The present invention relates to a ceramic solid electrolyte, which is a key component of an all-solid-state lithium secondary battery, for improving safety, and a method for synthesizing the same. The present invention relates to an oxide-based conductive ceramic of a new NASICON structure of the chemical formula Li.sub.1+xAl.sub.xX.sub.2−xP.sub.3O.sub.12 (X is Zr, Si, Sn, or Y, 0<x<2) or Li.sub.1+xZr.sub.2X.sub.xP.sub.3−xO.sub.12 (X=Si, Sn, Ge, or Y, 1.5≤x≤2.3). The present invention relates to a method for manufacturing an oxide-based conductive ceramic having the above novel NASICON structure.

The present disclosure relates to a solid electrolyte containing a halide-based nanocomposite, a method for preparing the same and an all-solid-state battery including the solid electrolyte. Halide-based nanocomposites were prepared by the mechanochemical reaction of a lithium oxide precursor, a lithium halide precursor, and a metal halide in order to improve the low ion conductivity and large interfacial resistance of the existing halide-based solid electrolyte. Furthermore, it is possible to provide superior atmospheric stability, improve ion conductivity through activation of interfacial conduction and, at the same time, significantly improve the interfacial stability with a sulfide-based solid electrolyte and high-voltage cycle stability.

Methods of synthesis of mesoporous silica are disclosed. The mesoporous silica synthesized herein, like SBA-15, possesses a two-dimensional, hexagonal, through-hole structure with a space group p6mm. An effective quantity of one or more water-soluble oxidized disulfide oil (ODSO) compounds are used during synthesis to impart distinct characteristics.

Provided are a barium titanate powder having spherical shape fine particles which have an average particle diameter (D.sub.50) in a range of about 140-270 nm, a tetragonal structure having a markedly improved tetragonality (c/a) in a range of 1.007-1.01 in contrast to the conventional composition, and at the same time, a markedly improved crystallinity in a range of 93-96%, thereby showing improved dielectric properties, and a manufacturing method thereof.

In a case where a detector is positioned in a [11-20] direction, and where a first measurement region including a center of a main surface is irradiated with an X ray in a direction within ±15° relative to a [−1-120] direction, a ratio of a maximum intensity of a first intensity profile is more than or equal to 1500. In a case where the detector is positioned in a direction parallel to a [−1100] direction, and where the first measurement region is irradiated with an X ray in a direction within ±6° relative to a [1-100] direction, a ratio of a maximum intensity of a second intensity profile is more than or equal to 1500. An absolute value of a difference between maximum value and minimum value of energy at which the first intensity profile indicates a maximum value is less than or equal to 0.06 keV.

A material of formula Li.sub.aTi.sub.b(A.sub.xS.sub.3-x).sub.c wherein A is a metalloid element chosen from selenium, tellurium and mixtures thereof, and the stoichiometric coefficients a, b, c and x are such that 0<x<2.2; 0.4≤a≤4.5; 0.9≤b≤1.1; and 0.9≤c≤1.1.

A method of preparing a lithium-ion conducting garnet via low-temperature solid-state synthesis is disclosed. The lithium-ion conducting garnet comprises a substantially phase pure aluminum-doped cubic lithium lanthanum zirconate (Li.sub.7La.sub.3Zr.sub.2O.sub.14). The method includes preparing nanoparticles comprising lanthanum zirconate (La.sub.2Zr.sub.2O.sub.7-np) via pyrolysis-mediated reaction of lanthanum nitrate (La(NO.sub.3).sub.3) and zirconium nitrate (Zr(NO.sub.3).sub.4). The method also includes pyrolyzing a solid-state mixture comprising the La.sub.2Zr.sub.2O.sub.7-np, lithium nitrate (LiNO.sub.3), and aluminum nitrate (Al(NO.sub.3).sub.3) to give the Li.sub.7La.sub.3Zr.sub.2O.sub.14 and thereby prepare the lithium-ion conducting garnet. A lithium-ion conducting garnet prepared via the method is also disclosed.

A lithium-ion conducting composite material includes a Li binary salt, a Li-ion conductor with a chemical composition of Li.sub.2−3x+y−zFe.sub.xO.sub.y(OH).sub.1−yCl.sub.1−z, and at least two of: a first inorganic compound with a chemical composition of (Fe.sub.1−xM1.sub.x)O.sub.1−y(OH).sub.yCl.sub.1−x; a second inorganic compound with a chemical composition of M2OX; and a defected doped inorganic compound with a chemical composition of (M3OX)′. The value of n is 1 or 2, x is greater than 0 and less than or equal to 0.25, and y is greater than or equal to 0 and less than or equal to 0.25. Also, M1 is at least one of Mg and Ca, M2 and M3 are each at least one of Fe, Al, Sc, La, and Y, and X is at least one of F, Cl, Br, and I.

A silver-doped, nano-porous hydroxyapatite material is provided that can be utilized to capture radioactive iodine, .sup.129I. Methods of using the silver-doped, nano-porous hydroxyapatite material to remove radioactive iodine, and methods of manufacturing the material are also provided.

A process for the recovery of lithium from waste lithium ion batteries or parts thereof is disclosed. The process comprising the steps of A) providing a crude lithium hydroxide as a solid, which contains fluoride; and (B) dissolving the crude lithium hydroxide solid with a lower alcohol such as methanol or ethanol provides good separation of lithium in high purity.