A solar-driven methanol reforming system for hydrogen production includes a water storage tank, high-temperature solar collector tubes, a thermocouple, valves, preheaters, an evaporator, a reactor, a heat exchanger, a mixed solution (methanol and water) storage tank, a gas separator, a pump, a carbon dioxide storage tank, a hydrogen storage tank, and pipes; the present invention utilizes solar energy to provide heat required for hydrogen production by methanol reforming, and stores some heat in a phase change material to supply heat for the methanol reforming reaction when sunlight is weak; the system does not need additional energy supply, thus saving energy consumption from traditional electric heating or fuel heating.

There are provided systems and methods for using fuel-rich partial oxidation to produce an end product from waste gases, such as flare gas. In an embodiment, the system and method use air-breathing piston engines and turbine engines for the fuel-rich partial oxidation of the flare gas to form synthesis gas, and reactors to convert the synthesis gas into the end product. In an embodiment the end product is methanol.

There are provided systems and methods for using fuel-rich partial oxidation to produce an end product from waste gases, such as flare gas. In an embodiment, the system and method use air-breathing piston engines and turbine engines for the fuel-rich partial oxidation of the flare gas to form synthesis gas, and reactors to convert the synthesis gas into the end product. In an embodiment the end product is methanol.

There are provided systems and methods for using fuel-rich partial oxidation to produce an end product from waste gases, such as flare gas. In an embodiment, the system and method use air-breathing piston engines and turbine engines for the fuel-rich partial oxidation of the flare gas to form synthesis gas, and reactors to convert the synthesis gas into the end product. In an embodiment the end product is methanol.

A method for producing aqueous hydrochloric acid from flue gases is provided. The method comprises conveying water to a first scrubber (102, 202, 302, 402, 502, 602, 702) or to a line (112b, 212b, 312b, 412b, 512b, 712b, 712c) to use the water in a scrubbing liquid of the first scrubber. The method also comprises providing flue gas containing chlorides into the first scrubber (102, 202, 302, 402, 502, 602, 702) and scrubbing the flue gas containing chlorides with the scrubbing liquid by contacting the flue gas with the scrubbing liquid in the first scrubber (102, 202, 302, 402, 502, 602, 702). Dilute hydrochloric acid and a flue gas derivate (104, 204, 304, 404, 504, 704) are produced. The method comprises letting out at least some of the dilute hydrochloric acid from the first scrubber (102, 202, 302, 402, 502, 602, 702) as a scrubber bleed, separating solids suspended by the scrubber bleed in a solids separator (192, 592, 692), conveying the scrubber bleed from the solids separator (192, 592, 692) into an evaporation vessel (194, 594, 694) and concentrating the scrubber bleed in the evaporation vessel (194, 594, 694) to produce hydrochloric acid vapor having a concentration of 5-22 wt-%. A corresponding system is also provided.

A hydrogen generating method includes generating hydrogen by dehydrogenation-reacting a chemical hydride of a solid state with an acid aqueous solution. The dehydrogenation-reaction is performed by reacting 1 mol of hydrogen atoms of the chemical hydride with an acid and water at a molar ratio of 0.5 to 2.

The present invention refers to a pre-reforming catalyst comprised of nickel oxide and having platinum content between 0.01 to 0.5%, characterized in that the catalyst is resistant to deactivation by passage of steam in the absence of a reducing agent and to a process for producing hydrogen or hydrogen-rich gases.

A process for producing hydrogen-lean syngas includes the steps of reacting, via a catalytic partial oxidation (CPO) reaction, a CPO reactant mixture in a CPO reactor to produce the hydrogen-lean syngas, wherein the CPO reactant mixture includes hydrocarbons and oxygen. The hydrocarbons include greater than or equal to about 3 mol % C2+ alkanes, wherein the CPO reactor include a CPO catalyst, and wherein the hydrogen-lean syngas include hydrogen, carbon monoxide, carbon dioxide, water, and unreacted hydrocarbons The hydrogen-lean syngas is characterized by a molar ratio of hydrogen to carbon monoxide (H2/CO) in a range of from about 0.8 to about 1.6. A system for carrying out the process is also provided.

Systems and methods generally involve processing a gaseous reducing agent and a gaseous reforming agent to produce syngas in the presence of a stable-phase change metal-oxide based oxygen carrier. During operation, an oxygen content is measured for a reactor input stream and a reactor output stream. A percent oxygen depletion of the metal oxide is determined using an initial oxygen content of the metal oxide, the oxygen content of the input stream, and the oxygen content of the output stream. Based on the percent oxygen depletion, a mole ratio of reducing gas to oxidant in the input stream may be adjusted accordingly.

A process is proposed for producing pure hydrogen by steam reforming of a feed gas comprising hydrocarbons, preferably natural gas or naphtha, with a simultaneously low and preferably adjustable export steam flow rate. The process includes the steam reforming of the feed gas, for which the heat of reaction required is provided by combustion of one or more fuel gases with combustion air in a multitude of burners arranged within the reformer furnace. According to the invention, the combustion air, before being introduced into the burners, is heated by means of at least one heat exchanger in indirect heat exchange with the hot flue gas to temperatures of at least 530° C.