The present invention relates to a method for preparing a functionalized graphene. The method for preparing a functionalized graphene according to the present invention can functionalize graphene by a simple method and does not use any other substance other than graphene and a salt containing a double bond, thereby enabling functionalization of graphene while exhibiting characteristics inherent to graphene.

The present disclosure provides a graphene based dry electrode for electrophysiological readings, in particular for use with EEG, EKG, EMG, and EOG systems and a method for making said electrodes. The electrodes comprising a doped silicon substrate; a silicon carbide film on the substrate; a graphene surface on the silicon carbide film; wherein the graphene surface has undergone a functionalisation and/or intercalation process to increase the amount of oxygen functional groups present, said process being preferably carried out through repeated contact of the graphene surface with an electrolyte solution.

A composition suitable for coating a metallic substrate that is susceptible to corrosion is disclosed. The composition comprises a carrier medium and graphene platelets in which the graphene platelets comprise between 0.002 wt % and 0.09 wt % of the coating, and the graphene platelets comprise one of or a mixture of two or more of graphene nanoplates, bilayer graphene nanoplates, few-layer graphene nanoplates, and/or graphite flakes in which the graphite flakes have one nanoscale dimension and 25 or less layers

A method, including irradiating graphene oxide (GO) with a beam of light or radiation to form reduced graphene oxide (RGO) in a three-dimensional (3D) pattern, wherein the RGO is porous RGO with pores having sizes tuned by controlling the beam of light or radiation.

A method of producing a substrate provided with a shaped graphene material electrically conductive region is described, the method comprising applying a photoresist material to a substrate, shaping the photoresist material to cover at least part of the substrate that is not to be electrically conductive, depositing a graphene material onto the substrate over the shaped photoresist material, and subsequently removing the photoresist material. Also described are devices such as touch sensors and shaped light emitting devices manufactured using the method.

A graphene nanostructure has a nanographene, a conjugated functional group bonded to the nanographene via a pyrazine skeleton, and at least one Br group and/or at least one CN group introduced into the conjugated functional group. A graphene nanostructure preferably has an average size of 1 nm or larger to 100 nm or smaller, a band gap of 0.01 eV or higher to 1.2 eV or lower, and/or a HOMO level of 6.0 eV or higher to 4.0 eV or lower. As the conjugated functional group into which the Br group(s) and/or the CN group(s) are/is introduced, a 4-bromobenzene group, a 4,5-dibromobenzene group, a 5-bromopyridine group, a 5-bromopyrazine group, a benzonitrile group, a phthalonitrile group, or a 2,3-dicyanopyrazine group is desirable.

The invention relates to the field of producing carbon nanomaterials, and can be used in the manufacture of electrodes in supercapacitors. The nanomaterials are produced from graphene by means of graphene sheet assembly using a method characterised in that, for said assembly, the graphene sheets undergo an electrodynamic fluidisation in which the chemically active edges of the graphene sheets connect during counter-collisions between oppositely charged sheets, resulting in the formation of covalent bonds and in the subsequent formation of aggregates and macrostructures. The series-connection of sheets in such collisions leads to strong, developed macro structures that have high electrical conductivity and a large surface, and can be used as a material for manufacturing supercapacitor electrodes. This method makes it possible to produce nanomaterials for the manufacture of supercapacitor electrodes which have high electrical conductivity and a large surface, and provides for high productivity and cost-effectiveness when producing the product.

Systems, methods, and devices of the various embodiments provide for the creation of holey graphene meshes (HGMs) and composite articles including HGMs. Various embodiments provide solvent-free methods for creating arrays of holes on holey graphene-based articles formed from dry compression (such as films, discs, pellets), thereby resulting in a HGM. In further embodiments, a HGM can used as part of a composite, such as by: 1) embedding a HGM into another matrix material such as carbon, polymer, metals, metal oxides, etc; and/or (2) the HGM serving as a matrix by filling the holes of the HGM or functionalizing the HGM body with another one or more materials. In various embodiments, HGM can also be made as a composite itself by creating holes on dry-compressed articles pre-embedded with one or more other materials.

The invention relates to a method for producing a functionalised semiconductor or conductor material from a layered structured base material by electrolytic exfoliation in an electrolysis cell, comprising at least one electrode pair consisting of first and second electrodes, and an aqueous and/or alcoholic electrolyte solution, containing sulphuric acid and/or at least one salt selected from sulphate and/or hydrogen sulphate and/or perchlorate and/or persulphate salt, comprising the steps of: a) bringing the electrodes into contact with the electrolyte solution; b) electronically exfoliating the base material by applying a voltage between the first and the second electrode; c) separating the functionalised conductor or semiconductor material from the electrolyte solution, wherein at least the first of the electrodes of the electrode pair contains the layered, carbon-based base material, the first electrode being connected as an anode, wherein at least one organic compound is added to the electrolyte solution before and/or during and/or immediately after the electrolytic exfoliation, wherein the organic compound is selected from i) anodically oxidisable organic molecules containing at least one alcohol group and/or at least one amino group and/or at least one carboxyl group, and/or ii) organic molecules containing at least one isocyanate group and/or at least one halide group and/or at least one epoxide group and/or at least one diazonium group and/or at least one peroxide group and/or at least one azide group and/or cyclic esters and/or cyclic amides, and/or iii) precursors or monomers of electrically conductive polymers, and/or iv) free-radical polymerisable, water-soluble vinyl monomers which have in their structure at least one amino group and/or at least one anionic functional group.

A method for the electrohydrodynamic deposition of carbonaceous materials utilizing an electrohydrodynamic cell comprising two electrodes comprised of a conductive material, by first combining a solid phase comprising a carbonaceous material and a suspension medium, placing the suspension between the electrodes, applying an electric field in a first direction, varying the intensity of the electric field sufficiently to drive lateral movement, increasing the electrical field to stop the lateral transport and fix the layers in place, then removing the applied field and removing the electrodes. Among the many different possibilities contemplated, the method may advantageously utilize: varying the spacing between the electrodes; removing the buildup from one or both electrodes; placing the electrodes into different suspensions; adjusting the concentration, pH, or temperature of the suspension(s); and varying the direction, intensity or duration of the electric fields.