An anode active material for a sodium ion secondary battery, a sodium ion secondary battery including an anode active material, and an electric device including the sodium ion secondary battery are disclosed. The anode active material for a sodium ion secondary battery includes a cobalt tin spinel oxide represented by Co.sub.2.4Sn.sub.0.6O.sub.4. The sodium ion secondary battery includes an anode made of an anode active material composed of a cobalt tin spinel oxide represented by Chemical Formula 1 below:
Co.sub.2+xSn.sub.1-xO.sub.4,Chemical Formula 1 where x is a real number satisfying 0x0.9; an electrolyte; and a cathode. The sodium ion secondary battery has high capacity characteristics. The electric device including the sodium ion secondary battery includes an electric vehicle, a hybrid electric vehicle, a plug-in hybrid electric vehicle, and an electric power storage system.

Electrode materials for electrochemical cells and batteries and methods of producing such materials are disclosed herein. The electrode materials comprise an active lithium metal oxide material prepared by: (a) contacting the lithium metal oxide material with an aqueous acidic solution containing one or more metal cations; and (b) heating the so-contacted lithium metal oxide from step (a) to dryness at a temperature below 200 C. The metal cations in the aqueous acidic solution comprise one or more metal cations selected from the group consisting of an alkaline earth metal ion, a transition metal ion, and a main group metal ion.

The invention relates to a molecular sieve composition, a process of preparing same and use thereof in the production of lower olefins. The molecular sieve composition comprises an aluminophosphate molecular sieve and a CO adsorbing component, both of which are present independently of each other. When the molecular sieve composition is used as a catalyst for producing lower olefins using synthesis gas as a raw material, the molecular sieve composition has the advantages of high selectivity to lower olefins and the like.

Provided are electrochemically active secondary particles that provide excellent capacity and improved cycle life. The particles are characterized by selectively enriched grain boundaries where the grain boundaries are enriched with Al and Co. The enrichment with Al reduces impedance generation during cycling thereby improving capacity and cycle life. Also provided are methods of forming electrochemically active materials, as well as electrodes and electrochemical cells employing the secondary particles.

Alumina is generally used as an inorganic filler, while spinel, which is known to be lower in thermal conductivity than alumina, is used in applications such as gems, fluorescence emitters, catalyst carriers, adsorbents, photocatalysts and heat-resistant insulating materials, but not expected to be used as a thermally conductive inorganic filler. Thus, an object of the invention is to provide spinel particles having excellent thermal conductive properties. The invention relates to a spinel particle including magnesium, aluminum and oxygen atoms and molybdenum and having a [111] plane crystallite diameter of 220 nm or more.

Exemplary embodiments of positive electrode active materials in the form of single particles, and a method of preparing each of them, are provided.

The single particles of the exemplary embodiments include The single particles are single particles of a nickel-based lithium composite metal oxide, having a plurality of crystal grains, each having a size of 180 nm to 300 nm, as analyzed by a Cu K X-ray (X-r5). The single particles include a metal doped in the crystal lattice thereof. One embodiment includes a surface coating. The total content of the metal doped in the crystal lattice thereof and the metal of the metal oxide coated on the surface thereof is controlled in the range of 2500 ppm to 6000 ppm.

Provided is a magnesium oxide-containing spinel powder capable of producing a ceramic sintered body having high strength and excellent strength stability. In the magnesium oxide-containing spinel powder, a 50% particle diameter (D50) is 0.30 to 10.00 m, a ratio (D90-D50)/(D50-D10) of a difference between a 90% particle diameter (D90) and the 50% particle diameter (D50) and a difference between the 50% particle diameter (D50) and a 10% particle diameter (D10) is 1.0 to 5.0, and a composition ratio of Mg and Al in terms of an oxide equivalent content is 50 to 90% by weight of MgO and 10 to 50% by weight of Al.sub.2O.sub.3.

A method for the rapid and controlled synthesis of mixed metal oxide nanoparticles using relatively low temperature plasma oxidation of liquid droplets of predetermined mixed metal precursors is disclosed. The resulting nanoparticles reflect the metal precursor stoichiometries and the mixed metal oxide's metastable phase can be controlled. The synthesis of mixed transition metal oxide comprising binary metal oxides, ternary mixed metal oxides, quaternary mixed metal oxides and pentanary mixed metal oxides are demonstrated herein.

A positive electrode active material includes a lithium transition metal oxide represented by Formula 1, wherein the lithium transition metal oxide includes a center portion having a layered structure and a surface portion having a secondary phase with a structure different from that of the center portion.

Li.sub.1a(Ni.sub.xCo.sub.yM.sup.1.sub.zM.sup.2.sub.w).sub.1aO.sub.2[Formula 1]

In Formula 1, 0a0.2, 0.6x1, 0y0.4, 0z0.4, and 0w0.1, M.sup.1 includes at least one selected from the group consisting of manganese (Mn) and aluminum (Al), and M.sup.2 includes at least one selected from the group consisting of zirconium (Zr), boron (B), tungsten (W), molybdenum (Mo), chromium (Cr), tantalum (Ta), niobium (Nb), magnesium (Mg), cerium (Ce), hafnium (Hf), lanthanum (La), titanium (Ti), strontium (Sr), barium (Ba), fluorine (F), phosphorus (P), sulfur (S), and yttrium (Y). A method of preparing the positive active material is also provided.

Provided are electrochemically active secondary particles that provide excellent capacity and improved cycle life. The particles are characterized by selectively enriched grain boundaries where the grain boundaries are enriched with Al and Co. The enrichment with Al reduces impedance generation during cycling thereby improving capacity and cycle life. Also provided are methods of forming electrochemically active materials, as well as electrodes and electrochemical cells employing the secondary particles.