Disclosed is an adsorbent containing a metal oxide for adsorption of hydrogen sulfide in biogas, and a biogas purification system using the same.

A method and apparatus for reforming carbonaceous material into syngas containing hydrogen and CO gases is disclosed. In one embodiment, a hydrogen rich torch reactor is provided for defining a reaction zone proximate to torch flame. One input of the reactor receives input material to be processed. Further inputs may be provided, such as for example to introduce steam and/or gases such as methane, oxygen, hydrogen, or the like.

There are provided systems and methods for using fuel-rich partial oxidation to produce an end product from waste gases, such as flare gas. In an embodiment, the system and method use air-breathing piston engines and turbine engines for the fuel-rich partial oxidation of the flare gas to form synthesis gas, and reactors to convert the synthesis gas into the end product. In an embodiment the end product is methanol.

There are provided systems and methods for using fuel-rich partial oxidation to produce an end product from waste gases, such as flare gas. In an embodiment, the system and method use air-breathing piston engines and turbine engines for the fuel-rich partial oxidation of the flare gas to form synthesis gas, and reactors to convert the synthesis gas into the end product. In an embodiment the end product is methanol.

There are provided systems and methods for using fuel-rich partial oxidation to produce an end product from waste gases, such as flare gas. In an embodiment, the system and method use air-breathing piston engines and turbine engines for the fuel-rich partial oxidation of the flare gas to form synthesis gas, and reactors to convert the synthesis gas into the end product. In an embodiment the end product is methanol.

A steam methane reformer-integrated fuel cell system includes: at least one fuel cell including: an anode, a cathode, and an electrolyte matrix separating the anode and the cathode; an anode gas oxidizer (AGO) configured to receive anode exhaust gas from the at least one fuel cell and a preheated air stream such that the anode exhaust gas reacts with the preheated air stream to produce a high-temperature exhaust stream, and configured to provide the high-temperature exhaust stream to the cathode of the at least one fuel cell; and a steam methane reformer configured to utilize heat from the high-temperature exhaust stream output from the AGO and to react methane with steam to produce a first product stream including hydrogen (H.sub.2), carbon dioxide (CO.sub.2), and carbon monoxide (CO).

A steam methane reformer-integrated fuel cell system includes at least one fuel cell having an anode, a cathode, and an electrolyte matrix separating the anode and the cathode. The system further includes a steam methane reformer configured to react methane with steam to produce a first product stream including hydrogen (H.sub.2), carbon dioxide (CO.sub.2), and carbon monoxide (CO).

A fuel cell system includes a reformer, fuel cell stacks, and an exhaust-gas combustor. The reformer has a tubular shape extending in an axial direction and reforms raw fuel into combustion gas. The fuel cell stacks generate electric power from the fuel gas and oxidant gas. The fuel cell stacks are arranged radially outward of the reformer in a circumferential direction to face the reformer in a radial direction. The exhaust-gas combustor burns fuel gas that is not used and included in exhaust gas from the fuel cell stacks. The exhaust-gas combustor is arranged radially inward of the reformer to face the reformer in the radial direction. Each fuel cell stack includes flat plate type cells stacked in the radial direction. This achieves downsizing of the fuel cell system.

A process for reducing an organic material to produce methane and/or hydrogen is disclosed. The process includes: (a) contacting the organic material with an excess amount of hydrogen gas in an enclosed reduction chamber at ambient temperature, where the reduction chamber is substantially free of oxygen, and heating the reduction chamber to cause a temperature increase in the organic material from ambient temperature to up to 425° C. at a rate of up to about 8° C. per minute, under positive pressure, to form a first gaseous mixture comprising methane, hydrogen, acid, and partially reduced volatile organic molecules; (b) heating the first gaseous mixture to a temperature of about 675° C. to about 875° C. in the presence of an excess amount of hydrogen gas to form a second gaseous mixture comprising methane, hydrogen, and acid; and (c) neutralizing the second gaseous mixture with a base.

Integrated refinery processes and systems for generating hydrogen by direct decomposition of hydrocarbons. The integrated processes and systems can be used to capture carbon and sulfur in solid form, reducing carbon dioxide and sulfur oxide emissions. The processes include reacting sour gas with a metal-based sorbent in a reactor to produce sulfur-bearing solids and water, and to partially reform hydrocarbons in the sour gas to produce hydrogen-rich syngas; and cracking remaining hydrocarbons thermally with or without the presence of a catalyst to produce hydrogen and solid carbon.