Patent classifications
C01B2203/042
Processing facility to produce hydrogen and petrochemicals
A processing facility is provided that includes a feedstock separation system configured to separate a feed stream into a lights stream and a heavies stream, a hydrogen production system configured to produce hydrogen and carbon dioxide from the lights stream, and a carbon dioxide conversion system configured to produce synthetic hydrocarbons or the carbon dioxide. The processing facility also includes a hydroprocessing system configured to process the heavies stream, and a hydroprocessor separation system configured to separate a hydroprocessing system effluent into a separator tops stream and a separator bottoms stream, wherein the separator bottoms stream is fed to the hydrogen production system.
Hydrogen production with membrane reformer
A system and method of producing hydrogen, including converting hydrocarbon to methane via steam and pre-reforming catalyst in a pre-reformer, converting the methane to hydrogen and carbon dioxide by steam reforming via a reforming catalyst in a membrane reformer, diffusing through hydrogen through a tubular membrane in the membrane reformer.
Hydrogen reforming system
A hydrogen reforming system includes: a reformer that generates first mixed gas through a reforming reaction between fuel gas and water; a transformer that is fed with the first mixed gas and generates second mixed gas from which carbon monoxide is removed by a water gas shift reaction; a pressure swing adsorption that purifies and separate hydrogen from the second mixed gas generated in the transformer; a heat exchanger that is provided between the reformer and the transformer and between the transformer and the PSA unit to control temperatures of the first mixed gas and the second mixed gas through heat exchange with water; a water feeder that communicates with the heat exchanger and supplies water to the heat exchanger; and a control value that is provided on a line through which water is discharged from the water feeder and adjusts a flow rate of water.
PRODUCTION OF AMMONIA, METHANOL, AND SYNTHESIS PRODUCTS FROM ONE OR MORE GASIFICATION PRODUCTS
Ammonia, methanol, Fischer Tropsch products, and derivatives thereof are made by using hydrogen and oxygen supplied from an electrolyzer that is at least partially powered by renewable power, resulting in green process and systems that produce green products disclosed herein. A process using biomass and renewable energy includes producing an unshifted syngas from biomass and oxygen in a gasification unit, introducing water into an electrolyzer to produce an oxygen product and a hydrogen product, and introducing the oxygen product to the gasification unit. The electrolyzer is powered by renewable energy, and the oxygen product supplies at least a portion of the oxygen to the gasification unit.
LNG REFORMER SYSTEM
LNG reformer system may include a reformer configured for reforming raw material gas including LNG gas and water vapor into hydrogen through a catalytic reaction thereof; a hydrogen PSA extracting the hydrogen in reformed gas produced in the reformer; a CO2 PSA fluidically connected to the hydrogen PSA and configured for extracting carbon dioxide in off-gas discharged from the hydrogen PSA; a first heat exchanger fluidically connected to the CO2 PSA and configured for cooling a fluid including carbon dioxide extracted in the CO.sub.2 PSA by LNG supplied from an LNG tank toward the reformer; a CO2 separator fluidically connected to the first heat exchanger and configured for separating the carbon dioxide from a fluid that passed through the first heat exchanger, the fluid including carbon dioxide; and a CO2 tank fluidically connected to the CO2 separator and storing the carbon dioxide separated in the CO2 separator.
Hydrogen purification device and hydrogen purification method
Provided are a hydrogen purification device and a hydrogen purification method whereby hydrogen having a high purity can be purified at a high yield from a starting gas. The hydrogen purification device comprises: a starting gas source that supplies a starting gas, said starting gas containing hydrogen molecules and/or a hydride, to a discharge space; a plasma reactor that defines at least a part of the discharge space; a hydrogen flow channel that is connected to the discharge space; and leads out purified hydrogen from the starting gas source; a hydrogen separation membrane that partitions the discharge space from the hydrogen flow channel defines at least a part of the discharge space by one surface thereof and defines at least a part of the hydrogen flow channel by the other surface thereof; an electrode that is positioned outside the discharge space; and an adsorbent that is filled in the discharge space and adsorbs the starting gas. In the hydrogen purification method according to the present invention, the starting gas is adsorbed by the adsorbent in the discharge space. Hydrogen molecules, which have been desorbed from the adsorbent by discharge, are allowed to penetrate through the hydrogen separation membrane 4 and led out into the hydrogen flow channel.
Absorber column and process for cleaning crude synthesis gas
The invention relates to an absorber column and to the use thereof for separation of unwanted, especially acidic, gas constituents, for example carbon dioxide and hydrogen sulfide, from a crude synthesis gas by absorption with an absorbent, especially under low load states of the absorber column in relation to the synthesis gas velocity. According to the invention, a defined concentration of carbon dioxide in the clean synthesis gas is established by mixing at least a portion of the absorbent regenerated by flash regeneration with the absorbent regenerated by means of hot regeneration prior to the recycling thereof into the absorber column.
PRODUCTION OF LOW OR NO CARBON INTENSITY HYDROGEN
A process for producing low or no carbon intensity hydrogen. In one embodiment, the process includes the step of pretreating a hydrocarbon gas stream. The pretreated hydrocarbon gas stream is fed into a reformer. The pretreated hydrocarbon gas steam is heated in the reformer to produce a synthesis gas stream and a flue gas stream. The flue gas stream is fed to a waste heat recovery section. Waste heat is recovered to increase the thermal efficiency of the process. The synthesis gas stream is fed to a shift gas reactor. Carbon monoxide from the synthesis gas stream in the shift gas reactor is converted to produce hydrogen and carbon dioxide. The carbon dioxide is separated from the synthesis gas stream and the hydrogen is separated. In another embodiment, the carbon dioxide is captured following the hydrogen separation. In another embodiment, the carbon dioxide is captured from the flue gas.
Method for increasing efficiency and reducing emissions in a steam reforming plant
A method for decreasing the SFFC of a steam reforming plant, including establishing a base operating mode. Then modifying the base operating mode by introducing the shift gas stream into a solvent based, non-cryogenic separator prior to introduction into the pressure swing adsorption and introducing the compressed hydrogen depleted off-gas stream in a membrane separation unit, wherein the membrane is configured to produce the hydrogen enriched permeate stream at a suitable pressure to allow the hydrogen enriched permeate stream to be combined with carbon dioxide lean shift gas stream, prior to introduction into the pressure swing adsorption unit without requiring additional compression. Thereby establishing a modified operating mode. Wherein said pressure swing adsorption unit has a modified overall hydrogen recovery. Wherein said modified operating mode has a modified hydrogen production, a modified hydrogen production unit firing duty, a modified SCO2e, and a modified SFFC.
Method for increasing efficiency and reducing emissions in a steam reforming plant
A method for decreasing the SFFC of a steam reforming plant, including establishing a base operating mode. Then modifying the base operating mode by introducing the shift gas stream into a solvent based, non-cryogenic separator prior to introduction into the pressure swing adsorption and introducing the compressed hydrogen depleted off-gas stream in a membrane separation unit, wherein the membrane is configured to produce the hydrogen enriched permeate stream at a suitable pressure to allow the hydrogen enriched permeate stream to be combined with carbon dioxide lean shift gas stream, prior to introduction into the pressure swing adsorption unit without requiring additional compression. Thereby establishing a modified operating mode. Wherein said pressure swing adsorption unit has a modified overall hydrogen recovery. Wherein said modified operating mode has a modified hydrogen production, a modified hydrogen production unit firing duty, a modified SCO2e, and a modified SFFC.