A preparation method of silicon-based composite negative electrode material for a lithium battery includes the following steps: forming steam from a raw material A containing Si and a reducing substance raw material B capable of reacting to generate a silicate under a vacuum heating condition, condensing and depositing in a deposition system after a reaction, and then carrying out carbon coating to obtain the silicon-based composite material. A certain amount of alloy is added into the raw material B, so that a proportion of a crystal region in the silicon-based composite material can be reduced, and the initial coulombic efficiency and the cycling stability of the negative electrode material are further improved.

A cathode active material for a lithium secondary battery includes a lithium-transition metal composite oxide particle having a lattice strain (η) of 0.18 or less, which is calculated by applying Williamson-Hall method defined by Equation 1 to XRD peaks measured through XRD analysis, and having an XRD peak intensity ratio of 8.9% or less, which is defined by Equation 2. By controlling the lattice strain and XRD peak intensity ratio of the lithium-transition metal composite oxide particle, a lithium secondary battery with improved life-span characteristics as well as output characteristics is provided.

The instant disclosure sets forth multiphase lithium-stuffed garnet electrolytes having secondary phase inclusions, where-in these secondary phase inclusions are material(s) which is/are not a cubic phase lithium-stuffed garnet but which is/are entrapped or enclosed within a lithium-stuffed garnet. When the secondary phase inclusions described herein are included in a lithium-stuffed garnet at 30-0.1 volume %, the inclusions stabilize the multiphase matrix and allow for improved sintering of the lithium-stuffed garnet. The electrolytes described herein, which include lithium-stuffed garnet with secondary phase inclusions, have an improved sinterability and density compared to phase pure cubic lithium-stuffed garnet having the formula Li.sub.7La.sub.3Zr.sub.2O.sub.12.

A tungsten(VI) oxytetrachloride having a chemical purity of greater than 99.95%. The tungsten(VI) oxytetrachloride has a fraction of compounds selected from WCl.sub.6, WO.sub.2Cl.sub.2, WO.sub.3 and WO.sub.2, as defined as a ratio of a reflection having a highest intensity of one of WCl.sub.6, WO.sub.2Cl.sub.2, WO.sub.3 and WO.sub.2, (I(P2)100) in an x-ray diffraction pattern to a reflection having a highest intensity of the tungsten(VI) oxytetrachloride (I(WOCl.sub.4)100) in the x-ray diffraction pattern, expressed as I(P2)100/I(WOCl.sub.4)100, of less than 0.03.

This positive electrode active material for nonaqueous electrolyte secondary batteries contains: a lithium transition metal composite oxide having secondary particles, each of which is formed of aggregated primary particles; and a surface modification compound which is present on at least the surfaces of the secondary particles, while containing at least one of Ca and Sr. The lithium transition metal composite oxide contains 70% by mole or more of Ni relative to the total number of moles of the metal elements excluding Li; and the total amount of Ca and Sr in the surface modification compound is 0.5% by mole or less relative to the total number of moles of the metal elements excluding Li in the lithium transition metal composite oxide.

Provided are a nano-sized thin sheet-like pseudoboehmite and a method of producing the same. The method of producing a sheet-like pseudoboehmite is performed by a one-pot method, unlike the conventional method of performing the reaction first in a basic solution, and then performing redispersion in an acidic solution, thereby simplifying the production process, and thus, may be useful in the production industry of a separator for a secondary battery, and the like.

A lithium-ion battery anode material containing surface-coated disordered rocksalt lithium vanadium oxide is disclosed. The surface coating contains a species selected from the group consisting of carbon, a metal oxide, a metalloid oxide, a metal fluoride, a metalloid fluoride, a metal phosphate, a metalloid phosphate, and combinations thereof. Materials, designs, synthesis methods, and devices related to fast-charging lithium-ion batteries are provided. This invention fills a technology gap by providing anode materials with disordered rocksalt lithium vanadium oxides to achieve fast charging in 10 minutes or less, greater than 200 W.Math.h/kg energy density, a lifetime of at least 10,000 cycles, and improved battery safety. Methods of making and using the optionally surface-coated disordered rocksalt lithium vanadium oxide are disclosed. Many experimental examples are included, demonstrating several remarkable attributes of this battery technology.

Highly heat-resistant anatase-type titanium oxide particles stably retard an anatase-type crystal phase having excellent reactivity in a temperature range of 700° C., and have fine particles and a uniform particle size distribution. The highly heat-resistant anatase-type titanium oxide includes titanium oxide particles having a content of an anatase crystal phase in the total crystal phases of 85% or more and a modification layer provided on the surfaces of the titanium oxide particles. The modification layer is obtained by modifying an organic acid having a molecular weight of 200 or less with an acidic solution containing 1.5×10.sup.−4 mol/L or more and 0.12 mol/L or less. The pH of the acidic solution is 0.2 to 5.

An anode material, including a matrix material, and the matrix material comprises carbon-doped silicon monoxide, and a content of the carbon ranges from 0.5% to 10% based on a total mass of the carbon and silicon monoxide. The anode material can significantly improve the cycle performance of an electrochemical device at room temperature and high temperature.

A positive electrode active material precursor for a lithium secondary battery containing at least Ni, in which S/D.sub.50 that is a ratio of a BET specific surface area S to a 50% cumulative volume particle size D.sub.50 is 2×10 to 20×10.sup.6 m/g, and, in powder X-ray diffraction measurement using a CuKα ray, A/B that is a ratio of an integrated intensity A of a diffraction peak within a range of 2θ=37.5±1° to an integrated intensity B of a diffraction peak within a range of 2θ=62.8±1° is more than 0.80 and 1.33 or less.