Provided is a catalyst that is free from catalyst deactivation caused by reaction of the support and exhibits good catalytic activity in an ammonia synthesis reaction in a low-temperature, low-pressure process. The present invention relates to an ammonia synthesis catalyst having a structure in which at least one of ruthenium or an oxide of ruthenium is loaded on a titanium suboxide support represented by the composition formula TiOx where x represents a number satisfying 1.5<x<2.0.

Provided is a catalyst that is free from catalyst deactivation caused by reaction of the support and exhibits good catalytic activity in an ammonia synthesis reaction in a low-temperature, low-pressure process. The present invention relates to an ammonia synthesis catalyst having a structure in which at least one of ruthenium or an oxide of ruthenium is loaded on a titanium suboxide support represented by the composition formula TiOx where x represents a number satisfying 1.5<x<2.0.

The present disclosure relates to systems and methods of making ammonia using stable ammonia absorbents. The system and method for producing ammonia, comprises a reactor comprising a catalyst that converts at least a portion of nitrogen feed gas and at least a portion of hydrogen feed gas to ammonia (NH3) forming a reaction mixture comprising the ammonia, unreacted nitrogen, and unreacted hydrogen. An absorber configured to selectively absorb ammonia from the reaction mixture at a temperature of about 180 deg. C. to 330 deg. C. and a pressure of about 1-20 bar, the absorber comprising a solid absorbent. Preferably the solid absorbent is at least one metal halide and a solid support. The unabsorbed ammonium, the unreacted nitrogen, and unreacted hydrogen gas are recycled to the reactor.

A process for synthesis of ammonia including generation of makeup gas in a frontend and conversion of said makeup gas in an ammonia synthesis loop including a circulator, a converter, a condensation section and a liquid ammonia separation section, including: when the loop operates at a partial load and a flow rate of makeup gas transferred from the front end to the synthesis loop is reduced, the loop is controlled by separating a gas stream from a converter feed line at a point upstream of the converter thus forming a bypass stream; reintroducing said bypass stream at the suction side of the circulator or at a point of the loop downstream of said separation section.

Ammonia is made in a system that includes a conversion reactor for performing a Haber-Bosch process. Effluent streams from the conversion reactor, which include an ammonia component and excess hydrogen and nitrogen reactants, are fed to a membrane separator that includes NaA zeolite membranes disposed on one or more hollow porous supports. The NaA zeolite membranes are highly selective for the ammonia component, allowing the ammonia to be collected from a lumen of the membranes as a product and enriching the excess hydrogen and nitrogen reactants for reuse in the conversion reactor. These systems and the methods of their use are effective to replace and/or modify the energy-intensive condensation/recycling steps in the traditional Haber-Bosch process used to condense NH3 from the exiting stream of the reactor. The selective removal of ammonia by high quality NaA membranes helps to shift the ammonia evolution reaction.

A containerized system for producing anhydrous ammonia from air, water and a power source, includes a containerized hydrogen production unit that produces hydrogen gas from a water source by low temperature electrolyser, high temperature electrolyser, battolyser or by other methods; a containerized nitrogen production unit comprising an onboard air compression and storage unit that produces and stores pressurized air, a pressure swing adsorption process or other methods that use regenerative molecule that does not need any maintenance, which intakes compressed air and produces nitrogen gas through a series of adsorption and desorption processes, or other such methods of producing nitrogen from air; a containerized ammonia production unit comprising a gas booster that increases the pressure of a mixture of the hydrogen gas and the nitrogen gas using the pressurized air; a multi-reactor assembly joint in series or in parallel; and a recycle loop that separates the ammonia from unreacted gases.

Disclosed is a ruthenium-based catalyst for ammonia synthesis, preparation method and use thereof. The ruthenium-based catalyst comprises Ru—Ba-A core-shell structure which comprises a ruthenium nanoparticle as a core covered with a first shell and a second shell sequentially, wherein the first shell consists of a barium nanoparticle, and the second shell consists of a metal oxide. The Ru—Ba-A core-shell structure can effectively preventing agglomerations of ruthenium nanoparticles during the use of the catalyst and avoiding direct contact between the ruthenium nanoparticles and the metal oxides. In addition, barium nanoparticles have a promoting effect as an electronic promoter, which can effectively improve the stability and catalytic activity of ruthenium-based catalyst for ammonia synthesis, especially in the system for synthesizing ammonia from a coal gas.

An ammonia derivative production plant includes: an electrolyzer for electrolyzing water; an ammonia synthesis system for synthesizing ammonia from hydrogen produced by the electrolyzer and nitrogen; a carbon dioxide generation system for producing carbon dioxide; and an ammonia derivative synthesis system for synthesizing an ammonia derivative from ammonia synthesized by the ammonia synthesis system and carbon dioxide produced by the carbon dioxide generation system. Oxygen produced by the electrolyzer is consumed to produce carbon dioxide by the carbon dioxide generation system.

An ammonia derivative production plant includes: an electrolyzer for electrolyzing water; an ammonia synthesis system for synthesizing ammonia from hydrogen produced by the electrolyzer and nitrogen; a carbon dioxide generation system for producing carbon dioxide; and an ammonia derivative synthesis system for synthesizing an ammonia derivative from ammonia synthesized by the ammonia synthesis system and carbon dioxide produced by the carbon dioxide generation system. Oxygen produced by the electrolyzer is consumed to produce carbon dioxide by the carbon dioxide generation system.

The present invention relates to a high pressure process for Pre-Combustion and Post-Combustion CO.sub.2 capture (HP/MP/LP gasification) from a CO.sub.2 gas stream (CO2-Stream) by way of CO.sub.2 total subcritical condensation (CO2-CC), separation of liquid CO.sub.2, higher pressure elevation of obtained liquid CO.sub.2 via HP pump, superheating of CO.sub.2 up to high temperature for driving of a set of CO.sub.2 expander turbines for additional power generation (CO2-PG), EOR or sequestration (First new Thermodynamic Cycle). The obtained liquid CO.sub.2 above, will be pressurized at a higher pressure and blended with HP water obtaining high concentrated electrolyte, that is fed into HP low temperature electrochemical reactor (HPLTE-Syngas Generator) wherefrom the cathodic syngas and anodic oxygen will be performed. In particular the generated HP oxygen/syngas will be utilized for sequential combustion (“H.sub.2/O.sub.2-torches”) for super-efficient hydrogen based fossil power generation (Second new Thermodynamic Cycle).