Provided is a process for producing a solid graphene foam-based sealing material. The process comprises: (a) preparing a graphene dispersion having a graphene material dispersed in a liquid medium, which contains an optional blowing agent; (b) dispensing and depositing the graphene dispersion into desired shapes and partially or completely removing the liquid medium from these shapes to form dried graphene shapes; (c) heat treating the dried graphene shapes at a first heat treatment temperature from 50 C. to 3,200 C. at a desired heating rate sufficient to induce volatile gas molecules from the non-carbon elements or to activate the blowing agent for producing the graphene foam; and (d) coating or impregnating the graphene foam with a permeation-resistant binder or matrix material to form the sealing material.

Provided is a graphene foam-based sealing material comprising: (a) a graphene foam framework comprising pores and pore walls, wherein the pore walls comprise a 3D network of interconnected graphene planes or graphene sheets; and (b) a permeation-resistant binder or matrix material that coats and embraces the exterior surfaces of the graphene foam framework and/or infiltrates into pores of the graphene foam, occupying from 10% to 100% (preferably from 10% to 98% and more preferably from 20% to 90%) of the pore volume of the graphene foam framework.

A process for producing a fabric comprising at least a graphene-based continuous or long fiber, comprising: (a) preparing a graphene dispersion having chemically functionalized graphene sheets dispersed in a fluid; (b) dispensing, depositing, and shearing at least a continuous or long filament of the graphene dispersion onto a substrate, and removing the fluid to form a continuous or long fiber comprising aligned chemically functionally graphene sheets; and (c) inducing chemical reactions between chemical functional groups attached to adjacent graphene sheets to form the graphene fiber; (d) combining the graphene fiber with a plurality of fibers, the same type as or different than the graphene fiber, to form at least one fiber yarn; and (e) combining the at least one fiber yarn and a plurality of fiber yarns, the same type as or different than the at least one fiber yarn, to form the fabric.

Provided is a process for producing an integral graphene film, comprising: (a) preparing a graphene dispersion having chemically functionalized graphene sheets dispersed in a fluid medium wherein the graphene sheets contain chemical functional groups attached thereto; (b) dispensing and depositing a wet film of the graphene dispersion onto a supporting substrate, wherein the dispensing and depositing procedure includes mechanical shear stress-induced alignment of the graphene sheets along a film planar direction, and partially or completely removing the fluid medium to form a relatively dried film comprising aligned chemically functionally graphene sheets; and (c) using heat, electromagnetic waves, UV light, or high-energy radiation to induce chemical reactions or chemical bonding between chemical functional groups attached to adjacent chemically functionalized graphene sheets to form the integral graphene film. The film after step (b) or (c) may be further compressed to increase the degree of graphene sheet orientation in the integral graphene film.

Provided is an integral graphene film comprising chemically functionalized graphene sheets that are chemically bonded or interconnected with one another having an inter-planar spacing d.sub.002 from 0.36 nm to 1.5 nm as determined by X-ray diffraction and a non-carbon element content of 0.1% to 47% by weight, wherein said functionalized graphene sheets are substantially parallel to one another and parallel to an in-plane direction of said integral graphene film and said integral graphene film has a length from 1 cm to 10,000 m, a width from 1 cm to 5 m, a thickness from 2 nm to 500 m, and a physical density from 1.5 to 2.25 g/cm.sup.3. The integral graphene film typically has a Young's modulus from 20 GPa to 300 GPa or a tensile strength from 1.0 GPa to 3.5 GPa.

The present disclosure provides a method for repairing defect of graphene, including: firstly introducing a composite fluid containing a reactive compound and a supercritical fluid to a reactor where the graphene powder has been placed, and impregnating the graphene powder with the composite fluid to passivate and repair the defect of graphene, wherein the reactive compound includes carbon, hydrogen, nitrogen, silicon or oxygen element; and separating the composite fluid from the graphene powder, simultaneously using molecular sieves to absorb the graphene from the composite fluid. The present disclosure further provides the graphene powder prepared by the method above. With the method of the present disclosure, it effectively reduces the ratio of the defect of the graphene, increases the content of the graphene, and has less-layer graphene with high thermal conductivity and electrical conductivity.

The present invention relates to a method for preparing a carbon nanotube-based heat-dissipating material and an LED lighting device. The LED lighting device comprises second LED substrates and a heat-dissipating frame. The heat-dissipating frame comprises: a frame body formed in a polygonal column shape being open at its upper and lower ends, in which substrate contact surfaces, with which the second LED substrates respectively come into contact, are formed on outer sides of the frame body; and auxiliary heat sinks made of a carbon nanotube-based heat-dissipating material and attachably and detachably provided on inner sides corresponding to the substrate contact surfaces of the frame body.

The present invention provides for an ice-nucleating particle for cloud seeding and other applications, which can initiate ice nucleation at a temperature of ?8? C. Further, the ice nucleation particle number increased continuously and rapidly with the reducing of temperature. The ice nucleating particle in the present invention is a nanostructured porous composite of 3-dimensional reduced graphene oxide and silica dioxide nanoparticles (PrGO-SN). The present invention also provides for a process for synthesizing the PrGO-SN.

A graphene thermostatic fabric includes a fibrous tissue and a graphene thermostatic layer. The fibrous tissue has a first tissue surface, a second tissue surface and an interspace between the first tissue surface and the second tissue surface. The graphene thermostatic layer adheres to the first tissue surface, fills a part of the interspace, and includes at least a hydrophobic resin and nano-graphene sheets dispersed in the hydrophobic resin. A thermal conductivity of the graphene thermostatic layer varies with a change of an ambient temperature, and the thermal conductivity of the graphene thermostatic layer perpendicular to the first tissue surface is less than the thermal conductivity of the graphene thermostatic layer parallel to the first tissue surface. A method of manufacturing the graphene thermostatic fabric is further provided.

The present invention provides a graphite/graphene composite material comprising flat graphite particles and graphene aggregates, wherein the flat graphite particles are stacked using the graphene aggregates as a binder so that the basal surfaces of the graphite particles are overlapped with one another, and the graphene aggregates are composed of deposited single-layer or multi-layer graphenes.