This invention relates to uses of graphene oxide, and in particular graphene oxide on a porous support, and a membrane comprising these materials. This invention also relates to methods of dehydration, which include vapour phase separation and pervaporation. Pervaporation is a method of separating mixtures of liquids using a membrane. Pervaporation consists of two basic steps: permeation of the permeate through the membrane and evaporation of the permeate from the other side of the membrane. Pervaporation is a mild which can be used to separate components which would not survive the comparatively harsh conditions needed for distillation (high temp, and/or low pressure).

Disclosed are a CMS membrane, characterized in that it is obtainable by pyrolysis of a polyimide composed of the monomers 1-(4-aminophenyl)-1,3,3-trimethyl-2H-inden-5-amine and 5-(1,3-dioxo-2-benzofuran-5-carbonyl-2-benzofuran-1,3-dione of the following formulae:

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preferably by pyrolysis of the polyimide having the CAS number 62929-02-6, and a supported CMS membrane comprising a CMS membrane obtainable from a polyimide by pyrolysis and a porous support, characterized in that a mesoporous intermediate layer is provided between the CMS membrane and the porous support.

Further disclosed are a process for preparing the supported membrane, the use of the membranes for separating gas mixtures or liquid mixtures, an apparatus for gas separation or for liquid separation, and the use of the polyimide for preparing a CMS membrane by pyrolysis.

Electro oxidation membrane evaporator 1 comprises sweep air handler 60; fluid tank 20 defining a fluid container; fluid contactor/separator 30; oxidation cell 40; and scrubber 80. Electro oxidation membrane evaporator 1 may allow higher percent water recovery from wastewater prior to delivering brine to a brine water recovery system and can allow O.sub.2 from air such as cabin air to continuously diffuse into the wastewater as O.sub.2 is consumed to generate oxidants, helping to eliminate the low oxidant environment at the end of the cycle that causes pH to remain high, and low pH prevents precipitates from forming for longer so more water can be evaporated from the wastewater.

A solar-thermal vapor-permeation membrane is provided. The solar-thermal vapor-permeation membrane includes a thermally conductive, microporous support layer having a feed surface, and an active separation layer adjacent the feed surface of the support layer. The support layer is capable of absorbing solar-thermal radiation. Utilization of solar energy for a membrane separation process replaces fossil-fuel derived energy with renewable energy as the driving force and does not involve the generation of undesirable greenhouse gas emissions. Therefore, the solar-thermal vapor-permeation process using the provided membrane is cost effective, energy efficient, and environmentally friendly.

A membrane distillation (MD) system consisting of a membrane module and carbon nanotube immobilized membrane for organic solvent separation is disclosed. The MD module includes a feed inlet and outlet, a sweep gas inlet, and a sweep gas outlet. Thermostats are positioned at the feed inlet and outlet to measure the change in temperature. Preferential sorption of the organic on carbon nanotube immobilized membrane contributes to enhanced solvent removal of the MD system. A pervaporation (PV) system consisting of a membrane module and polyvinyl alcohol (PVA) mixed matrix membranes with graphene oxide (GO)—carbon nanotubes (CNTs) for enhanced purification of the alcohol solution after membrane distillation to remove trace amount of water is disclosed.

A high salinity water purification system and process, including a forward osmosis system and a reverse osmosis or nanofiltration system. A solids membrane separation system removes solids from the influent water being processed. A pervaporation (PV) system eliminates liquid impurities from the influent water being processed.

A membrane evaporative condenser (MEC) includes a repeating sequence of channels for evaporation and/or condensation are arranged, each sequence of channels includes a condensation channel for condensation of a vapor to a liquid, an evaporation channel, and zero to one hundred evaporation-condensation channels. The condensation channel has walls of a non-permeable material which exterior to the condensation channel share the wall with a liquid evaporative medium (LEM) conduit that contains a LEM. The LEM conduit includes a moisture transfer membrane (MTM), where the LEM can evaporate into an evaporation channel or an evaporation-condensation channel that can amplify the effect of the heat transfer for additional mass transfer.

The present disclosure generally relates to liquid separation membranes. The present disclosure also relates to membranes comprising at least a nanoporous hydrophilic layer and a porous hydrophobic substrate. The present disclosure also relates to a process for preparing the membranes and to use of the membranes in pervaporation and/or membrane distillation processes including desalination and/or solvent dehydration.

Rapid evaporation of water for desalination and dewatering using nanobubbles and micro-droplets is disclosed. Warm nanobubbles of air are injected into seawater or another water source to be treated, and the normal stasis of the nanobubbles is disrupted with ultrasonic energy. The nanobubbles implode and violently recombine into microbubbles. Energized by the effects of the nanobubble state change, these energetic, relatively high surface area microbubbles bubbles quickly rise to the surface of the water, creating an aerosol of micro-water droplets above the surface that is drawn into a dry, warm stream of air and rapidly evaporates, precipitating out salt crystals. The air is then cooled with a chiller, condensing the moisture in the air into fresh water.

Disclosed herein is a method and apparatus that uses a brine from a well that is used to both generate electricity and recover valuable minerals present in the brine. The method and apparatus uses a hydrophobic membrane to separate water vapor from the brine to concentrate the brine that is then used to recover the minerals.