The invention relates to a process for preparing hydrogen by reforming hydrocarbons with steam, and for separation of carbon dioxide. The process includes one endothermic and one autothermal reforming step for production of a synthesis gas stream, wherein heat generated in the autothermal reforming step is utilized for heating in the endothermic reforming step. The process also includes a step of converting the synthesis gas stream obtained for enrichment with hydrogen, a step of separating the hydrogen thus prepared by pressure swing adsorption, and a step of separation of carbon dioxide from the residual gas obtained in the pressure swing adsorption. The reforming units for the endothermal and autothermal reforming steps are arranged parallel to one another or in series.

A process of hydrogen production comprising the steps of: subjecting a gaseous mixture comprising a hydrocarbon and steam, and having a steam to carbon ratio of at least 0.9:1, to adiabatic pre-reforming in a pre-reformer followed by autothermal reforming with an oxygen-rich gas in an autothermal reformer to generate a reformed gas mixture, optionally adding steam to the reformed gas mixture, increasing the hydrogen content of the reformed gas mixture by subjecting it to one or more water-gas shift stages in a water-gas shift unit to provide a hydrogen-enriched reformed gas, cooling the hydrogen-enriched reformed gas and separating condensed water therefrom, passing the resulting de-watered hydrogen-enriched reformed gas to a carbon dioxide separation unit to provide a carbon dioxide gas stream and a crude hydrogen gas stream, passing the crude hydrogen gas stream to a purification unit to provide a purified hydrogen gas and a fuel gas.

The invention is directed to a process for the preparation of a syngas comprising hydrogen and carbon monoxide from a methane comprising gas, which process comprises the steps of: (a) reacting the methane comprising gas with an oxidising gas in an autothermal reformer to obtain a hot raw syngas comprising carbon monoxide and hydrogen; (b) cooling the hot raw syngas resulting from step (a) to obtain the syngas, wherein step (b) comprises cooling the hot raw syngas by indirect heat exchange against the methane comprising gas used in step (a) and wherein sulphur is added upstream of cooling step (b). The invention also relates to a process for the preparation of hydrocarbon products in which a feed syngas is prepared in the process as described above followed by a desulphurisation treatment and the desulphurised syngas is subsequently converted into hydrocarbon products in a Fischer-Tropsch process.

Offshore systems and methods may be configured for offshore power generation and carbon dioxide injection for enhanced gas recovery for gas reservoirs. For example, a method may include: providing an offshore facility including a gas turbine, and a gas separator; producing a produced gas from a gas reservoir to the offshore facility; combusting the produced gas in a gas turbine to produce power and a flue gas; at least partially removing nitrogen from the flue gas in a gas separator to produce a carbon dioxide-enriched flue gas and a nitrogen-enriched flue gas; compressing the carbon dioxide-enriched flue gas in a gas compressor to produce a compressed gas; and injecting the compressed gas from the gas compressor into the gas reservoir, wherein 80 mol % or more of hydrocarbon in the produced gas is combusted and/or injected into the gas reservoir.

The present invention is to provide a method for refining hydrogen with a hydrogen refining device in which the inside of a cell is divided into a primary side space and a secondary side space by palladium alloy capillaries each having one end being closed and a tube sheet supporting the open end of the palladium alloy capillaries, in which impurity-containing hydrogen is introduced from the primary side space to allow hydrogen to permeate the palladium alloy capillaries so as to collect pure hydrogen from the secondary side space. The method for refining hydrogen has a capability of decreasing the removed amount of gas containing impurities and efficiently collecting pure hydrogen from the secondary side space. From hydrogen with 1000 ppm or less of impurities as raw material hydrogen, gas containing impurities that does not penetrate the palladium alloy capillaries is removed from the primary side space at the flow rate of 10% or less of the introduction flow rate of the raw material hydrogen. Furthermore, gas containing impurities that does not penetrate the palladium alloy capillaries is removed from the primary side space at a flow rate based on the content of impurities contained in raw material hydrogen.

The present invention provides for a pressure swing adsorption (PSA) process for the substantial removal of H.sub.2O and CO.sub.2 from a synthesis gas to obtain a multicomponent product gas substantially free of H.sub.2O and CO.sub.2 with high recovery of the product gas. Further, the present invention provides an integrated process that achieves sufficiently high H.sub.2 and CO recoveries such that compression and recycling of the syngas purification PSA tailgas is not necessary to be economically advantageous compared to the conventional processes.

A process and system for treating a hydroprocessing unit effluent gas stream for recycling includes introducing the effluent gas stream into a hydrogen purification zone and recovering a hydrogen-rich gas stream and a liquid stream containing a mixture that includes C1 to C4 hydrocarbons and H.sub.2S which is then mixed with an oxidant and fed to an oxidation unit containing catalyst for conversion of the H.sub.2S to elemental sulfur vapors that is separated for recovery of the elemental sulfur, and recovering a sweetened mixture that includes C1 to C4 hydrocarbons. Alternatively, the hydroprocessing unit effluent gas stream containing H.sub.2S is cooled, contacted with a solvent to absorb the C1 to C4 hydrocarbons and H.sub.2S, with the hydrogen-rich stream being recovered for recycling to the hydroprocessing unit, and the rich liquid solvent being flashed to produce a lean solvent stream for recycling to the adsorption zone and a mixed gas stream that includes the C1 to C4 hydrocarbons and H.sub.2S that is passed to an oxidation zone and is reacted with an oxidant in the presence of a catalyst to complete the process as described above for the recovery of elemental sulfur and a mixture that includes the sweetened C1 to C4 hydrocarbons.

Generation of bubbles in an organic-substance production apparatus is suppressed. A gas treatment method including: an adsorption step of passing a source gas containing at least carbon dioxide and nitrogen through an adsorption unit housing an adsorbent for adsorbing carbon dioxide to reduce a carbon dioxide concentration in the source gas; a supply step of supplying the source gas whose carbon dioxide concentration has been reduced by the adsorption step to an organic-substance production apparatus that produces an organic substance; and a monitoring step of monitoring a carbon dioxide concentration and a nitrogen concentration in the source gas before passing through the adsorption unit, a carbon dioxide concentration and a nitrogen concentration in the source gas after having passed through the adsorption unit, or a carbon dioxide concentration and a nitrogen concentration in the source gas having been supplied to the organic-substance production apparatus; wherein the adsorption step has an ability regulation step of enhancing an ability of the adsorption unit to reduce a carbon dioxide concentration in the source gas, when a total concentration of the carbon dioxide concentration and the nitrogen concentration monitored in the monitoring step exceeds a threshold value.

The invention relates to a process for preparing hydrogen by reforming hydrocarbons with steam, and for separation of carbon dioxide. The process includes one endothermic and one autothermal reforming step for production of a synthesis gas stream, wherein heat generated in the autothermal reforming step is utilized for heating in the endothermic reforming step. The process also includes a step of converting the synthesis gas stream obtained for enrichment with hydrogen, a step of separating the hydrogen thus prepared by pressure swing adsorption, and a step of separation of carbon dioxide from the residual gas obtained in the pressure swing adsorption. The reforming units for the endothermal and autothermal reforming steps are arranged parallel to one another or in series.

A process and a plant for the continuous conversion of a hydrocarbonaceous feed gas into a synthesis gas comprising carbon monoxide and hydrogen, wherein the H.sub.2/CO molar ratio of the product gases can be varied within a wide range. This is achieved in that at least a part of a methane-rich gas obtained during the fractionation of the raw synthesis gas is admixed to the feed gas mixture, and that in the alternative at least a part of the H.sub.2 product gas and/or a fraction of a hydrogen-rich gas increased with respect to the normal operation of the process is admixed to the heating gas mixture, in order to lower the H.sub.2/CO ratio, or at least a part of the CO product gas and/or a fraction of a carbon monoxide-rich gas increased with respect to the normal operation of the process is admixed to the heating gas mixture, in order to increase the H.sub.2/CO ratio.