A corrosion resistant refractory ceramic hexagonal target tile body for use covering a catalyst, including a generally flat hexagonal portion and a plurality of generally right circular cylindrical aperture portions extending therethrough, wherein the hexagonal tile body has a thickness of about 89 mm and a width of about 42 cm and is 13 percent yttria fully stabilized YSZ. Each respective aperture has a diameter of about 19 mm.

An apparatus for steam reforming of hydrocarbons is described including a steam reformer containing a plurality of externally-heated vertical tubes each tube having an inlet for a feed gas mixture including hydrocarbon and steam, and an outlet for a reformed gas mixture, wherein the tubes contain a particulate steam reforming catalyst adjacent the outlet and a structured steam reforming catalyst adjacent the inlet. A process for steam reforming of hydrocarbons using the apparatus is also described.

A reactor configured to release hydrogen from a hydrogen-bearing, liquid compound, having a reactor vessel which comprises at least one body with metallic support structure. A solid, highly porous coating is applied on said at least one body which comprises catalytically acting substances for the release of hydrogen from the liquid, hydrogen-bearing compound, wherein the at least one body with metallic support structure comprises at least one cutout with a volume that remains the same or becomes larger from along a cross-sectional dimension extending from bottom to top, based on the reactor vessel.

The present invention relates to reactor tubes packed with a catalyst system employed to deliberately bias process gas flow toward the hot tube segment and away from the cold segment in order to reduce the circumferential tube temperature variation.

A generally spherical high strength ceramic body for use in an ATR and/or SR unit covering a catalyst media bed. The ceramic body is a fully stabilized YSZ composite composition having at least about 13% yttria YSZ, and more typically from about 12% to about 20% yttria YSZ, with a porosity of less than 20 percent and a diameter of at least 25 mm and, more typically, selected from the group comprising 25 mm, 50 mm, 76 mm and 100 mm.

A corrosion resistant refractory ceramic hexagonal target tile body for use covering a catalyst, including a generally flat hexagonal portion and a plurality of generally right circular cylindrical aperture portions extending therethrough, wherein the hexagonal tile body has a thickness of about 89 mm and a width of about 42 cm and is 13 percent yttria fully stabilized YSZ. Each respective aperture has a diameter of about 19 mm.

An apparatus and method for producing hydrocarbons including aromatic hydrocarbons and lower olefins including propylene from CH.sub.4 and CO.sub.2 through CO and H.sub.2 with high activity and high selectivity. The apparatus is provided with: a synthetic gas production unit to which a gas containing CH.sub.4 and CO.sub.2 is supplied from a first supply unit, and which generates a synthetic gas containing CO and H.sub.2 while heating a first catalyst structure; a production unit to which the synthetic gas is supplied and which generates hydrocarbons including aromatic hydrocarbons having 6-10 carbon atoms and lower olefins including propylene while heating a second catalyst structure; and a detection unit which detects propylene and the aromatic hydrocarbons discharged from the production unit, in which the first catalyst structure includes first supports having a porous structure and a first metal fine particle in the first supports, the first supports have a first channels, the first metal fine particle is present in the first channels, the second catalyst structure includes second supports having a porous structure and a second metal fine particle in the second supports, the second supports have a second channels, and a portion of the second channels have an average inner diameter of 0.95 nm or less.

Provided is a process for producing synthesis gas with minimized emissions of ammonia. The process includes converting hydrocarbon containing feed stream in reformer tubes (104A-N) and discharging a crude synthesis gas stream and a flue gas stream, routing the flue gas stream through a catalyst unit (112), cooling the crude synthesis gas stream to form an aqueous condensate stream comprising ammonia, tripping the aqueous condensate stream comprising ammonia with a stripping gas stream, routing out a condensate stream depleted in ammonia and a stripping gas stream enriched in ammonia, introducing the stripping gas stream enriched in ammonia into a flue gas duct (110), where both the at least a portion of the flue gas stream and the at least a portion of the stripping gas stream enriched in ammonia pass through a first catalyst zone (114) and subsequently through a second catalyst zone (116) of the catalyst unit (112).

A hydrogen mixed gas generation method using a device that includes a heating pipe housing therein a reduction acceleration member and a heating part including a heating device that heats the heating pipe includes a first process and a second process. The first process includes: causing raw water to flow into the heating pipe and heating the flowing raw water to generate water vapor; heating the generated water vapor to between 500? C. to 800? C.; causing the heated water vapor to be in contact with the reduction acceleration member that is heated along with the raw water to reduce the water vapor and generate hydrogen gas. The second process includes: diluting the hydrogen gas generated in the first process to obtain hydrogen mixed gas whose concentration of hydrogen gas is between 500 ppm to 20000 ppm.

A liquid fuel reformer includes a fuel vaporizer which utilizes heat from an upstream source of heat, specifically, an electric heater, operable in the start-up mode of the reformer, and therefore independent of the reforming reaction zone of the reformer, to vaporize fuel in a downstream vaporization zone.