Patent classifications
C01B39/023
Process for the production of the CHA-AFT zeolite intergrowth COE-10 and use thereof in heterogeneous catalysis
A process for the production of a zeolitic material comprising one or more zeolite intergrowth phases of one or more zeolites having a CHA-type framework structure comprising SiO.sub.2 and X.sub.2O.sub.3, and one or more zeolites having an AFT-type framework tructure comprising SiO.sub.2 and X.sub.2O.sub.3, wherein X is a trivalent element, and wherein said process comprises: (1) preparing a mixture comprising one or more sources for SiO.sub.2, one or more sources for X.sub.2O.sub.3, and seed crystals comprising a zeolitic material, said zeolitic material comprising SiO.sub.2 and X.sub.2O.sub.3 in its framework structure and having a CHA-type framework structure; (2) heating the mixture prepared in (1) for obtaining a zeolitic material comprising one or more zeolite intergrowth phases; and (R) subjecting the zeolitic material obtained in (2) to a procedure for removing at least a portion of X from the framework structure of the zeolitic material.
Method for manufacture of co-crystallized zeolite beta and zeolite mordenite in the presence of ODSO
The present disclosure is directed to a method of manufacture of co-crystallized *BEA/MOR zeolites. This is accomplished by using an improved sol-gel formulation including a water-soluble fraction of ODSO as an additional component. The resulting products are, or contain, co-crystallized *BEA/MOR zeolites, whereas in the absence of the ODSO, the resulting products are zeolite beta.
SYNTHESIS OF POROUS CRYSTALLINE MATERIALS IN THE PRESENCE OF WATER-SOLUBLE OXIDIZED DISULFIDE OIL AND FLUORIDE MINERALIZER
Methods are provided for hydrothermal synthesis of porous crystalline materials. The method generally comprises forming a solution of precursors and reagents in effective ratios for a porous crystalline material including a fluoride-containing mineralizer, and water-soluble oxidized disulfide oil. The solution is hydrothermally treated under effective conditions and for an effective time to synthesize porous crystalline materials.
METHOD FOR SYNTHESIS OF NANO-SIZED ZEOLITE Y
The present disclosure is directed to methods of zeolite Y synthesis. Two-stage temperature crystallization methods are employed to synthesize nano-sized zeolite Y that possesses improved crystallinity, surface area, and pore volume compared to zeolite Y produced using alternative methods.
METHOD FOR PRODUCING MODIFIED ALUMINOSILICATE, METHOD FOR PRODUCING CATALYST CONTAINING MODIFIED ALUMINOSILICATE, METHOD FOR PRODUCING AROMATIC POLYHYDROXIDE COMPOUND USING SAME CATALYST, AND MODIFIED ALUMINOSILICATE
Provided are a method for producing a modified aluminosilicate capable of highly selectively producing hydroquinones by a reaction of phenols and hydrogen peroxide under industrially advantageous conditions, a method for producing a catalyst for producing an aromatic dihydroxide compound, a catalyst containing a modified aluminosilicate, a method for producing an aromatic dihydroxide compound using the catalyst, and a modified aluminosilicate. The method for producing an aluminosilicate may include preparing a liquid in which sol-like silica containing water is contacted with a metal compound (AL) containing aluminum and oxygen to obtain an aluminosilicate having a specific range of a molar ratio of water to silica (HMR); treating the aluminosilicate with an acid; subjecting the treated product to primary calcination; and contacting the calcined product with a liquid containing one or more elements in Group 4 and Group 5 of the Periodic Table, followed by carrying out drying and secondary calcination.
Oxidic material comprising a zeolite having framework type AEI
A process for preparing an oxidic material comprising a zeolitic material having framework type AEI and a framework structure comprising a tetravalent element Y, a trivalent element X, and O, the process comprising preparing a synthesis mixture comprising water, a source of Y, a source of X comprising sodium, an AEI framework structure directing agent, and a source of sodium other than the source of X; and heating the synthesis mixture obtained from (i) to a temperature in the range of from 100 to 180 C. and keeping the synthesis mixture under autogenous pres-sure at a temperature in this range for a time in the range of at least 6 h, obtaining the oxidic material comprising a zeolitic material having framework type AEI and a framework structure comprising a tetravalent element Y, a trivalent element X, and O, comprised in its mother liquor; wherein the AEI framework structure directing agent according to (i) comprises a N, N-diethyl-2,6-dimethylpiperidinium cation.
MOLECULAR SIEVE SSZ-91 WITH HIERARCHICAL POROSITY, METHODS FOR PREPARING, AND USES THEREOF
Disclosed are crystalline mesoporous molecular sieves based on molecular sieve SSZ-91, methods for making mesoporous SSZ-91, and use of mesoporous SSZ-91 in hydroconversion applications. Mesoporous molecular sieve SSZ-91 is characterized as: having a low degree of faulting, having a low aspect ratio that inhibits hydrocracking as compared to conventional ZSM-48 materials having an aspect ratio of greater than 8, being substantially phase pure, and having a total pore volume (measured at P/P.sub.0 of 0.95) in the mesopore diameter range is at least about 0.2 cc/g and wherein the micropore volume is at least 0.05 cc/g.