An asymmetric system containing a first conductive polymer modified with a redox active moiety and a second conductive polymer modified with a surfactant is used for the separation of organic compounds from aqueous solutions. The asymmetric system has complementary hydrophobicity tunability in response to electrochemical modulations. For example, both materials are hydrophobic in their respective neutral states, therefore exhibiting affinity toward organic compounds. Application of a mild potential drives the desorption of the organic compounds and regeneration of the materials. The asymmetric system can be used in a cyclic fashion, through repeated electrical discharge or shorting of the two electrodes to program the capture of organics from a feed solution, and application of a potential to stimulate the release of the adsorbed organics.

Use of poly(alkylamine)-derived (PAD) self-supported cross-linked polymeric ammonium salts and ionomer hydrogels for adsorbing and desorbing organic contaminants, specifically per and polyfluoro alkyl substances (PFAS) from water.

A method and apparatus for collection and disposal or utilization as a carbon neutral fuel of fats, oil and grease that includes a first porous container, a second porous container, and a grease trap having an inlet and an outlet. The first porous container is positioned proximate the grease trap inlet and the second porous container is positioned proximate the grease trap outlet. The first and second porous containers are formed of a porous fabric and contain an absorbent, organic hydrocarbon material capable of absorbing a quantity of fats, oil and grease. The second porous container may be positioned on either side of the grease trap outlet (within the grease trap or intermediate the outlet and an exit pipe) and may be held in a stationary manner via a tether and/or a hinged door having a flange for capturing and holding the porous container in a stationary manner.

Use of an alkyltrichlorosilane of the following formula I: R—SiCl.sub.3, wherein: R represents an alkyl group, Si represents a silicon atom and Cl represents a chlorine atom, and/or of a silsesquioxane of the following formula II: [RSiO.sub.3/2].sub.n, wherein: R represents an alkyl group, Si represents a silicon atom, O represents an oxygen atom and n represents an integer, for the removal of microplastic particles from water and/or for the treatment of water. Further, a method for the removal of microplastic particles from water and/or for the purification of water is provided, as well as an inclusion and/or intercalation compound, a kit for the removal of microplastic particles from water and/or for the purification of water as well as a water treatment system.

The present invention provides compositions for removal of arsenic or heavy metal contaminants in the process of fluid filtration comprising an organically modified inorganic adsorbent, wherein the composition is produced by reaction with 1,3-dipolar compounds prior to filtration. Also provided are systems for fluid filtration, comprising compositions as provided herein, in a column or column-like format, wherein a fluid is provided to the column such that the fluid flows through the organically modified inorganic adsorbent, and wherein contaminants present in the fluid are bound to the composition. Additionally provided are methods for fluid filtration, comprising contacting a fluid sample with the composition of claim 1 and collecting the filtered fluid sample after filtration.

Method and systems are disclosed for the removal of metal contaminants from aqueous mediums. In an example, a chamber contains activated sorptive media and a primary ligand and optionally, a secondary ligand that has been loaded onto the activated sorptive media using hydraulic loading. A pre-treatment of the sorptive media, a specific volume of the activated sorptive media within the chamber, specific pH ranges of aqueous mediums, and hydraulic loading of the primary ligand and optionally, a secondary ligand, known as dynamic fluidized loading. Pore pressures of the seeding solution within the media are at least sufficient to overcome the gravitational forces acting on the media within the column. The methods and systems provide a highly uniform and predictable loading of the primary ligand and optionally, the secondary ligand, onto the activated sorptive media throughout the sorptive media for effective sorption and increased capacity for metal removal from aqueous mediums.

Cross-linked polymeric resins from anilines linked together with dithiocarbamate alkyl chains. A process for producing the cross-linked polymeric resins by Mannich-type polycondensation of anilines and diaminoalkanes linked together by an aldehyde and subsequent conversion of one or more amine functionalities to dithiocarbamate moieties. In addition, a method for removing heavy metals, such as Hg(II) from aqueous solution via contacting and treatment with the cross-linked polymeric resins.

A filter is treated with a reduced amount of a halo active aromatic sulfanomide compound of Formula (I):

##STR00001##

wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, and R.sub.5 are independently selected from hydrogen, COOR′, CON(R″).sub.2, alkoxy, CN, NO.sub.2, SO.sub.3R″, halogen, substituted or unsubstituted phenyl, sulfonamide, halosulfonamide, and substituted or unsubstituted C.sub.1-C.sub.12 alkyl; R′ is hydrogen, an alkali metal, an alkaline earth metal, substituted C.sub.1-C.sub.12 alkyl, or unsubstituted C.sub.1-C.sub.12 alkyl; and R″ is hydrogen or substituted or unsubstituted C.sub.1-C.sub.12 alkyl, where the two R″ groups in CON(R″).sub.2 may be independently selected; X is halogen; M is an alkali or alkaline earth metal; and n is the number of water molecules per molecule of the sulfonamide compound. The compound effectively suppresses odors pre-use, in use, and post-use for extended periods of time.

A composition of matter wherein the composition comprises a siliceous substrate having silanols on the surface and a polymer selected from the group consisting essentially of a water soluble polymer, a water soluble copolymer, an alcohol soluble polymer, an alcohol soluble copolymer, and combinations of such polymers, wherein the polymer is chemically bonded to the siliceous substrate by a silane linking material having the general formula
O.sub.3/2SiQY
that is derived from an alkoxy-functional silane having the general formula
(RO).sub.3SiQX
and processes for preparing the crosslinked polymer that is chemically bonded to the surface of the siliceous substrate.

Provided is a silica particle coated with β-cyclodextrin, wherein said cyclodextrin is attached to said silica particle via at least one crosslinking agent and/or at least one copolymer. Also provided are methods of removing contaminants from a flowing or stationary liquid phase comprising the step of contacting said liquid phase with the silica particle coated with β-cyclodextrin.