A catalyst-free synthesis method for the formation of a metalorganic compound comprising a desired (first) metal may include, for example, selecting another (second) metal and an organic solvent, with the second metal being selected to (i) be more reactive with respect to the organic solvent than the first metal and (ii) form, upon exposure of the second metal to the organic solvent, a reaction by-product that is more soluble in the organic solvent than the metalorganic compound. An alloy comprising the first metal and the second metal may be first produced (e.g., formed or otherwise obtained) and then treated with the organic solvent in a liquid phase or a vapor phase to form a mixture comprising (i) the reaction by-product comprising the second metal and (ii) the metalorganic compound comprising the first metal. The metalorganic compound may then be separated from the mixture in the form of a solid.

This disclosure provides systems, methods, and apparatus related to color centers. In one aspect, a method includes providing diamond doped with a dopant. A heavy-ion is directed to the diamond that passes through the diamond. The heavy-ion forms a line of dopant-vacancy centers as it passes through the diamond.

Cellulose-nanofiber carbon which can achieve a large specific surface area, and a method of producing the same are provided. The method for heat treating a cellulose nanofiber for carbonization includes: a freezing step of freezing a solution or gel containing the cellulose nanofiber to obtain a frozen product a drying step of drying the frozen product in a vacuum to obtain a dried product and a carbonizing step of heating and carbonizing the dried product in an atmosphere which does not burn the dried product to obtain the cellulose-nanofiber carbon.

The present invention relates to a method for manufacturing a structure of a titanium compound selected from the group consisting of sheets, wires and tubes. The present invention also relates to intermediate products and structures comprising titanium dioxide obtainable by the method. The invention provides an improved method giving improved yield as well as other advantages.

The present disclosure is directed to methods of Quantum Spin Engineering of spinel superparamagnetic ferrite nanoparticles (SMFNs) for MRI contrast agents and for magnetohyperthermia agents. Using the methods herein, the magnetic properties of the SMFNs can be controlled by changing the amount of 3d-transition element cations having unpaired electrons in the 3d orbital that occupy the octahedral sites of the spinel crystal form, to form mixed spinels, while anions in the spinels can be utilized to magnetically couple the cations utilizing intra-crystalline angles determined by ion sizes and crystal structure, and further tuning of other critical parameters is provided. The mixed spinels disclosed herein provide enhanced MRI contrast agents and improved magnetohyperthermia agents with lower toxicity and safety concerns, while the production methods disclosed herein have lower cost.

A process for producing a process for producing a LnM.sub.2Cu.sub.3O.sub.x high-temperature superconductive powder, the process comprising: i) providing an aqueous solution of Ln, M and Cu and at least one mineral acid; ii) adding at least one sequestrating agent and, optionally, at least one dispersant to the solution to form a precipitate; iii) recovering the precipitate from the solution; and iv) heating the precipitate in a flow of oxygen to form the LnM.sub.2Cu.sub.3O.sub.x powder, wherein Ln is a rare earth element, preferably Y, Ce, Dy, Er, Gd, La, Nd, Pr, Sm, Sc, Yb, or a mixture of two or more thereof, and wherein M is selected from Ca, Sr, and Ba.

A catalyst-free synthesis method for the formation of a metalorganic compound comprising a desired (first) metal may include, for example, selecting another (second) metal and an organic solvent, with the second metal being selected to (i) be more reactive with respect to the organic solvent than the first metal and (ii) form, upon exposure of the second metal to the organic solvent, a reaction by-product that is more soluble in the organic solvent than the metalorganic compound. An alloy comprising the first metal and the second metal may be first produced (e.g., formed or otherwise obtained) and then treated with the organic solvent in a liquid phase or a vapor phase to form a mixture comprising (i) the reaction by-product comprising the second metal and (ii) the metalorganic compound comprising the first metal. The metalorganic compound may then be separated from the mixture in the form of a solid.

Provided are group-III nitride nanoparticles that prevent the piezoelectric field caused by strains on the nanoparticles, achieving good luminous efficiency. The group-III nitride nanoparticle represented by Al.sub.xGa.sub.yIn.sub.zN (0≤x, y, z≤1) incorporating two crystal structures; a wurtzite structure and a zincblende structure, in a single particle. As another example, the group-III nitride nanoparticle has a core-shell structure with a core and a shell, in which the particle constituting the core contains two crystal structures; the wurtzite structure and the zincblende structure, in the particle. Nanoparticles containing the two crystal structures can be produced by using a phosphorus-containing solvent as a reaction solvent, and the mixture ratio of the two crystal structures, (wurtzite structure)/(zincblende structure), is 20/80 or higher.

The present disclosure relates to a system and a method for preparing carbon nanofiber and hydrogen through continuous microwave pyrolysis. The system includes four apparatus. The melting and feeding apparatus is to heat and melt feedstocks. The microwave pyrolysis apparatus is for catalytic pyrolysis and includes a feedstock inlet, a gas outlet and a carbon outlet. The gas purification and utilization apparatus is for hydrogen purification and residual gas separation, The power generation apparatus includes a generator and a small internal combustion engine utilizing residual gas as fuel, and the generated smoke is conveyed to the melting and feeding apparatus for feedstocks melting. According to the present disclosure, a poly-generation system for co-producing high-performance carbon materials and hydrogen through plastic wastes with greatly increased energy utilization rate is formed to solve the technical problems of low product yield and high energy consumption in traditional pyrolysis.

Nanostructured aluminosilicates including aluminosilicate nanorods are formed by heating a geopolymer resin containing up to about 90 mol % water in a closed container at a temperature between about 70° C. and about 200° C. for a length of time up to about one week to yield a first material including the aluminosilicate nanorods. The aluminosilicate nanorods have an average width of the between about 5 nm and about 30 or between about 5 nm and about 60 nm or between about 5 nm and about 100 nm, and a majority of the aluminosilicate nanorods have an aspect ratio between about 2 and about 100.