A capacitive adsorption module assembly is proposed. The capacitive adsorption module assembly includes a plurality of capacitive adsorption modules, each having a disk-shaped spacer configured to form a flow path through which feed flows, a cation exchange membrane attached to any one of an upper surface and a lower surface of the spacer, a first electrode attached to the cation exchange membrane, an anion exchange membrane attached to the other of the upper surface and the lower surface of the spacer, and a second electrode attached to the anion exchange membrane, wherein the capacitive adsorption modules are vertically stacked such that adjacent capacitive adsorption modules share or contact the first electrode or the second electrode, and at least one first terminal and second terminal passing through the stacked modules being provided, wherein the first terminal is electrically connected to the first electrode of an odd-numbered module, and the second terminal is electrically connected to the second electrode of an even-numbered module.

A system separates and in-situ analyzes a discrete sample of multiphase fluid. The system includes a separation vessel having a first inner chamber for separating a discrete sample of multiphase fluid into liquid phases including an aqueous liquid phase and a nonporous liquid phase, and a built-in water analysis unit. The built-in water analysis unit includes an analytical cell disposed inside the first inner chamber of the separation vessel, the analytical cell having a second inner chamber, and at least one probe having a sensing area disposed in the second inner chamber for in-situ analysis of a sample of the aqueous liquid phase that is separated from the discrete sample of multiphase fluid in the first inner chamber and that is channeled to the second inner chamber from the first inner chamber for the in-situ analysis. The second inner chamber is defined inside the first inner chamber.

Provided are hybrid electrochemical and membrane-based systems for removing silica from water stream to achieve ultra-pure water. The silica concentration of a feed water stream may dictate the most effective and economical variation of disclosed hybrid processes to use. For example, for a feed water stream having a silica concentration of 1-30 ppm, a hybrid system for treating the feed water includes an electrodialysis reversal unit, the electrodialysis reversal unit comprising an inlet stream and a product outlet stream; a reverse osmosis unit, the reverse osmosis unit comprising an inlet stream and a product outlet stream, wherein the inlet stream of the reverse osmosis unit comprises the product outlet stream of the electrodialysis reversal unit; and an electrodeionization unit, the electrodeionization unit comprising an inlet stream and a product outlet stream, wherein the inlet stream of the electrodeionization unit comprises the product outlet stream of the reverse osmosis unit.

Various examples related to resin wafer technologies including ionomers and resin wafers with solution processable ionomers and their production are provided. In one example, a wafer includes an ion conducting layer having ion-exchange resin particles and an ionomer binder coating the ion-exchange resin particles. The ionomer binder can bind the ion-exchange resin particles together in the ion conducting layer. In another example, the wafer can contain water dissociation catalysts for promoting water-splitting in the wafers.

A system for modifying pH in an aqueous environment comprises an aqueous salt solution feed stream having a first pH and an electrochemical device positioned proximate an aqueous restoration area. The electrochemical device is configured to receive the feed stream and convert the feed stream to an acid stream and a base stream having respective predetermined pH values. A first effluent stream comprises the base stream, wherein the first effluent stream has a second pH that is higher than the first pH. The first effluent stream is delivered proximate the aqueous restoration area. A second effluent stream comprises the acid stream, wherein the second effluent stream has a third pH that is lower than the second pH.

A system for modifying pH in an aqueous environment comprises an aqueous salt solution feed stream having a first pH and an electrochemical device positioned proximate an aqueous restoration area. The electrochemical device is configured to receive the feed stream and convert the feed stream to an acid stream and a base stream having respective predetermined pH values. A first effluent stream comprises the base stream, wherein the first effluent stream has a second pH that is higher than the first pH. The first effluent stream is delivered proximate the aqueous restoration area. A second effluent stream comprises the acid stream, wherein the second effluent stream has a third pH that is lower than the second pH.

Provided are electrodialysis systems comprising a plurality of electrodialysis devices, wherein each electrodialysis device of the plurality of electrodialysis devices has a product inlet stream, a product outlet stream, a brine inlet stream, and a brine outlet stream. The product inlet stream for a first electrodialysis device comprises the brine outlet stream of a second electrodialysis device. Further, a first portion of a feed stream is the brine inlet stream for the first electrodialysis device and a second portion of the feed stream is the brine inlet stream for the second electrodialysis device or a third electrodialysis device.

The present invention relates to the technical field of electrocatalytic electrode preparation, and discloses a lead dioxide-carbon nanotube adsorptive electrochemical submicroelectrode, a preparation method, and use thereof. The electrochemical submicroelectrode according to the present invention comprises multiple layers of orderly arranged spherical lead dioxide submicroholes communicating with each other, where the carbon nanotubes are partially or completely inserted (in the form of twigs) in the lead dioxide hole and in the wall of the hole. The combined effect of adsorption and catalysis inside the submicroreactor effectively solves the problems of low catalytic efficiency and diffusion control associated with the conventional flat lead dioxide electrode, thus greatly improving the electrochemical catalytic performance of the electrode.

A quaternary ammonium group-grafted cation resin and a preparation method thereof are provided. The preparation method includes: adding a chloromethylated cross-linked polystyrene (PS) resin, trimethylamine hydrochloride, and a 20% sodium hydroxide aqueous solution successively to a reactor for a reaction under stirring at 30° C. to 40° C.; filtering a resulting reaction solution, followed by washing and drying to obtain a quaternary ammonium group-grafted resin; adding the quaternary ammonium group-grafted resin, 1,2-dichloroethane, silver sulfate, concentrated sulfuric acid, and fuming sulfuric acid successively for a reaction for 1 hour at 50° C. to 60° C., a reaction for 1 hour at 70° C. to 80° C., and a reaction for 5 hours at 115° C. to 125° C.; and cooling a resulting reaction solution to room temperature, followed by diluting, filtering, washing and drying to obtain the quaternary ammonium group-grafted cation resin.

A plasma activated water production system includes a plasma reactor and a membrane concentrator. The plasma reactor includes an internal cavity, at least one electrically-conductive inlet capillary and outlet capillary. A mixing chamber has a feed gas inlet, a liquid inlet, and a mixed gas and liquid outlet. A power source is provided. The plasma reactor propagates a plasma discharge between the inlet capillary and the outlet capillary. A membrane concentrator includes a water flow channel with a water inlet and a water outlet, a dry gas inlet and a humidified gas outlet. An ion selective membrane is provided, and water will pass through the membrane into the dry gas, and the water leaving the membrane concentrator will have increased concentrations of nitrates, nitrites and hydrogen peroxide. An electrodialysis embodiment and a method of generating plasma activated with increased concentration of nitrates, nitrites and hydrogen peroxide are also disclosed.