A method of producing a magnetic powder includes: performing heat treatment on first particles that contain triiron tetraoxide to prepare second particles that contain ε-iron oxide.

A method of producing a magnetic powder includes: performing heat treatment on first particles that contain triiron tetraoxide to prepare second particles that contain ε-iron oxide.

A raw material solution containing trivalent iron ions, or trivalent iron ions and ions of a metal element that partially substitutes Fe sites, and an alkaline aqueous solution for neutralizing the raw material solution are added to a reaction system to adjust the pH of the reaction system from 1.0 to 3.0 or lower. Hydroxycarboxylic acid is added to the obtained reaction solution and the pH of the reaction system is then neutralized from 7.0 to 10.0 or lower. The obtained precipitate of a substituent metal element-containing iron oxyhydroxide is coated with silicon oxide, followed by heating so as to form particles of ε-iron oxide in which Fe sites are partially substituted by other metal elements, and then, a slurry containing the particles is classified. The iron-based oxide magnetic powder has a particle shape close to a perfect sphere and is suitable for use in a magnetic recording medium.

A raw material solution containing trivalent iron ions, or trivalent iron ions and ions of a metal element that partially substitutes Fe sites, and an alkaline aqueous solution for neutralizing the raw material solution are added to a reaction system to adjust the pH of the reaction system from 1.0 to 3.0 or lower. Hydroxycarboxylic acid is added to the obtained reaction solution and the pH of the reaction system is then neutralized from 7.0 to 10.0 or lower. The obtained precipitate of a substituent metal element-containing iron oxyhydroxide is coated with silicon oxide, followed by heating so as to form particles of ε-iron oxide in which Fe sites are partially substituted by other metal elements, and then, a slurry containing the particles is classified. The iron-based oxide magnetic powder has a particle shape close to a perfect sphere and is suitable for use in a magnetic recording medium.

Provided are a magnetic recording medium including: a non-magnetic support; and a magnetic layer which is provided on at least one surface of the non-magnetic support and includes particles of epsilon type iron oxide-based compound, and a binding agent, in which a contact angle measured regarding a surface of the magnetic layer is equal to or greater than 30.0° and smaller than 45.0° with respect to 1-bromonaphthalene and 80.0° to 95.0° with respect to water, a manufacturing method of particles of an epsilon iron oxide-based compound, and a manufacturing method of a magnetic recording medium.

Provided is an electromagnetic-wave absorber composition and an electromagnetic-wave absorber that can favorably absorb a plurality of electromagnetic waves of different frequencies in a high frequency band in or above the millimeter-wave band. The electromagnetic-wave absorber composition includes a magnetic iron oxide that magnetically resonates at a high frequency in or above the millimeter-wave band and a resin binder. The electromagnetic-wave absorber composition has two or more extrema separated from each other on a differential curve obtained by differentiating a magnetic property hysteresis loop at an applied magnetic field intensity of from 16 kOe to −16 kOe. The electromagnetic-wave absorber includes an electromagnetic-wave absorbing layer formed of the above-described electromagnetic-wave absorber composition.

Provided is an electromagnetic-wave absorber composition and an electromagnetic-wave absorber that can favorably absorb a plurality of electromagnetic waves of different frequencies in a high frequency band in or above the millimeter-wave band. The electromagnetic-wave absorber composition includes a magnetic iron oxide that magnetically resonates at a high frequency in or above the millimeter-wave band and a resin binder. The electromagnetic-wave absorber composition has two or more extrema separated from each other on a differential curve obtained by differentiating a magnetic property hysteresis loop at an applied magnetic field intensity of from 16 kOe to −16 kOe. The electromagnetic-wave absorber includes an electromagnetic-wave absorbing layer formed of the above-described electromagnetic-wave absorber composition.

An iron oxide powder includes a porous structure having the diameter of from 0.3 μm to 2 μm, wherein the iron oxide powder has an aluminum content of from 10 mol % to 80 mol %.

A method for producing an iron pigment and hydrochloric acid with reduced or substantially eliminated waste streams includes: providing an iron chloride solution, wherein the iron chloride solution includes one or both of iron (II) chloride and iron (III) chloride; neutralizing the iron chloride solution with one or both of ammonia and ammonium hydroxide to form a slurry of an iron oxide solid component and an ammonium chloride solution; separating the iron oxide solid component from the ammonium chloride solution; drying the iron oxide solid component to form an iron pigment or pigment intermediate; reacting the ammonium chloride solution with an alkaline-earth metal solid to form an alkaline-earth metal chloride solution and to evolve ammonia as a vapor, wherein at least a portion of the evolved ammonia reacts with water to form ammonium hydroxide; recycling one or both of the evolved ammonia and the formed ammonium chloride for use in connection with the neutralization step; and pyrohydrolyzing the alkaline-earth metal chloride solution to form hydrochloric acid and to regenerate the alkaline-earth metal solid. Iron pigment or pigment intermediate produced in accordance with the method may have a yellow, red, or black color.

Provided is an iron oxide powder for a brake friction material which can be suitably used in a brake friction material that is less likely to cause problems regarding brake squealing and that provides superior braking performance. The iron oxide powder for a brake friction material according to a first embodiment of the present invention is characterized by having a sulfur content of 150 ppm or less as measured by combustion ion chromatography, and a saturation magnetization of 20 emu/g or less. The iron oxide powder for a brake friction material according to a second embodiment of the present invention is characterized by having an average particle size of 1.0 μm or more, a chlorine content of 150 ppm or less as measured by combustion ion chromatography, and a saturation magnetization of 20 emu/g or less.