Process for the synthesis of ammonia from natural gas comprising conversion of a charge of desulphurized natural gas and steam, with oxygen-enriched air or oxygen, into a synthesis gas, and treatment of the synthesis gas with shift reaction and decarbonation, wherein a part of the CO2-depleted synthesis gas, obtained after decarbonation, is separated and used as fuel fraction for one or more furnaces of the conversion section, and the remaining part of the gas is used to produce ammonia.

Process for the synthesis of ammonia from natural gas comprising conversion of a charge of desulphurized natural gas and steam, with oxygen-enriched air or oxygen, into a synthesis gas, and treatment of the synthesis gas with shift reaction and decarbonation, wherein a part of the CO2-depleted synthesis gas, obtained after decarbonation, is separated and used as fuel fraction for one or more furnaces of the conversion section, and the remaining part of the gas is used to produce ammonia.

A steam network assembly for a plant including an ammonia-producing unit and a urea-producing unit, including a high-pressure steam line, two medium-pressure steam lines and first and second turbines supplied with high-pressure steam by the high-pressure steam line; wherein the first turbine is a condensing-type turbine with extraction into one of the two medium-pressure steam lines, and is configured to deliver power to a syngas compressor in the ammonia-producing unit of the plant, and the second turbine is a counter-pressure type turbine with extraction connected to the two medium-pressure steam lines and is configured to deliver power to a CO.sub.2 compressor in the urea-producing unit of the plant. A method to distribute high-pressure steam in a steam network assembly for a plant including an ammonia-producing unit and a urea-producing unit and a method to revamp the steam network assembly for a plant including an ammonia-producing unit and a urea-producing unit.

A steam network assembly for a plant including an ammonia-producing unit and a urea-producing unit, including a high-pressure steam line, two medium-pressure steam lines and first and second turbines supplied with high-pressure steam by the high-pressure steam line; wherein the first turbine is a condensing-type turbine with extraction into one of the two medium-pressure steam lines, and is configured to deliver power to a syngas compressor in the ammonia-producing unit of the plant, and the second turbine is a counter-pressure type turbine with extraction connected to the two medium-pressure steam lines and is configured to deliver power to a CO.sub.2 compressor in the urea-producing unit of the plant. A method to distribute high-pressure steam in a steam network assembly for a plant including an ammonia-producing unit and a urea-producing unit and a method to revamp the steam network assembly for a plant including an ammonia-producing unit and a urea-producing unit.

A chemical plant including: a reforming section arranged to receive a feed gas comprising hydrocarbons and provide a combined synthesis gas stream, wherein the reforming section includes: an electrically heated reforming reactor housing a first catalyst, an autothermal reforming reactor in parallel with the electrically heated reforming reactor, wherein the reforming section is arranged to output a combined synthesis gas stream including at least part of the first and/or second synthesis gas streams, an optional post processing unit downstream the reforming section, a gas separation unit arranged to separate a synthesis gas stream into a water condensate and an intermediate synthesis gas, and a downstream section arranged to receive the intermediate synthesis gas and to process the intermediate synthesis gas to a chemical product and an off-gas. Also, a process for producing a chemical product from a feed gas comprising hydrocarbons.

A method of a hydrocarbon product and ammonia comprises introducing C.sub.2H.sub.6 to a positive electrode of an electrochemical cell comprising the positive electrode, a negative electrode, and a proton-conducting membrane between the positive electrode and the negative electrode. The proton-conducting membrane comprising an electrolyte material having an ionic conductivity greater than or equal to about 10.sup.−2 S/cm at one or more temperatures within a range of from about 150° C. to about 600° C. N.sub.2 is introduced to the negative electrode of the electrochemical cell. A potential difference is applied between the positive electrode and the negative electrode of the electrochemical cell. A system for co-producing higher hydrocarbons and NH.sub.3, and an electrochemical cell are also described.

An ammonia synthesis plant comprising: a feed pretreating section operable to pretreat a feed stream; a syngas generation section operable to reform the feed stream to produce a reformer product stream; a shift conversion section operable to subject the reformer product stream to the water gas shift reaction, to produce a shifted gas stream comprising more hydrogen than the reformer gas stream; a purification section operable to remove at least one component from the shifted gas stream, and provide an ammonia synthesis feed stream; and/or an ammonia synthesis section operable to produce ammonia from the ammonia synthesis feed stream, wherein the ammonia synthesis plant is configured such that, relative to a conventional ammonia synthesis plant, more of the energy required by the ammonia synthesis plant or one or more sections thereof is provided by a non-carbon based energy source, a renewable energy source, and/or electricity.

A steam network assembly for a plant including an ammonia-producing unit and a urea-producing unit, including a high-pressure steam line, two medium-pressure steam lines and first and second turbines supplied with high-pressure steam by the high-pressure steam line; wherein the first turbine is a condensing-type turbine with extraction into one of the two medium-pressure steam lines, and is configured to deliver power to a syngas compressor in the ammonia-producing unit of the plant, and the second turbine is a counter-pressure type turbine with extraction connected to the two medium-pressure steam lines and is configured to deliver power to a CO.sub.2 compressor in the urea-producing unit of the plant. A method to distribute high-pressure steam in a steam network assembly for a plant including an ammonia-producing unit and a urea-producing unit and a method to revamp the steam network assembly for a plant including an ammonia-producing unit and a urea-producing unit.

A steam network assembly for a plant including an ammonia-producing unit and a urea-producing unit, including a high-pressure steam line, two medium-pressure steam lines and first and second turbines supplied with high-pressure steam by the high-pressure steam line; wherein the first turbine is a condensing-type turbine with extraction into one of the two medium-pressure steam lines, and is configured to deliver power to a syngas compressor in the ammonia-producing unit of the plant, and the second turbine is a counter-pressure type turbine with extraction connected to the two medium-pressure steam lines and is configured to deliver power to a CO.sub.2 compressor in the urea-producing unit of the plant. A method to distribute high-pressure steam in a steam network assembly for a plant including an ammonia-producing unit and a urea-producing unit and a method to revamp the steam network assembly for a plant including an ammonia-producing unit and a urea-producing unit.

A high-temperature solid oxide fuel cell arrangement fueled by a hydrogen or hydrocarbon fuel and generating electricity and anunonia as a byproduct comprises: (a) a cathode area fed with a humid air; (b) an anode area fed with the fuel; and (c) an oxygen-conducting electrolyte disposed between the cathode and anode areas. The cathode has an ammonia-rich tail-gas stream. The fuel cell further comprises a gas separator configured for separating ammonia generated on the cathode from tail-gas stream and means for utilizing separated ammonia selected from the group consisting of: an ammonia reformer configured for generating hydrogen to be admixed to the fuel fed to the anode, a collecting tank for storing the anunonia and an auxiliary solid oxide fuel cell fueled by the separated anunonia and any combination thereof.