There is disclosed an organic-free, metal-containing zeolite Beta with a silica-to-alumina ratio (SAR) ranging from 5 and 20, and a metal content of at least 0.5 wt. %. There is also disclosed a method of making such a zeolite Beta without organic structure directing agent (SDA). The metal, which may comprise Fe or Cu, can be found in amounts ranging from 1-10 wt. %. A method of selective catalytic reduction of nitrogen oxides in exhaust gases using the disclosed zeolite is also disclosed.

There is disclosed an organic-free, metal-containing zeolite Beta with a silica-to-alumina ratio (SAR) ranging from 5 and 20, and a metal content of at least 0.5 wt. %. There is also disclosed a method of making such a zeolite Beta without organic structure directing agent (SDA). The metal, which may comprise Fe or Cu, can be found in amounts ranging from 1-10 wt. %. A method of selective catalytic reduction of nitrogen oxides in exhaust gases using the disclosed zeolite is also disclosed.

A novel synthetic crystalline aluminogermanosilicate molecular sieve material, designated SSZ-121, is provided. SSZ-121 can be synthesized using 1,3-bis(1-adamantyl)imidazolium cations as a structure directing agent. SSZ-121 may be used in organic compound conversion reactions and/or sorptive processes.

An organotemplate-free synthetic process for synthesizing an aluminosilicate molecular sieve SSZ-122 is provided. The process includes (1) preparing a reaction mixture comprising: (a) a silicon atom source; (b) an aluminum atom source; (c) a source of an alkali metal [M]; (d) a source of hydroxide ions; (e) water; and (f) seed crystals; and (2) subjecting the reaction mixture to crystallization conditions sufficient to form crystals of the aluminosilicate molecular sieve.

An organotemplate-free synthetic process for synthesizing an aluminosilicate molecular sieve SSZ-122 is provided. The process includes (1) preparing a reaction mixture comprising: (a) a silicon atom source; (b) an aluminum atom source; (c) a source of an alkali metal [M]; (d) a source of hydroxide ions; (e) water; and (f) seed crystals; and (2) subjecting the reaction mixture to crystallization conditions sufficient to form crystals of the aluminosilicate molecular sieve.

According to embodiments disclosed herein, a method of forming nano-sized, mesoporous zeolite particles may include contacting initial nano-sized zeolite particles with a first mixture to form nano-sized, mesoporous zeolite particles from the initial nano-sized zeolite particles. The initial nano-sized zeolite particles may have a particle size of less than or equal to 100 nm and may have an average pore size of less than 2 nm. The first mixture may include NaOH; NH.sub.4NO.sub.3, NH.sub.4OH, or both; and a surfactant. The NaOH and the surfactant may interact with the initial nano-sized zeolite particles to remove one or more silica components of the initial nano-sized zeolite particles to form mesopores. The NH.sub.4NO.sub.3, NH.sub.4OH, or both may interact with the initial nano-sized zeolite particles to exchange at least one positively-charged ion from the NH.sub.4NO.sub.3, NH.sub.4OH, or both with at least one positively-charged ion from the initial nano-sized zeolite particles.

According to embodiments disclosed herein, a method of forming nano-sized, mesoporous zeolite particles may include contacting initial nano-sized zeolite particles with a first mixture to form nano-sized, mesoporous zeolite particles from the initial nano-sized zeolite particles. The initial nano-sized zeolite particles may have a particle size of less than or equal to 100 nm and may have an average pore size of less than 2 nm. The first mixture may include NaOH; NH.sub.4NO.sub.3, NH.sub.4OH, or both; and a surfactant. The NaOH and the surfactant may interact with the initial nano-sized zeolite particles to remove one or more silica components of the initial nano-sized zeolite particles to form mesopores. The NH.sub.4NO.sub.3, NH.sub.4OH, or both may interact with the initial nano-sized zeolite particles to exchange at least one positively-charged ion from the NH.sub.4NO.sub.3, NH.sub.4OH, or both with at least one positively-charged ion from the initial nano-sized zeolite particles.

The present disclosure relates to the preparation of pyridine derivatives, such as α-picoline or α-parvoline, and catalysts useful for the selective preparation of such pyridine derivatives. Particularly, the present disclosure relates to the selective preparation of certain pyridine derivative using dealuminated zeolite catalysts.

The present disclosure relates to the preparation of pyridine derivatives, such as α-picoline or α-parvoline, and catalysts useful for the selective preparation of such pyridine derivatives. Particularly, the present disclosure relates to the selective preparation of certain pyridine derivative using dealuminated zeolite catalysts.

Embodiments of the present disclosure are directed to hydrocracking catalysts and methods of making same. The hydrocracking catalyst comprises a platinum encapsulated zeolite having a crystallinity greater than 20% determined by X-ray powder diffraction analysis.