A method for ammonia decomposition is disclosed. The method may comprise providing a catalyst comprising an alumina support and a layer adjacent to the support. The layer comprises a perovskite phase comprising aluminum, cerium, and lanthanum, an oxide of at least one of an alkali metal and a rare earth metal, and an active metal. The method may comprise bringing the catalyst in contact with ammonia at a temperature of from about 400 C. to 700 C. to generate a reformate stream comprising hydrogen and nitrogen at an ammonia conversion efficiency of at least about 70%. The method may further comprise directing the hydrogen to a fuel cell to generate electricity. The method may further comprise generating heat for a reformer comprising the catalyst by combustion of gases or by electricity generated from hydrogen.

A system and method for processing unconditioned syngas first removes solids and semi-volatile organic compounds (SVOC), then removes volatile organic compounds (VOC), and then removes at least one sulfur containing compound from the syngas. Additional processing may be performed depending on such factors as the source of syngas being processed, the products, byproducts and intermediate products desired to be formed, captured or recycled and environmental considerations.

The present disclosure provides natural gas and petrochemical processing systems including oxidative coupling of methane reactor systems that integrate process inputs and outputs to cooperatively utilize different inputs and outputs of the various systems in the production of higher hydrocarbons from natural gas and other hydrocarbon feedstocks.

Embodiments of the invention are directed to methods, processes, and systems for safely and reliably purifying hydrogen from a gas mixture containing hydrogen and oxygen.

A CO shift catalyst according to the present invention reforms carbon monoxide (CO) in gas. The CO shift catalyst has one of molybdenum (Mo) or iron (Fe) as a main component and has an active ingredient having one of nickel (Ni) or ruthenium (Ru) as an accessory component and one or two or more kinds of oxides from among titanium (Ti), zirconium (Zr), and cerium (Ce) for supporting the active ingredient as a support. The temperature at the time of manufacturing and firing the catalyst is equal to or higher than 550 C.

A membrane unit is able to recover hydrogen from a resid waste gas stream. Two membrane units provide even greater hydrogen recovery. The membrane separation is performed at conditions that allow the pressure of the recovered hydrogen to enter into a second stage of compression, saving the expense of the first stage of compression.

A pressure swing adsorption process is provided to remove oxygen from a hydrogen stream through the use of a copper material in combination with layers of adsorbent to remove water, C2 and C3 hydrocarbons, as well as other impurities. The feed gas comprises more than 70 mol % hydrogen, at least 1 mol % methane and more than 10 ppmv oxygen. The purified product hydrogen stream comprises greater than 99 mol % hydrogen, with less than 1 ppmv oxygen.

Synthesis gas containing nitrogen as the majority component is processed to increase the hydrogen to carbon dioxide ratio. Nitrogen, carbon dioxide, and other contaminants are subsequently removed by a purification unit to produce a purified hydrogen gas stream. A recycle stream within the purification unit helps achieve a hydrogen purity greater than 99.9 percent, and hydrogen recovery greater than 99 percent.

The present invention relates to a process for processing a gas mixture comprising methane, carbon dioxide, carbon monoxide, hydrogen, nitrogen, argon and traces of olefins and oxygenates. Methane, carbon dioxide and carbon monoxide, and optionally hydrogen, can be recovered from the gas mixture in a very efficient way.

A separator system for treating a gas from a biomass gasification system, including: first and second cyclones, where the first cyclone includes an inlet for receiving a gas from a biomass gasification unit, the first cyclone being arranged for removing particulate matter from the gas from the biomass gasification unit in order to provide a first cleaner gas, piping arranged to lead the first cleaner gas to the second cyclone, where the second cyclone is arranged to remove particulate matter from the first cleaner gas in order to provide a second cleaner gas, a pipe arranged to lead the second cleaner gas to a special piping element, the latter including a burner, thereby providing a third cleaned gas, and a gas distribution unit arranged to lead the third cleaned gas to one or more tar reformer units. Also, a method of treating a gas from a biomass gasification system.