Patent classifications
C01P2002/86
Negative electrode active material, mixed negative electrode active material, and method for producing negative electrode active material
A negative electrode active material including a negative electrode active material particle. The negative electrode active material particle includes a silicon compound particle including a silicon compound (SiO.sub.x: 0.5≤x≤1.6). The silicon compound particle includes crystalline Li.sub.2SiO.sub.3 in at least part of the silicon compound particle. Among a peak intensity A derived from Li.sub.2SiO.sub.3, a peak intensity B derived from Si, a peak intensity C derived from Li.sub.2Si.sub.2O.sub.5, and a peak intensity D derived from SiO.sub.2 which are obtained from a .sup.29Si-MAS-NMR spectrum of the silicon compound particle, the peak intensity A is the highest intensity, and the peak intensity A and the peak intensity C satisfy a relationship of the following formula 1.
3C<A Formula 1:
Method for producing solid electrolyte, and electrolyte precursor
A method of producing a solid electrolyte having a high ionic conductivity, which adopts a liquid-phase method and suppresses the generation of hydrogen sulfide, wherein a raw material inclusion containing a lithium element, a sulfur element, a phosphorus element, and a halogen element is mixed with a complexing agent containing a compound having at least two tertiary amino groups; and an electrolyte precursor constituted of a lithium element, a sulfur element, a phosphorus element, a halogen element, and a complexing agent containing a compound having at least two tertiary amino groups.
NEGATIVE ELECTRODE ACTIVE MATERIAL, MIXED NEGATIVE ELECTRODE ACTIVE MATERIAL, AND METHOD FOR PRODUCING NEGATIVE ELECTRODE ACTIVE MATERIAL
A negative electrode including a negative electrode active material layer including a negative electrode active material including a negative electrode active material particle. The negative electrode active material particle includes a silicon compound particle including a silicon compound (SiOx: 0.5≤x≤1.6). The silicon compound particle includes crystalline Li2SiO3 in at least part of the silicon compound particle. Among a peak intensity A derived from Li2SiO3, a peak intensity B derived from Si, a peak intensity C derived from Li2Si2O5, and a peak intensity D derived from SiO2 which are obtained from a 29Si-MAS-NMR spectrum of the silicon compound particle, the peak intensity A is the highest intensity, and the peak intensity A and the peak intensity C satisfy a relationship of the following formula 1:
Formula 1: 3C<A
Graphene material inlaid with single metal atoms and preparing method and application thereof
The present invention relates to a graphene material inlaid with single metal atoms, the preparation method thereof and its application of being used as the catalyst for the electroreduction of carbon dioxide. The graphene material inlaid with single metal atoms comprises single metal atoms and graphene; the single metal atoms are dispersed in the framework of the graphene; and the graphene is at least one selected from N doped graphene and N and S co-doped graphene. The material is used for the electrochemical reduction reaction of carbon dioxide, which significantly improves the utilization efficiency of the metal atoms and enhances the catalytic activity for the electroreduction of carbon dioxide, improves the catalytic stability, inhibits effectively the hydrogen evolution reaction, improves the selectivity for CO product, and broadens the electric potential window of reducing carbon dioxide to generate CO.
AEI type zeolite, method for producing same, and uses thereof
Provided is a method for producing an inexpensive, high-performance AEI type zeolite and an AEI type zeolite having a Si/Al ratio of 6.5 or less and an acidity of 1.2 mmol/g or more and 3.0 mmol/g or less, by using neither an expensive Y type zeolite as a raw material nor dangerous hydrofluoric acid. The method for producing an AEI type zeolite having a Si/Al ratio of 50 or less includes: preparing a mixture including a silicon atom material, an aluminum atom material, an alkali metal atom material, an organic structure-directing agent, and water; and performing hydrothermal synthesis of the obtained mixture, in which a compound having a Si content of 20% by weight or less and containing aluminum is used as the aluminum atom material; and the mixture includes a zeolite having a framework density of 14 T/1000 Å.sup.3 or more in an amount of 0.1% by weight or more with respect to SiO.sub.2 assuming that all Si atoms in the mixture are formed in SiO.sub.2.
SnTiO3 MATERIAL, METHOD OF PREPARATION THEREOF, USE THEREOF AS FERROELECTRIC MATERIAL AND DEVICE COMPRISING A FERROELECTRIC MATERIAL
The present invention relates to a material of the formula SnTiO.sub.3 having a crystal structure comprised of layers, wherein the layers comprise Sn(II) ions, Ti(IV) ions and edge-sharing O.sub.6-octahedra, the edge-sharing O.sub.6-octahedra form a sub-layer, the Ti(IV) ions are located within ⅔ of the edge-sharing O.sub.6-octahedra, thus forming edge-sharing TiO.sub.6-octahedra, the edge-sharing TiO.sub.6-octahedra form a honeycomb structure within the sub-layer, the honeycomb structure comprising hexagons with Ti(IV)-vacancies within the hexagons, the Sn(II) ions are located above and below the Ti(IV)-vacancies with respect to the sub-layer, the Ti(IV) ions are optionally substituted with M, M is one or more elements selected from Group 4 and Group 14 elements, and the crystal structure satisfies at least one of the following features (i) and (ii): (i) the Sn(II) ions have a tetrahedral coordination sphere involving three O ions of the layer and the electron lone pair of the Sn(II) ions which is situated at an apical position relative to the three O ions of the layer, (ii) the layers are stacked so that each layer is translated relative to each adjacent layer by a stacking vector S1 or a stacking vector S2, the centers of adjacent hexagons form a parallelogram with a side having a length x and side having a length y, the stacking vector S1 is a combined translation along the side having the length x by ⅔ x and along the side having a lengthy by ⅓ y, the stacking vector S2 is a combined translation along the side having the length x by ⅓ x and along the side having a lengthy by ⅔ y, and the crystal structure comprises layers translated relative to adjacent layers by the stacking vector 1 and layers translated relative to adjacent layers by the stacking vector S2. The present invention is further directed to a material of the formula SnTiO.sub.3 having a tetragonal perovskite-type crystal structure, a method for the preparation of SnTiO.sub.3, a device comprising a ferroelectric material and a use of the material of the formula SnTiO.sub.3 in a ferroelectric element.
Reinforcement materials, elastomeric compositions and tyres for vehicles wheels comprising the same
The present invention relates to new elastomeric materials for the production of tyres for vehicle wheels with good mechanical properties, in particular high moduli associated with low hysteresis values, including new reinforcement materials. Said reinforcement materials are obtainable by derivatising silica—in-situ during the mixing of the elastomeric composition, or previously—with special silanising agents (A) and silsesquioxanes (B), both substituted with reactive alkenyl functionalities.
A PROCESS FOR PREPARING A ZEOLITIC MATERIAL HAVING FRAMEWORK TYPE AEI
The present disclosure relates to a process for preparing a zeolitic material having framework type AEI and having a framework structure which comprises a tetravalent element Y, a trivalent element X, and O. Further, the present invention disclosure relates to a zeolitic material having framework type AEI and having a framework structure which comprises a tetravalent element Y, a trivalent element X, and O, preferably obtained by the process, and further relates to the use of the zeolitic material as a catalytically active material, as a catalyst, or as a catalyst component.
SULFIDE SOLID ELECTROLYTE AND ALL SOLID STATE BATTERY
A sulfide solid electrolyte is capable of suppressing a decrease in Li ion conductivity due to moisture. A sulfide solid electrolyte includes a Li element, a P element, a S element and an O element, and having a granular shape, and including a crystal portion oriented along the granular shape, on an inner surface of the sulfide solid electrolyte.
METHOD FOR PRODUCING SOLID ELECTROLYTE, AND ELECTROLYTE PRECURSOR
A method of producing a solid electrolyte having a high ionic conductivity, which adopts a liquid-phase method and suppresses the generation of hydrogen sulfide, wherein a raw material inclusion containing a lithium element, a sulfur element, a phosphorus element, and a halogen element is mixed with a complexing agent containing a compound having at least two tertiary amino groups; and an electrolyte precursor constituted of a lithium element, a sulfur element, a phosphorus element, a halogen element, and a complexing agent containing a compound having at least two tertiary amino groups.