C01B39/42

Catalytic composition and process using it for the alkylation of aromatic hydrocarbons with alcohols, or mixtures of alcohols and olefins

The invention relates to a new catalytic composition for the alkylation of aromatic compounds with alcohols, or mixtures of alcohols and corresponding olefins, wherein said composition comprises a zeolite of the MTW type and is characterized in that it contains one or more alkaline metals in a total quantity which is less than or equal to 0.02% by weight. The use of said catalyst in the alkylation of aromatic compounds with alcohols, in particular benzene with isopropanol or ethanol, allows the formation, as by-product, of the aldehyde or ketone corresponding to the alcohol used, to be minimized: the formation of reaction by-products of said aldehydes or ketones having a boiling point very close to that of polyalkylation products, is therefore significantly reduced. This provides a considerable advantage in the subsequent transalkylation step for the recovery of said polyalkylates by transformation into the corresponding monoalkylates.

Synthesis of MTW framework type molecular sieves
10138132 · 2018-11-27 · ·

A method is disclosed for synthesizing MTW framework type molecular sieves using 1,1-diethyl-4-methylpiperidinium cations as a structure directing agent.

Synthesis of MTW framework type molecular sieves
10138132 · 2018-11-27 · ·

A method is disclosed for synthesizing MTW framework type molecular sieves using 1,1-diethyl-4-methylpiperidinium cations as a structure directing agent.

Synthesis of Succinimides and Quaternary Ammonium Ions for Use in Making Molecular Sieves
20180305309 · 2018-10-25 ·

The present invention relates to the synthesis of succinimides, in particular to a method for the synthesis of a succinimide compound, comprising the step of reacting an alkyne, with carbon monoxide and ammonia or an amine, in the presence of an iron catalyst, wherein the reaction is carried out in an amine liquid phase and/or in the absence of an ether solvent. The succinimides may be reduced to quaternary ammonium cations which may be used as structure directing agents in the synthesis of molecular sieves.

Synthesis of Succinimides and Quaternary Ammonium Ions for Use in Making Molecular Sieves
20180305309 · 2018-10-25 ·

The present invention relates to the synthesis of succinimides, in particular to a method for the synthesis of a succinimide compound, comprising the step of reacting an alkyne, with carbon monoxide and ammonia or an amine, in the presence of an iron catalyst, wherein the reaction is carried out in an amine liquid phase and/or in the absence of an ether solvent. The succinimides may be reduced to quaternary ammonium cations which may be used as structure directing agents in the synthesis of molecular sieves.

Synthesis of succinimides and quaternary ammonium ions for use in making molecular sieves

The present invention relates to the synthesis of succinimides, in particular to a method for the synthesis of a succinimide compound, comprising the step of reacting an alkyne, with carbon monoxide and ammonia or an amine, in the presence of an iron catalyst, wherein the reaction is carried out in an amine liquid phase and/or in the absence of an ether solvent. The succinimides may be reduced to quaternary ammonium cations which may be used as structure directing agents in the synthesis of molecular sieves.

Synthesis of succinimides and quaternary ammonium ions for use in making molecular sieves

The present invention relates to the synthesis of succinimides, in particular to a method for the synthesis of a succinimide compound, comprising the step of reacting an alkyne, with carbon monoxide and ammonia or an amine, in the presence of an iron catalyst, wherein the reaction is carried out in an amine liquid phase and/or in the absence of an ether solvent. The succinimides may be reduced to quaternary ammonium cations which may be used as structure directing agents in the synthesis of molecular sieves.

SYNTHESIS OF MTW FRAMEWORK TYPE MOLECULAR SIEVES
20180111836 · 2018-04-26 ·

A method is disclosed for synthesizing MTW framework type molecular sieves using 1,1-diethyl-4-methylpiperidinium cations as a structure directing agent.

Interzeolite transformation and metal encapsulation in the absence of an SDA

Provided is a method of encapsulating a metal in a zeolite. The method comprises inserting a metal precursor into a parent zeolite, and then converting the parent zeolite to a zeolite having a higher framework density than the parent zeolite. The conversion is achieved without the need of an organic structure directing agent.

Interzeolite transformation and metal encapsulation in the absence of an SDA

Provided is a method of encapsulating a metal in a zeolite. The method comprises inserting a metal precursor into a parent zeolite, and then converting the parent zeolite to a zeolite having a higher framework density than the parent zeolite. The conversion is achieved without the need of an organic structure directing agent.