A draw solute for forward osmosis membrane process, comprising an addition polymer obtained by addition polymerization of an alkylene oxide having 2 to 10 carbon atoms to an amine compound.

One or more novel processes for producing hydrogen, oxygen, and in some cases, distilled and cleaned water from a contaminated effluent, are disclosed. In one example of utilizing this novel process, the water from contaminated effluent is transferred into a draw solution using an entrochemical system through a vapor-mediated membrane-free forward osmosis process. The process is enabled by the generation of a wet vacuum in one or more entrochemical cells incorporated into the entrochemical system. This process generates a diluted draw solution that can be utilized as an abundant water feedstock in an electrolyzer for electrolysis, which in turn generates hydrogen and oxygen. In some embodiments, an entrochemical distiller may also be utilized to distill a portion of the contaminated effluent for clean water as a result of thermal transfers during the vapor-mediated membrane-free forward osmosis process.

An electrochemical system has a first reservoir receiving a feed stream. The feed stream includes a solvent and a solute different than the salt. A second reservoir receives a brine stream with a higher salt concentration higher than the feed stream. Electrodes contact a loop of redox- active electrolyte material causing reversible redox reactions. The reactions cause the loop to accept a first ion from the salt in the first reservoir and drive a second ion into the brine stream in the second reservoir. Three ionic exchange membranes of alternating type define the first and second reservoirs. A concentrate stream is output from the first reservoir, the concentrate stream having a second solute concentration greater than the first solute concentration.

The present invention relates to a water extraction system for up-concentration of organic solutes comprising a flow cell comprising a membrane; said membrane comprising an active layer comprising immobilized aquaporin water channels and a support layer, and said membrane having a feed side and a non-feed side; and an aqueous source solution in fluid communication with the feed side of the membrane. The system also includes an aqueous source solution in fluid communication with the feed side of the membrane and an aqueous draw solution in fluid communication with the draw side of the membrane. The aqueous source solution comprises the organic solutes. The membrane module comprises an inlet and an outlet for the aqueous draw solution. The aquaporin vesicles are formed by self-assembly of block copolymers in the presence of an aquaporin protein suspension.

The present invention relates to a thermo-responsive solution and in particular, a solution for use in an osmosis process that is suitable for separating or purifying solutes and or water from an aqueous solution on a large scale and under energy efficient conditions.

Provided herein is forward osmosis-based water purification process, that includes contacting a solution of a soluble draw agent with a dehydrated insoluble draw agent, separating the now hydrated insoluble draw agent from the now concentrated draw solution, and exerting a stimulus on the hydrated insoluble draw agent for extracting water therefrom, thereby regenerating a dehydrated insoluble draw agent, wherein the osmotic concentration (osmolality) of the insoluble draw agent is greater than the osmotic concentration of the diluted draw solution, and the insoluble draw agent is impermeable to the soluble draw agent.

A hybrid process and system for separating water from an inlet brine solution is disclosed. The hybrid process couples at least two different separation processes/systems. The inlet brine solution is fed into a first separation process, which produces a water distillate and a brine concentrate. The brine concentrate from the first separation process is then fed into the second separation process to further recover additional water. The excess heat from the second separation process is supplied to the first separation process.

A process for separating solvent from a feed solution, said process comprising: contacting a feed solution comprising solutes dissolved in a solvent with one side of a nanofiltration membrane, applying hydraulic pressure to the feed solution, such that solvent and some of the dissolved salts from the feed solution flow through the nanofiltration membrane to provide a permeate solution on the permeate-side of the nanofiltration membrane and a concentrated solution on the retentate-side of the nanofiltration membrane; contacting the permeate solution from the nanofiltration membrane with one side of a reverse osmosis membrane and applying hydraulic pressure to the permeate solution, such that solvent from the permeate solution flows through the reverse osmosis membrane to leave a concentrated solution on the retentate-side of the reverse osmosis membrane, using the concentrated solution from the retentate-side of the reverse osmosis membrane as at least part of the feed solution to the nanofiltration membrane; withdrawing at least a portion of the concentrated solution from the retentate-side of the nanofiltration membrane.

An apparatus and method for recovering metal from a solution comprising a metal-selective sorbent disposed in a column. Additional embodiments provide for using a metal-selective membrane configured for selective transport, isolation, retention, and recovery of metal ions and compounds; electrodialysis and forward osmosis apparatuses to recover metal from a solution. A modular system to process a solution at a remote field site is disclosed. The process is a green process and produces limited to no industrial waste.

Forward osmosis membrane vessels, and particularly stackable forward osmosis membrane vessels, are provided as well as systems and methods thereof. The forward osmosis membrane vessel has a body, a strong draw solution chamber, a first and a second semipermeable membrane, and a brine chamber. The first and second semipermeable membranes each are disposed within the cavity of the body. The first and second semipermeable membranes are configured to produce diluted draw solution streams and brine streams. The brine chamber is disposed at least partially between the first semipermeable membrane and the second semipermeable membrane. The forward osmosis membrane vessel may be configured such that in a stacked configuration the brine chamber and the strong draw solution chamber of the forward osmosis membrane vessel aligns with a brine chamber and a strong draw solution chamber of an adjacent second forward osmosis membrane vessel.