The invention relates to a host material for stabilizing a Li metal electrode, fabricating methods and applications of the same. The host material includes crumpled graphene balls operably defining a scaffold having volumes and voids inside and in between the crumpled graphene balls so as to allow uniform and stable Li deposition/dissolution inside and in between the crumpled graphene balls without electrode volume fluctuations or with sufficiently small electrode volume fluctuations. The crumpled paper ball-like structures of graphene particles can readily assemble to yield the scaffold with scalable Li loading up to 10 mAh cm-2 within tolerable volume fluctuations. High Coulombic efficiency of 97.5% over 750 cycles (1500 hours) is achieved. Plating/stripping Li up to 12 mAh cm-2 on the crumpled graphene scaffold does not experience dendrite growth.

Disclosed herein are methods and compositions directed to a promising class of nanomaterials called organic nanoparticles, or carbon nanodots. The present disclosure provides a facile method for the conversion of biomolecule-based carbon nanodots into high surface area three-dimensional graphene networks with excellent electrochemical properties.

The present invention relates to a graphene material inlaid with single metal atoms, the preparation method thereof and its application of being used as the catalyst for the electroreduction of carbon dioxide. The graphene material inlaid with single metal atoms comprises single metal atoms and graphene; the single metal atoms are dispersed in the framework of the graphene; and the graphene is at least one selected from N doped graphene and N and S co-doped graphene. The material is used for the electrochemical reduction reaction of carbon dioxide, which significantly improves the utilization efficiency of the metal atoms and enhances the catalytic activity for the electroreduction of carbon dioxide, improves the catalytic stability, inhibits effectively the hydrogen evolution reaction, improves the selectivity for CO product, and broadens the electric potential window of reducing carbon dioxide to generate CO.

The present disclosure provides a method for manufacturing a graphene-metal composite wire. The method includes: (1) growing graphene on a surface of a metal wire through a chemical vapor deposition process; (2) twisting the wire; (3) pretensioning and pre-straining the wire; (4) cold-drawing the wire; and (5) subjecting the wire to a chemical vapor deposition process, wherein the wire is subjected to steps (2) to (5) successively and cycled n times, wherein f wires obtained in step (1) are used in the first cycle, f wires obtained from previous cycle are used in subsequent cycle, and finally a graphene-metal composite wire with fn strands is obtained, and wherein (a) f is an integer of 2-9; and (b) n is an integer of 6 or more.

The present invention provides a method for forming a graphene film through horizontally tiling and self-assembling graphene, including: proportionally adding toluene and alcohol into a graphene aqueous solution to be fully and uniformly mixed; then pouring the mixture into a vacuum filtration device, wherein when a solution in a filter flask forms a layered solution system with upper and lower layers, graphene is confined at an interface and tiled horizontally under a shear force at the interface to allow (002) planes of graphene to gradually become parallel to the interface, and graphene to be self-assembled to form the graphene film; and activating the suction filtration device to remove the solution, to obtain a graphene film with the (002) planes parallel to each other at a microscopic level on a filter paper.

The present invention relates to methods of fabrication of hollow shells/spheres/particles, core-shell particles and composite materials made from these particles.

Disclosed here is a method for making a three-dimensional micro-architected aerogel, comprising: (a) curing a reaction mixture comprising a co-sol-gel material (e.g., graphene oxide (GO)) and at least one catalyst to obtain a crosslinked co-sol-gel (e.g., GO hydrogel); (b) providing a photoresin comprising a solvent, a photoinitiator, a crosslinkable polymer precursor, and a dispersion of the crosslinked co-sol-gel (e.g., GO hydrogel); (c) curing the photoresin using projection microstereolithography layer-by-layer to produce a wet gel having a pre-designed three-dimensional structure; (d) drying the wet gel to produce a dry gel; and (e) pyrolyzing the dry gel to produce a three-dimensional micro-architected aerogel (e.g., graphene aerogel). Also disclosed is a photoresin for projection microstereolithography, comprising a solvent, a photoinitiator, a crosslinkable polymer precursor, and a dispersion of a crosslinked co-sol-gel.

The present invention generally relates to a method of making graphene and graphene devices.

The present invention addresses the problem of providing a method for producing a fibrous carbon nanohorn aggregate with higher efficiency. According to one embodiment of the present invention, a method for producing a carbon nanohorn aggregate comprising a fibrous carbon nanohorn aggregate, is provided, which includes a step (a) of fixing the end of a rod-shaped carbon target to a fixing jig, and a step (b) of irradiating the rod-shaped carbon target with a laser light, and moving the irradiation position of the laser light in the longitudinal direction of the rod-shaped carbon target without rotating the rod-shaped carbon target.

A method to make free-standing graphene sheets and the free-standing graphene sheets so formed. The method includes the steps of exfoliating partially oxidized graphene from a carbon-containing electrode into an aqueous solution, acidifying the aqueous solution, and separating from the acidified solution partially oxidized graphene sheet. The partially oxidized graphene is then dried to yield free-standing graphene sheet having a carbon-to-oxygen ratio of at least about 8.0.