A method can include combusting a sulfur precursor in air to form sulfur dioxide, providing the sulfur dioxide to an electrolyzer with at least a threshold gauge pressure, providing water to the electrolyzer, and oxidizing the sulfur dioxide to sulfuric acid and reducing the water to hydrogen in the electrolyzer.

A method can include combusting a sulfur precursor in air to form sulfur dioxide, providing the sulfur dioxide to an electrolyzer with at least a threshold gauge pressure, providing water to the electrolyzer, and oxidizing the sulfur dioxide to sulfuric acid and reducing the water to hydrogen in the electrolyzer.

A water treatment solution may include a metal salt and a base product fluid. The base product fluid may include a molecular compound that is a chelating compound. The molecular compound may have the formula: ((NH.sub.4).sub.2SO.sub.4).sub.a.(H.sub.2SO.sub.4).sub.b.(H.sub.2O).sub.c.(NH.sub.4HSO.sub.4).sub.x. In the formula, a may be between 1 and 5, b may be between 1 and 5, c may be between 1 and 5, and x may be between 1 and 10. The water treatment solution may be formed by adding the metal salt to the base product fluid and water. The water treatment solution may be added to water in need of treatment. The water in need of treatment may be a static body of water.

A base product fluid is produced by adding anhydrous liquid ammonia and a first portion of sulfuric acid to water flowing in a process line to form a mixed fluid. The mixed fluid may be cooled by flowing the mixed fluid through a heat exchanger. A second portion of sulfuric acid may be added to the mixed fluid to form the base product fluid. The second portion of sulfuric acid may be greater, by weight, than the first portion of sulfuric acid. The base product fluid may include a molecular compound that is a chelating compound. The molecular compound may have the formula: ((NH.sub.4).sub.2SO.sub.4).sub.a.(H.sub.2SO.sub.4).sub.b.(H.sub.2O).sub.c.(NH.sub.4HSO.sub.4).sub.x.

A system for the production of ammonium sulfate granules including a pipe cross reactor (PCR) configured to contact concentrated sulfuric acid with anhydrous ammonia to produce a PCR product comprising ammonium sulfate; and a granulator fluidly connected to the PCR, whereby PCR product extracted from the PCR can be introduced into the granulator, an inlet for ammonium sulfate seed material, an ammonia sparger configured to spray liquid anhydrous ammonia onto a bed of ammonium sulfate granules within the granulator, and a granulator product outlet configured for extraction of granulator product comprising ammonium sulfate granules from the granulator. A method of producing ammonium sulfate granules is also provided.

A system for the production of ammonium sulfate granules including a pipe cross reactor (PCR) configured to contact concentrated sulfuric acid with anhydrous ammonia to produce a PCR product comprising ammonium sulfate; and a granulator fluidly connected to the PCR, whereby PCR product extracted from the PCR can be introduced into the granulator, an inlet for ammonium sulfate seed material, an ammonia sparger configured to spray liquid anhydrous ammonia onto a bed of ammonium sulfate granules within the granulator, and a granulator product outlet configured for extraction of granulator product comprising ammonium sulfate granules from the granulator. A method of producing ammonium sulfate granules is also provided.

A method and system for collecting gaseous nitrogen compounds into an aqueous solution are provided. The method enables the combination of gaseous sulfur and nitrogen compounds in the aqueous solution to generate ammonium compound components, to include ammonium sulfate. Sulfur may be pressure injected into the solution as gaseous sulfur dioxide. Optionally, carbon may be introduced into the solution as gaseous carbon dioxide. The sulfur may be earlier sourced by a burning of a sulfurous solid. The pH of the solution may be monitored and the introduction of ammonia, carbon and/or sulfur may be halted or constrained while the pH of the solution is measured outside of specified range. The solution may be allowed to age to permit a mix of compounds of ammonium carbonate, ammonium bicarbonate and ammonium carbonate to restabilize and thereby encourage a renewed surge of ammonium sulfate generation.

A method and system for collecting gaseous nitrogen compounds into an aqueous solution are provided. The method enables the combination of gaseous sulfur and nitrogen compounds in the aqueous solution to generate ammonium compound components, to include ammonium sulfate. Sulfur may be pressure injected into the solution as gaseous sulfur dioxide. Optionally, carbon may be introduced into the solution as gaseous carbon dioxide. The sulfur may be earlier sourced by a burning of a sulfurous solid. The pH of the solution may be monitored and the introduction of ammonia, carbon and/or sulfur may be halted or constrained while the pH of the solution is measured outside of specified range. The solution may be allowed to age to permit a mix of compounds of ammonium carbonate, ammonium bicarbonate and ammonium carbonate to restabilize and thereby encourage a renewed surge of ammonium sulfate generation.

The present disclosure is directed to methods for treating an organic material, including the steps of transporting the organic material into a first vessel; heating the organic material in the first vessel and applying a negative pressure to the organic material in the first vessel to a boiling point of the organic material, wherein the heat and negative pressure separates a portion of an ammonia from the organic material; removing the portion of the ammonia from the first vessel; transporting the removed portion of the ammonia from the first vessel to an acid solution in a second vessel; and separating a portion of the ammonia from the acid solution.

The present disclosure is directed to methods for treating an organic material, including the steps of transporting the organic material into a first vessel; heating the organic material in the first vessel and applying a negative pressure to the organic material in the first vessel to a boiling point of the organic material, wherein the heat and negative pressure separates a portion of an ammonia from the organic material; removing the portion of the ammonia from the first vessel; transporting the removed portion of the ammonia from the first vessel to an acid solution in a second vessel; and separating a portion of the ammonia from the acid solution.