Provided is an anode for a lithium battery or sodium battery, the anode comprising multiple porous graphene balls and multiple particles or coating of a lithium-attracting metal or sodium-attracting metal at a graphene ball-to-metal volume ratio from 5/95 to 95/5, wherein the porous graphene ball comprises a plurality of graphene sheets forming into the ball having a diameter from 100 nm to 20 μm and a pore or multiple pores having a pore volume fraction from 10% to 99.9% based on the total graphene ball volume, and wherein the particles or coating of lithium-attracting metal or sodium-attracting metal, having a diameter or thickness from 1 nm to 20 μm, are selected from Au, Ag, Mg, Zn, Ti, K, Al, Fe, Mn, Co, Ni, Sn, V, Cr, an alloy thereof, or a combination thereof.

The present disclosure is directed to novel germanosilicate compositions and methods of producing and using the same. Included among the new materials are the new germanosilicates of CIT-5 topology having Si:Ge ratios either in a range of from 3.8 to 5.4 or from 30 to 200, with and without added metal oxides. The disclosure also describes methods of preparing and using these new germanosilicate compositions as well as the compositions themselves.

The present disclosure is directed to novel germanosilicate compositions and methods of producing and using the same. In particular, this disclosure describes new germanosilicates of CIT-14 topology. The disclosure also describes methods of preparing and using these new germanosilicate compositions as well as the compositions themselves.

A manganese oxide, a manganese oxide/carbon mixture and a manganese oxide composite electrode material, having high catalytic activity produced at low cost, to be used as an anode catalyst for oxygen evolution in water electrolysis, and their production methods, are provided. A manganese oxide for an oxygen evolution electrode catalyst in water electrolysis is provided, which is a manganese oxide having a metallic valence of higher than 3.0 and at most 4.0, having an average primary particle size of at most 80 nm and an average secondary particle size of at most 25 μm, a manganese oxide/carbon mixture for an oxygen evolution electrode catalyst in water electrolysis, having a proportion of manganese oxide to the total of the manganese oxide and electrically conductive carbon of from 0.5 to 40 wt %, and a manganese oxide composite electrode material which includes an electrically conductive substrate constituted by fibers.

Provided are a barium germanium oxide having a 3-4 eV band gap, a method for producing the same, a sintered body thereof, and a target thereof. The barium germanium oxide includes at least Ba, Ge, and O, includes a crystal represented by a general formula of ABO.sub.3 (here, A includes at least Ba and B includes at least Ge), and has a hexagonal 6H-type perovskite structure.

A hydroprocessing catalyst or catalyst precursor has been developed. The catalyst is a poorly crystalline transition metal molybdotungstate material or a metal sulfide decomposition product thereof. The hydroprocessing using the crystalline ammonia transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

The present invention provides a carbonaceous material suitable for a negative electrode active material for non-aqueous electrolyte secondary batteries (e.g., lithium ion secondary batteries, sodium ion secondary batteries, lithium sulfur batteries, lithium air batteries) having high charge/discharge capacities, and preferably high charge/discharge efficiency and low resistance, a negative electrode comprising the carbonaceous material, a non-aqueous electrolyte secondary battery comprising the negative electrode, and a production method of the carbonaceous material. The present invention relates to a carbonaceous material having a nitrogen content obtained by elemental analysis of 3.5 mass % or more, a ratio of nitrogen content and hydrogen content (R.sub.N/H) of 6 or more and 100 or less, a ratio of oxygen content and nitrogen content (R.sub.O/N) of 0.1 or more and 1.0 or less, and a carbon interplanar spacing (d.sub.002) observed by X-ray diffraction measurement of 3.70 or more.

The present invention relates to entangled-type carbon nanotubes which have a bulk density of 31 kg/m.sup.3 to 85 kg/m.sup.3 and a ratio of tapped bulk density to bulk density of 1.37 to 2.05, and a method for preparing the entangled-type carbon nanotubes.

The invention relates to a process for delamination of a layered silicate in an aqueous medium, wherein in a first step a layered silicate having a layer charge L.sub.c from 0.25 to 1.0 and a charge equivalent area A.sub.s=47.6 .sup.2/(2L.sub.c), is treated with a delamination agent, and in a second step the thus treated layered silicate is contacted with an aqueous medium, whereby the delamination agent is a compound having exactly one positively charged atom, the positively charged atom being selected from the group consisting of nitrogen and phosphorous; contains of functional groups selected from the group consisting of hydroxyl groups, ether groups, sulfonic acid ester groups and carboxylic acid ester groups, n.sub.f being a number from 1 to 10; comprises a total number of carbon atoms n.sub.c being from 2 to 20; has a ratio n.sub.c/(1+n.sub.f) from 1 to 5, wherein n.sub.c is the total number of carbon atoms of the delamination agent and n.sub.f is the total number of functional groups in the delamination agent as defined under ii.; and has a charge equivalent area A.sub.d being from at least 0.90-fold to 3-fold of the charge equivalent area of the layered silicate A.sub.s; and wherein the delamination agent is used to treat the layered silicate in an amount of at least equal to the cation exchange capacity of the layered silicate, with the proviso that n.sub.f2, if L.sub.c0.6. The invention further relates to the thus produced delaminated layered silicates, their use in the production of composite and coating material and as a barrier material. Moreover, the invention relates to compositions containing the thus produced delaminated layered silicates.

Particles with suitable properties may be generated using systems and methods provided herein. The particles may include carbon particles.