Disclosed is a method for the producingtiona target compoundby oxidative coupling of methane. A starting gas mixture is provided which contains an olefin, carbon monoxide, carbon dioxide and optionally hydrogen, wherein the olefin is subjected to hydroformylation with the carbon monoxide and the hydrogen of the starting mixture to obtain an aldehyde, wherein the paraffin and the olefin have a carbon chain with a first carbon number and the aldehyde has a carbon chain with a second carbon number which is greater by one than the first carbon number. The carbon dioxide present in the starting mixture is removed upstream and/or downstream of the hydroformylation. The carbon dioxide is subjected to dry reforming with methane to obtain carbon monoxide, and that the carbon monoxide subjected to hydroformylation comprises at least part of the carbon monoxide obtained in the dry reforming .

A hydrogen reforming system is provided and includes a steam reforming system, a dry reforming system, and a water supply device. The steam reforming system is configured to (i) receive a raw material gas and react the raw material gas with water to generate a first mixed gas containing hydrogen and carbon monoxide, (ii) react the first mixed gas with the water to generate hydrogen and carbon dioxide, and (iii) discharge hydrogen and carbon dioxide. The dry reforming system is configured to (i) receive and react the raw material gas and the carbon dioxide discharged from the steam reforming system to generate a second mixed gas containing hydrogen, (ii) react the second mixed gas with the water to generate hydrogen and carbon dioxide, and (iii) discharge hydrogen and carbon dioxide. The water supply device is configured to supply the water to the steam reforming system and the dry reforming system.

A process and system for generating hydrogen gas are described, in which water is electrolyzed to generate hydrogen and oxygen, and a feedstock including oxygenate(s) and/or hydrocarbon(s), is non-autothermally catalytically oxidatively reformed with oxygen to generate hydrogen. The hydrogen generation system in a specific implementation includes an electrolyzer arranged to receive water and to generate hydrogen and oxygen therefrom, and a non-autothermal segmented adiabatic reactor containing non-autothermal oxidative reforming catalyst, arranged to receive the feedstock, water, and electrolyzer-generated oxygen, for non-autothermal catalytic oxidative reforming reaction to produce hydrogen. The hydrogen generation process and system are particularly advantageous for using bioethanol to produce green hydrogen.

Methods and systems for gas separation of syngas applying differences in water solubilities of syngas components, the method including producing a product gas comprising hydrogen and carbon dioxide from a hydrocarbon fuel source; separating hydrogen from the product gas to create a hydrogen product stream and a byproduct stream by solubilizing components in water that are more soluble in water than hydrogen; injecting the byproduct stream into a reservoir containing mafic rock; and allowing components of the byproduct stream to react in situ with components of the mafic rock to precipitate and store components of the byproduct stream in the reservoir.

A system for producing CO and CO.sub.2 to achieve an efficient oil recovery operation having de minimis undesirable gaseous emissions is provided. The system includes a portable CO producing device and a portable CO.sub.2 producing device located proximate to the reservoir and a gas collecting device configured to receive CO and CO.sub.2 and selectively distribute a desired ratio of CO and CO.sub.2 dynamically based on current reservoir conditions. Producing CO.sub.2 proximate to the reservoir comprises reforming carbon based fuel within oxygen. Electrical energy generated is used to selectively distribute the desired ratio of CO/CO.sub.2 to the reservoir with de minimis greenhouse gases produced transmitted into the atmosphere. The system is an energy efficient arrangement that recycles and reuses by-products and unused products from the process. Greenhouse gas emissions are significantly reduced compared to conventional processes by-products are fully utilized. Hydrogen produced can be used to generate electricity, as can heat generated from other sources within the process.

Provided herein are systems and methods for controlling production of low-carbon liquid fuels and chemicals. In an aspect, provided herein is a method controlling a process that produces e-fuels. In another aspect, provided herein is a system for producing an e-fuel.

An integrated process for the production of a useful liquid hydrocarbon product comprises: feeding a gasification zone with an oxygen-containing feed and a first carbonaceous feedstock comprising waste materials and/or biomass, gasifying the first carbonaceous feedstock in the gasification zone to produce first synthesis gas, partially oxidising the first synthesis gas in a partial oxidation zone to generate partially oxidised synthesis gas, combining at least a portion of the first synthesis gas and/or the partially oxidised synthesis gas and at least a portion of electrolysis hydrogen obtained from an electrolyser in an amount to achieve the desired hydrogen to carbon monoxide molar ratio of from about 1.5:1 to about 2.5:1, and to generate a blended synthesis gas, wherein the electrolyser operates using green electricity; and subjecting at least a portion of the blended synthesis gas to a conversion process effective to produce the liquid hydrocarbon product.

A novel process for synthesis gas generation comprises treating a hydrocarbon feed in a primary reformer (PR), compressing at least part of the flue gas from the primary reformer in a compressor (C1), and feeding the compressed flue gas to a secondary reformer (SR) together with the primary reformer effluent. In the process, enriched air (EA) is added either to the primary reformer, to the secondary reformer or both. The process is especially suited for co-production of ammonia and methanol or for production of either ammonia or methanol. The total CO.sub.2 emission is lowered considerably by using the process of the invention.

In a process for treating wastewater from a combined gasification and Fischer-Tropsch (F-T) process, feedstock derived from Municipal Solid Waste or the like is gasified in a reactor (R) and treated in a cleanup unit (C) which generates a first wastewater stream (1st WWT STREAM) containing salts and inorganic pollutants. The first wastewater stream is treated in a treatment unit (T1) to remove inorganic pollutants derived from the syngas The treatment comprises a) degassing, and subsequently b) neutralising the first wastewater stream before treatment in a Dissolved Air Flotation unit (72c) and filtering in a moving sand bed or similar (72d) to remove solids, and a stripping process to remove ammonia. A second wastewater stream (2.sup.nd WWT Stream) containing organic pollutants but being low in salts arises from the F-T process and is treated separately to allow recycling within the F-T process.

The present invention describes a process for steam reforming natural gas, comprising a steam reforming exchanger-reactor (3000), a reactor for converting CO to CO.sub.2 (3100), and a PSA hydrogen purification unit (4300), with a view to producing a synthesis gas in which the heat necessary for the steam reforming reaction is supplied by a first combustion chamber (3100) connected to a second combustion chamber (3200) generating fumes in order to produce a very high degree of thermal integration.