In various aspects, systems and methods are provided for integration of molten carbonate fuel cells with a Fischer-Tropsch synthesis process. The molten carbonate fuel cells can be integrated with a Fischer-Tropsch synthesis process in various manners, including providing synthesis gas for use in producing hydrocarbonaceous carbons. Additionally, integration of molten carbonate fuel cells with a Fischer-Tropsch synthesis process can facilitate further processing of vent streams or secondary product streams generated during the synthesis process.

The present invention relates to a process for processing a gas mixture comprising methane, carbon dioxide, carbon monoxide, hydrogen, nitrogen, argon and traces of olefins and oxygenates. Methane, carbon dioxide and carbon monoxide, and optionally hydrogen, can be recovered from the gas mixture in a very efficient way.

The invention relates to a process for the production of liquid hydrocarbons by Fischer-Tropsch synthesis in which the reforming section of the plant comprises a process line comprising autothermal reforming (ATR) (5) or catalytic partial oxidation (CPO), and a separate process line comprising steam methane reforming (SMR) (8).

A method for preparing hydrogen gas includes a decomposition step, a first adsorption step, a second adsorption step, a first regeneration step, a third heat-exchange step, and a second regeneration step.

Systems and methods are provided for capturing CO.sub.2 from a combustion source using molten carbonate fuel cells (MCFCs). At least a portion of the anode exhaust can be recycled for use as part of anode input stream. This can allow for a reduction in the amount of fuel cell area required for separating CO.sub.2 from the combustion source exhaust and/or modifications in how the fuel cells can be operated.

The present invention relates, in general, to systems and methods for generating hydrogen from ammonia on-board vehicles, where the produced hydrogen is used as fuel source for an internal combustion engine. The present invention utilizes an electric catalyst unit operating in series with a heat exchange catalyst unit. The electric catalyst unit is used to initiate an ammonia cracking process on-board during a cold start or low load operating condition of the internal combustion engine, where the ammonia cracking process occurs in the heat exchange catalyst unit once exhaust gas from the internal combustion engine has been heated to a threshold temperature suitable to perform the ammonia cracking process.

The present invention relates, in general, to systems and methods for generating hydrogen from ammonia on-board vehicles, where the produced hydrogen is used as fuel source for an internal combustion engine along with ammonia. The present invention utilizes ammonia not only as a co-fuel for the engine, but also as a heat-exchange medium used by a cooling system for the internal combustion engine, such that the heat is transferred from hot engine coolant to the ammonia, thereby cooling the engine coolant, and also pre-heating the ammonia.

An embodiment described herein provides a method of treating a gas stream, where the method includes: flowing the gas stream containing H.sub.2S and CO.sub.2 into a plasma reactor; igniting a plasma in the plasma reactor containing the gas stream; decomposing the H.sub.2S to generate H.sub.2 and elemental sulfur in the plasma generating a product gas stream; condensing the elemental sulfur from the product gas stream as a liquid; and separating the H.sub.2 from the product gas stream.

The present invention relates, in general, to systems and methods for generating hydrogen from ammonia on-board vehicles, where the produced hydrogen is used as fuel source for an internal combustion engine along with ammonia. The present invention utilizes ammonia not only as a co-fuel for the engine, but also as a heat-exchange medium used by a cooling system that supplements radiator cooling along with air intake louvers that are adjusted based on the temperature of the internal combustion engine.

The invention concerns a process and apparatus for cracking ammonia in which heated ammonia gas at super-atmospheric pressure is partially cracked in at least two adiabatic reactors in series with interstage heating in which the feed temperature to a first reactor is higher than the feed temperature to a further reactor to produce a partially cracked ammonia gas which is then fed to catalyst-containing reactor tubes in a furnace to produce a cracked gas comprising hydrogen gas, nitrogen gas and residual ammonia gas. The use of the adiabatic reactors enables more efficient heat integration within the process and the higher temperature in the first reactor enables the use of a nickel-based catalyst in that reactor as an alternative solution to the potential problem of the presence of oil in the ammonia.