing and rendering boron filled hybrid nanotubes suitable for applications are provided. A mixture of a boron containing nanowire producing compound and catalysts is prepared and ground for a predetermined time period. The ground mixture is subjected to a vapor deposition process including passing an inert gas over the ground mixture after adding a nanotube producing compound to the ground mixture or after passing a reactant gas on the ground mixture in a reactor at a configurable reaction temperature and a configurable reaction pressure for a configurable reaction time to produce the boron filled hybrid nanotubes with enhanced mechanical, thermal and electrical properties. Each boron filled hybrid nanotube includes one or more boron based nanowires embedded within one or more single walled or multi-walled nanotubes. The boron filled hybrid nanotubes are further purified and functionalized using acids, and/or bases, and/or surfactants.