The present invention relates to a method of producing a sodium iron(II)-hexacyanoferrate(II) (Na.sub.2-xFe[Fe(CN).sub.6].mH.sub.2O), where x is <0.4) material commonly referred to as Prussian White. The method comprises the steps of acid decomposition of Na.sub.4Fe(CN).sub.6.10H.sub.2O to a powder of Na.sub.2-xFe[Fe(CN).sub.6].mH.sub.2O, drying and enriching the sodium content in the Na.sub.2-xFe[Fe(CN).sub.6].mH.sub.2O powder by mixing the powder with a saturated or supersaturated solution of a reducing agent containing sodium in dry solvent under an inert gas. The steps of acid decomposition and enriching the sodium content are performed under non-hydrothermal conditions.

A method to extend a shelf life of a sodium nitroprusside solution includes: dissolving about two parts by weight of a 2-hydroxybenzyl alcohol and about one part by weight of a sodium nitroprusside in about seventy-five parts by weight of a polyethylene glycol. Compositions for preserving a sodium nitroprusside solution are also described.

A combination of redox active compounds is useful in connection with a rechargeable battery and includes a first redox active compound having a first solubility, and a second redox active compound having a second solubility, wherein the combination has a third solubility that is greater than one or both of the first solubility and the second solubility.

A combination of redox active compounds is useful in connection with a rechargeable battery and includes a first redox active compound having a first solubility, and a second redox active compound having a second solubility, wherein the combination has a third solubility that is greater than one or both of the first solubility and the second solubility.

The object of the invention is to provide an adsorbent that can adsorb ammonia with no large volume change between absorption and desorption, that has a high ammonia and/or ammonium ion adsorption capacity, and that can have an additional function by gaining proper control of composition, etc. The invention makes it possible to provide an adsorbent that absorbs ammonia and/or ammonium ions through the use of a metal cyanocomplex as an ammonia adsorbent, experiences no or little volume change, exhibits high enough capacity for adsorbing ammonia and/or ammonium ions, and has a function of decomposing ammonia as well as a function of varying optical responses before and after adsorption, etc.

The object of the invention is to provide an adsorbent that can adsorb ammonia with no large volume change between absorption and desorption, that has a high ammonia and/or ammonium ion adsorption capacity, and that can have an additional function by gaining proper control of composition, etc. The invention makes it possible to provide an adsorbent that absorbs ammonia and/or ammonium ions through the use of a metal cyanocomplex as an ammonia adsorbent, experiences no or little volume change, exhibits high enough capacity for adsorbing ammonia and/or ammonium ions, and has a function of decomposing ammonia as well as a function of varying optical responses before and after adsorption, etc.

A system, method, and articles of manufacture for a surface-modified transition metal cyanide coordination compound (TMCCC) composition, an improved electrode including the composition, and a manufacturing method for the composition which may include multiple chelation species (Che_x). The composition, compound, device, and uses thereof according to A.sub.xMn.sub.(y-k)M.sup.j.sub.k[Mn.sup.m(CN).sub.(6-p-q)(NC).sub.p(Che_I).sup.r.sub.q].sub.z.CHE_GROUP (Vac).sub.(1-z).nH.sub.2O, wherein CHE_GROUP includes one or more chelation materials selected from the group consisting of (Che_I).sup.r.sub.w, (Che_II).sup.s.sub.v, and combinations thereof, and wherein 0<j4, 0k0.1, 0(p+q)6, 0<x4, 0<y1, 0<z1, 0<w0.2; 3r3; 0<v0.2; 3s3; and 0n6; wherein x+2(yk)+jk+(m+(r+1)q6)z+wr+vs=0.

A system, method, and articles of manufacture for a surface-modified transition metal cyanide coordination compound (TMCCC) composition, an improved electrode including the composition, and a manufacturing method for the composition which may include multiple chelation species (Che_x). The composition, compound, device, and uses thereof according to A.sub.xMn.sub.(y-k)M.sup.j.sub.k[Mn.sup.m(CN).sub.(6-p-q)(NC).sub.p(Che_I).sup.r.sub.q].sub.z.CHE_GROUP (Vac).sub.(1-z).nH.sub.2O, wherein CHE_GROUP includes one or more chelation materials selected from the group consisting of (Che_I).sup.r.sub.w, (Che_II).sup.s.sub.v, and combinations thereof, and wherein 0<j4, 0k0.1, 0(p+q)6, 0<x4, 0<y1, 0<z1, 0<w0.2; 3r3; 0<v0.2; 3s3; and 0n6; wherein x+2(yk)+jk+(m+(r+1)q6)z+wr+vs=0.

A system, method, and articles of manufacture for a surface-modified transition metal cyanide coordination compound (TMCCC) composition, an improved electrode including the composition, and a manufacturing method for the composition which may include multiple chelation species (Che_x). The composition, compound, device, and uses thereof according to A.sub.xMn.sub.(y-k)M.sup.j.sub.k[Mn.sup.m(CN).sub.(6-p-q)(NC).sub.p(Che_I).sup.r.sub.q].sub.z. CHE_GROUP (Vac).sub.(1-z).nH.sub.2O, wherein CHE_GROUP includes one or more chelation materials selected from the group consisting of (Che_I).sup.r.sub.w, (Che_II).sup.s.sub.v, and combinations thereof, and wherein 0<j4, 0k0.1, 0(p+q)6, 0<x4, 0<y1, 0<z1, 0<w0.2; 3r3; 0<v0.2; 3s3; and 0n6; wherein x+2(yk)+jk+(m+(r+1)q6)z+wr+vs=0.

A system, method, and articles of manufacture for a surface-modified transition metal cyanide coordination compound (TMCCC) composition, an improved electrode including the composition, and a manufacturing method for the composition which may include multiple chelation species (Che_x). The composition, compound, device, and uses thereof according to A.sub.xMn.sub.(y-k)M.sup.j.sub.k[Mn.sup.m(CN).sub.(6-p-q)(NC).sub.p(Che_I).sup.r.sub.q].sub.z. CHE_GROUP (Vac).sub.(1-z).nH.sub.2O, wherein CHE_GROUP includes one or more chelation materials selected from the group consisting of (Che_I).sup.r.sub.w, (Che_II).sup.s.sub.v, and combinations thereof, and wherein 0<j4, 0k0.1, 0(p+q)6, 0<x4, 0<y1, 0<z1, 0<w0.2; 3r3; 0<v0.2; 3s3; and 0n6; wherein x+2(yk)+jk+(m+(r+1)q6)z+wr+vs=0.