A process for separating two gaseous streams, including purifying a first gaseous stream in a first acid gas removal absorber, purifying in a first temperature swing adsorption unit, and then separating at a cryogenic temperature in a separation unit to produce a stream of fluid enriched in carbon monoxide and a stream of fluid enriched in hydrogen, sending a second gaseous stream containing at least carbon monoxide, hydrogen and at least one acid gas to a shift reaction unit, the shifted second stream is purified in a second acid gas removal absorber to remove carbon dioxide and the purified second stream is sent as a feed stream to a pressure swing adsorption unit to produce a hydrogen enriched stream, and sending at least part of the stream enriched in hydrogen from the separation unit as a feed stream to the pressure swing adsorption unit to produce the hydrogen-enriched stream.

Disclosed are methods for accommodating changes in the conditions of partial oxidation of hydrocarbonaceous feedstock by changing characteristics of the hot oxygen used in the partial oxidation.

Disclosed is methodology for controlling the H2:CO ratio of the product produced in a partial oxidation reactor, by adjusting the properties of the product formed in the partial oxidation.

Disclosed is methodology for controlling the H2:CO ratio of the product produced in a partial oxidation reactor, by carrying out the partial oxidation under temperature conditions that produce less than maximum conversion.

Hydrogen purification devices and their components are disclosed. In some embodiments, the devices may include at least one foil-microscreen assembly disposed between and secured to first and second end frames. The at least one foil-microscreen assembly may include at least one hydrogen-selective membrane and at least one microscreen structure including a non-porous planar sheet having a plurality of apertures forming a plurality of fluid passages. The planar sheet may include generally opposed planar surfaces configured to provide support to the permeate side. The plurality of fluid passages may extend between the opposed surfaces. The at least one hydrogen-selective membrane may be metallurgically bonded to the at least one microscreen structure.

A solids discharge system (SDS) is configured to separate solids from product gas. The system includes a solids separation device and at least one solids transfer conduit configured to receive solids from the solids separation device. The solids transfer conduit is selectively partitioned into a plurality of compartments (or “sections”) along its length by isolation valves. A gas supply conduit and a gas discharge conduits are connected to one of the sections to facilitate removal of solids. A filter in fluid communication with that section is configured to prevent solids from passing through the gas discharge conduit so that the solids can be removed from one of the sections of the solids transfer conduit. A product gas generation system incorporates first and second reactors, the latter of which receives products created by the second reactor.

A system and method for producing hydrogen, including providing hydrocarbon and steam into a vessel to a region external to a tubular membrane in the vessel. The method includes steam reforming the hydrocarbon in the vessel via reforming catalyst to generate hydrogen and carbon dioxide. The method includes diffusing the hydrogen through the tubular membrane into a bore of the tubular membrane, wherein the tubular membrane is hydrogen selective.

A system and method of producing hydrogen, including converting hydrocarbon to methane via steam and pre-reforming catalyst in a pre-reformer, converting the methane to hydrogen and carbon dioxide by steam reforming via a reforming catalyst in a membrane reformer, diffusing through hydrogen through a tubular membrane in the membrane reformer.

A system and method for producing hydrogen from hydrocarbon and steam, including a membrane reformer with multiple membrane reactors each having a tubular membrane. The bore of the tubular membrane is the permeate side for the hydrogen. The region external to the tubular membrane is the retentate side for carbon dioxide. A sweep gas flows through the bore to displace hydrogen in a direction countercurrent to flow of hydrocarbon and steam in the region external to the tubular membrane. The method includes discharging hydrogen as permeate with the sweep gas from the bore, and discharging carbon dioxide in the region external to the tubular membrane as retentate from the membrane reactor.

The present invention provides a process for producing one or more products for use as a transportation or heating fuel. In various embodiments the process comprises treating a cellulosic feedstock in one or more processing steps that release extractives from the feedstock. A solids-liquid separation is subsequently conducted on the process stream comprising the extractives and solids. An aqueous stream comprising one or more of the extractives may be fed to an anaerobic digester to produce crude biogas from which one or more impurities may optionally be removed. In various embodiments the process further comprises providing a solids stream to a thermal process. A product produced or derived from the thermal process may displace a product made from fossil fuel. One or more products obtained or derived from at least one of the foregoing process steps are provided for use as a transportation or heating fuel. In various embodiments the process enables advantaged fuel credit generation.