Devices and methods for reducing the specific energy required to reform or pyrolyze reactants in plasmas operating at high flow rates and high pressures are presented. These systems and methods include 1) introducing electrons and/or easily ionized materials to a plasma reactor, 2) increasing turbulence and swirl velocity of the flows of feed gases to have improved mixing in a plasma reactor, and 3) reducing slippage from a plasma reactor system. Such plasma systems may allow plasma reactors to operate at lower temperatures, higher pressure, with improved plasma ignition, increased throughput and improved energy efficiency. In preferred embodiments, the plasma reactors are used to produce hydrogen and carbon monoxide, hydrogen and carbon, or carbon monoxide through reforming and pyrolysis reactions. Preferred feedstocks include methane, carbon dioxide, and other hydrocarbons.

Disclosed is an adsorbent containing a metal oxide for adsorption of hydrogen sulfide in biogas, and a biogas purification system using the same.

Embodiments of the present disclosure are directed to a diesel reformer system comprising: a diesel autothermal reforming unit; a post-reforming unit disposed downstream of the autothermal reforming unit; a heat exchanger disposed downstream of the post-reforming unit; and a desulfurization unit disposed downstream of the heat exchanger.

A method of integrating a fuel cell with a steam methane reformer is provided. The system includes at least one fuel cell including an anode and a cathode, and a steam methane reformer including a syngas stream, and a flue gas stream. The method includes introducing at least a portion of the flue gas stream to the cathode, thereby producing a CO2 depleted flue gas stream and introducing a hydrocarbon containing stream to the anode, thereby producing an electrical energy output and a carbon dioxide and hydrogen containing stream from the fuel cell.

A system having a catalytic partial oxidation (CPO) reactor operable to produce a CPO reactor effluent characterized by a hydrogen to carbon monoxide (H.sub.2/CO) molar ratio and an M ratio (H.sub.2—CO.sub.2)/(CO+CO.sub.2); a steam methane reforming (SMR) reactor operable to produce an SMR reactor effluent characterized by a H.sub.2/CO molar ratio greater than that of the CPO reactor effluent, and an M ratio greater than that of the CPO reactor effluent. The system includes a flow line(s) configured to combine at least a portion of the CPO reactor effluent with at least a portion of the SMR reactor effluent to provide a combined syngas stream upstream or downstream of a heat exchanger operable to transfer heat from at least a portion of the CPO reactor effluent, at least a portion of the SMR reactor effluent, or the combined syngas stream to the first portion and/or the second portion of hydrocarbons.

It is provided a method of converting a carbonaceous material into syngas at a carbon conversion rate of at least 78% comprising gasifying the carbonaceous material in a fluidized bed reactor producing a crude syngas, classifying the crude syngas by particle size and density into a cut sizing device, introducing the classified particle crude syngas into a thermal reformer and reforming the classified crude syngas at a temperature above mineral melting point, producing the syngas.

In the electrochemical element, a plate-like support includes an internal passage through which a first gas flows, a gas-permeable portion, and an electrochemical reaction portion in which a film-like electrode layer, a film-like electrolyte layer, and a film-like counter electrode layer are stacked so as to entirely or partially cover the gas-permeable portion. The internal passage includes a plurality of auxiliary passages through which the first gas flows in a predetermined flowing direction, and a distribution portion provided on the upstream side of the plurality of auxiliary passages in the flowing direction of the first gas. The plate-like support includes a supply structure that is located between the distribution portion and the auxiliary passages in the flowing direction. The first gas is temporarily stored in the distribution portion and supply of the first gas from the distribution portion to the plurality of auxiliary passages is limited.

Disclosed is an absorbent containing an amine for absorption of an acid gas in a biogas, and a biogas purification system using the same.

A method for operating a blast furnace, including collecting a blast furnace gas from the blast furnace, the blast furnace gas being a CO.sub.2 containing gas, combining the blast furnace gas with a fuel gas to obtain a gas mixture, the fuel gas being a hydrocarbon containing gas, subjecting the gas mixture to a reforming process, thereby producing a synthesis gas containing CO and H.sub.2; and feeding at least a portion of the synthesis gas and an oxygen-rich gas into the blast furnace, where the blast furnace gas is combined with the fuel gas while containing substantially the same amount of CO.sub.2 as when exiting the blast furnace and wherein the blast furnace gas is combined with the fuel gas in an over-stoichiometric ratio, so that the synthesis gas contains a surplus portion of the blast furnace gas.

Disclosed is an adsorbent containing a metal oxide for adsorption of hydrogen sulfide in biogas, and a biogas purification system using the same.