C01P2002/86

Lithium ion conductive sulfide-based solid electrolyte with controlled halogen elements content and method of preparing the same

Disclosed are a sulfide-based solid electrolyte imparted with improved lithium ion conductivity and a method of preparing the same. More particularly, disclosed is a sulfide-based solid electrolyte containing a lithium element (Li), a phosphorus element (P), a sulfur element (S) and a halogen element (X), and including a crystal phase of an argyrodite crystal structure, wherein a molar ratio (X/P) of the halogen element (X) to the phosphorus element (P) is higher than 1.

Solid conductor, preparation method thereof, solid electrolyte including the solid conductor, and electrochemical device including the solid conductor

A solid conductor including: a compound represented by Formula 1, a compound represented by Formula 2, or a combination thereof
Li.sub.1+x+y−zTa.sub.2−xM.sub.xP.sub.1−yQ.sub.yO.sub.8−zX.sub.z  Formula 1
wherein, in Formula 1, M is an element having an oxidation number of +4, Q is an element having an oxidation number of +4, X is a halogen, a pseudohalogen, or a combination thereof, and 0≤x≤2, 0≤y<1, and 0≤z≤2, except that cases i) x and y and z are simultaneously 0, ii) M is Hf, X is F, x is 1, y is 0, and z is 1, iii) M is Hf, X is Cl, x is 2, y is 0, and z is 2, and iv) M is Hf, X is F, x is 2, y is 0, and z is 2,
Li.sub.1+x+y−zTa.sub.2−xM.sub.xP.sub.1−yQ.sub.yO.sub.8.Math.zLiX  Formula 2
wherein, in Formula 2, M is an element having an oxidation number of +4, Q is an element having an oxidation number of +4, X is a halogen, a pseudohalogen, or a combination thereof, and 0≤x≤2, 0≤y<1, and 0≤z2, except that cases i) x and y and z are simultaneously 0, ii) M is Hf, X is F, x is 1, y is 0, and z is 1, iii) M is Hf, X is Cl, x is 2, y is 0, and z is 2, and iv) M is Hf, X is F, x is 2, y is 0, and z is 2.

EFFECT PIGMENTS COATED WITH ORGANIC BINDERS FOR POWDER PAINTS, AND A METHOD FOR PRODUCING SAID COATED EFFECT PIGMENTS AND THEIR USE
20230250298 · 2023-08-10 ·

The invention relates to coated effect pigments, wherein the coating comprises a binder which is suitable for powder paints. They comprise a crystalline and an amorphous fraction which is determined by C.sup.13 NMR MAS relaxation measurements, the relaxation of the .sup.13C cores being fitted as a biexponential relaxation according to the formula (II) and the degree of crystallinity c being in a range between 40 to 85%, and relaxation having a short average relaxation time T.sub.1.sup.s and a long average relaxation time T.sub.1.sup.l, and T.sub.1.sup.l being in a range of from 65 to 130 s. The effect pigments coated according to the invention have at least one endothermic peak with a maximum from a range of T.sub.max=100 to 150° C. and an enthalpy ΔH associated with said peak from a range of 15 J/g to 80 J/g in DSC at a feed speed of 5° C./min, the enthalpy being calculated relative to the amount of the binder. The binders are applied to the effect pigment by way of spontaneous precipitation.

Negative electrode active material, mixed negative electrode active material, negative electrode for nonaqueous electrolyte secondary battery, lithium ion secondary battery, and method for producing negative electrode active material

A negative electrode active material includes: particles of negative electrode active material, the particles of negative electrode active material contain particles of silicon compound containing a silicon compound (SiO.sub.x:0.5≤x≤1.6); the particles of silicon compound contain at least one kind or more of Li.sub.2SiO.sub.3 and Li.sub.4SiO.sub.4; the particles of negative electrode active material contain Li.sub.2CO.sub.3 and LiOH on a surface thereof; and a content of the Li.sub.2CO.sub.3 is 0.01% by mass or more and 5.00% by mass or less relative to a mass of the particles of negative electrode active material and a content of the LiOH is 0.01% by mass or more and 5.00% by mass or less relative to the mass of the particles of negative electrode active material. Thus a negative electrode active material is capable of improving initial charge/discharge characteristics and the cycle characteristics when used as a negative electrode active material of the secondary battery.

Calcium-alumino-silicate-hydrate nano-seeds suspension and preparation method thereof

The invention discloses a calcium-alumino-silicate-hydrate nano-seeds suspension and preparation method thereof. The preparation method of calcium-alumino-silicate-hydrate nano-seeds suspension includes the following steps: dropwise adding the aqueous solution of calcium source, the aqueous solution of silicon source and the aqueous solution of aluminum source to the solution of polycarboxylate superplasticizer, and adjusting the pH value to 10.0˜13.5, and continuously stirring to obtain the calcium-alumino-silicate-hydrate nano-seeds suspension. The beneficial effect in the present invention is: the calcium-alumino-silicate-hydrate nano-seeds has small particle size, good dispersion stability, and it can effectively improve the early hydration and mechanical performance of cement-based materials, and has good application prospects; the preparation process is simple, without washing, drying, ultrasonic dispersion and other subsequent processes, suitable for large-scale production.

AEROGEL AND PRODUCTION METHOD THEREFOR
20220119266 · 2022-04-21 · ·

A production method for an aerogel includes a sol generation step by adding a silicon compound to an aqueous solution containing an acid catalyst and performing hydrolysis, where the silicon compound contains at least a quadri-functional silane compound and a tri-functional silane compound among quadri-functional silane compounds, tri-functional silane compounds, and di-functional silane compounds, the density of the aerogel is 0.15 g/cm.sup.3 or less, for example the silicon compound is a mixture of a quadri-functional silane compound, a tri-functional silane compound, and a di-functional silane compound having portions satisfying 0<Qx<50, 50≤Tx<100, 0≤Dx<30, and Qx+Tx+Dx=100, where Qx, Tx, and Dx represent the mass percentages of the quadri-functional silane compound, the tri-functional silane compound, and the di-functional silane compound, respectively. This provides aerogel having excellent thermal insulating characteristics and a large area.

Compact and homogeneous quantum dots and methods of making the same

The present disclosure provides quantum dots and methods of making the quantum dots comprising a substantially homogeneous population of monomeric nanocrystals, of a very small size, about 7 nm to about 12 nm in diameter. The method comprises mixing a nanocrystal coated with weakly binding ligands or ions with a polymer in a solution and incubating at a temperature greater than about 100° C., thereby forming a quantum dot having a substantially homogenous population of monomeric nanocrystals. The quantum dots can be further conjugated to bioaffinity molecules, enabling broad utilization of compact, biofunctional quantum dots for studying crowded macromolecular environments.

POST-SYNTHETIC DOWNSIZING ZEOLITE-TYPE CRYSTALS AND/OR AGGLOMERATES THEREOF TO NANOSIZED PARTICLES

The present invention relates to a method of post-synthetic downsizing zeolite-type crystals and/or agglomerates thereof to nanosized particles, and in particular a heating-free and chemical-free method. The present invention also relates to nanosized particles of zeolite-type material capable of being obtained by the method of the invention and to the use of such particles as a catalyst or catalyst support for heterogeneous catalyst, or as molecular sieve, or as a cation exchanger.

PROCESS FOR PREPARING COMPOUNDS FOR TYRES AND TYRES COMPRISING THEM

The present invention relates to a compound represented by the formula (II): CB-O-ROS-GC-Zn (II) where CB represents the white filler, O represents one or more oxygen bridge bonds, ROS represents an organo-silane residue, GC represents one or more coordinating groups forming a chelate with zinc in ionic form represented by linear, branched or cyclic alkyl chains, comprising one or more heteroatoms inside or at the end of the alkyl chain, and Zn represents zinc in ionic form coordinated with the coordinating groups, a process for the preparation thereof, and the use thereof in the vulcanisation process of elastomeric compounds.

NOVEL PERCHLORINATED DISILENES AND GERMASILENES AND ALSO NEOPENTATETRELANES, A METHOD FOR THE PREPARATION THEREOF AND USE THEREOF

The invention provides disilenes, germasilenes and neopentatetrelanes, a method for the preparation thereof and use thereof.