The present disclosure relates to cogeneration of power and one or more chemical entities through operation of a power production cycle and treatment of a stream comprising carbon monoxide and hydrogen. A cogeneration process can include carrying out a power production cycle, providing a heated stream comprising carbon monoxide and hydrogen, cooling the heated stream comprising carbon monoxide and hydrogen against at least one stream in the power production cycle so as to provide heating to the power production cycle, and carrying out at least one purification step so as to provide a purified stream comprising predominately hydrogen. A system for cogeneration of power and one or more chemical products can include a power production unit, a syngas production unit, one or more heat exchange elements configured for exchanging heat from a syngas stream from the syngas production unit to a stream from the power production unit, and at least one purifier element configured to separate the syngas stream into a first stream comprising predominately hydrogen and a second stream.

Raw synthesis gas (syngas) compositions are provided herein. The syngas compositions are generally formed from a partial oxidation reaction with a plastic feedstock within a PDX gasifier. The raw syngas compositions may by characterized by a desirable ratio of carbon monoxide to hydrogen and/or less impurities than syngas compositions formed using other feedstocks, such as natural gas or coal.

The present disclosure provides a process for controlling syngas composition from an internal combustion engine-based syngas generator. While air is typically used as an oxidant, with nitrogen (N.sub.2) as a diluent, this results in expensive downstream compression, and low feedstock conversion efficiencies. This disclosure provides CO.sub.2 as a diluent to reduce N.sub.2 concentration in the syngas. In some embodiments, the CO.sub.2 diluent may be from either a biogas processing coupled with methanol, DME, and/or hydrocarbon production; or natural gas processing coupled with Fischer-Tropsch (FT) synthesis and/or other hydrocarbon synthesis.

A process for producing syngas that uses the syngas product from an oxygen-fired reformer to provide all necessary heating duties, which eliminates the need for a fired heater. Without the flue gas stream leaving a fired heater, all of the carbon dioxide produced by the reforming process is concentrated in the high-pressure syngas stream, allowing essentially complete carbon dioxide capture.

The invention relates to a method and to a plant for chemical looping oxidation-reduction combustion (CLC) of a gaseous hydrocarbon feed, for example natural gas essentially containing methane. According to the invention, catalytic steam reforming of the feed is performed between two successive feed combustion steps on contact with an oxidation-reduction active mass in form of particles. The reforming catalyst is arranged in a fixed bed in an intermediate reforming zone (130) between the two reduction zones (120, 140) where the two combustion steps are conducted.

A hydrocarbon stream is combusted within a reactor to produce soot and syngas. Sub-stoichiometric combustion of the hydrocarbon stream within the reactor converts at least 10% of the carbon in the hydrocarbon stream into soot. The syngas is mixed with a steam stream to produce a hydrogenation feed stream. A shift reactor converts at least a portion of the carbon monoxide and steam to carbon dioxide and hydrogen to produce a shifted gas stream. Water is separated from the shifted gas stream to produce a dehydrated gas stream. The dehydrated gas stream is separated to produce a hydrogen product stream and a recycle stream. The recycle stream is recycled to the reactor.

There are provided systems and methods for using fuel-rich partial oxidation to produce an end product from waste gases, such as flare gas. In an embodiment, the system and method use air-breathing piston engines and turbine engines for the fuel-rich partial oxidation of the flare gas to form synthesis gas, and reactors to convert the synthesis gas into the end product. In an embodiment the end product is methanol.

A process is described for the production of formaldehyde, comprising (a) subjecting methanol to oxidation with air in a formaldehyde production unit thereby producing a formaldehyde-containing stream; (b) separating said formaldehyde-containing stream into a formaldehyde product stream and a formaldehyde vent gas stream; wherein the vent gas stream, optionally after treatment in a vent gas treatment unit, is passed to one or more stages of: (i) synthesis gas generation, (ii) carbon dioxide removal, (iii) methanol synthesis or (iv) urea synthesis.

In accordance with the present invention, disclosed herein is an apparatus and method for removing CO.sub.2 from products by using a first acid gas absorber and a second acid gas absorber, which are both a part of a single acid gas removal unit.

A process for production of ammonia includes: providing a reaction stream including carbon monoxide and hydrogen; passing the reaction stream and steam over a water gas shift catalyst in a catalytic shift reactor, forming a shifted gas mixture depleted in carbon monoxide and enriched in hydrogen; passing the shifted gas mixture with an oxygen-containing gas over a selective oxidation catalyst at 175 C., forming a selectively oxidized gas stream with a portion of the carbon monoxide converted to carbon dioxide; removing some of the carbon dioxide from the selectively oxidized gas stream in a carbon dioxide removal unit; passing the carbon dioxide depleted stream over a methanation catalyst in a methanator to form a methanated gas stream, optionally adjusting its hydrogen:nitrogen molar ratio to form an ammonia synthesis gas; and passing the ammonia synthesis gas over an ammonia synthesis catalyst in an ammonia converter to form ammonia.