Described herein is a functional graphene composition comprising a graphene scaffold and one or more metal chelating functional groups covalently bonded to the graphene scaffold and a porous substrate that includes the functional graphene composition. Also provided is a method of removing dissolved metals from an aqueous liquid, such as, acid mine drainage.

In order to solve the problem in the existing conventional water treatment process of low removal efficiency of heavy metal in water, especially lower efficiency for simultaneous removal of heavy metal pollutants during coexisting, a method is provided for removing heavy metal pollutants in water with divalent manganese strengthened ferrate: preparing a ferrate mother liquor having the concentration of 20-10,000 mmol/L; preparing a divalent manganese salt mother liquor having the concentration of 30-10,000 mmol/L; adding the divalent manganese salt mother liquor into water of the heavy metal pollutants; then adding the ferrate mother liquor, and reacting; and then adding a flocculant and precipitating, so that the removal rate of arsenate, chromium, thallium, antimony, chromium and molybdate in water is 90% or more, and the removal rate of heavy metal such as lead and cadmium is 85% or more.

An ion removal device based on electrochemical and photoelectrochemical methods, and the application of energy conversion and storage are provided. In the ion removal process based on the electrochemical and photoelectrochemical fluidization battery device, the positive active material in the flow battery is the positive pole of device, the negative active material in the fluid battery is the negative pole of the device, and the salt solution is the electrolyte in the middle stream. The positive and negative active materials include organic materials such as 4-hydroxy-piperidinol oxide, riboflavin sodium phosphate or methyl viologen, which have the advantages of low raw material cost, environmental friendliness, high sustainability, excellent electrochemical performance, high specific capacity and good cycle stability etc. The electrolyte can be separated from the positive and negative active liquid flow materials according to the fixed sequence of self-assembly of fluid battery mold.

The disclosure relates to the field of metal ion capture, more particularly of selective capture of nickel Ni(II) ions, by a polymeric compound based on a polymer selected from styrenic polymers and chloropolymers. In the polymeric compound, at least one portion of the monomer units of the polymer is functionalised by the ligand, the ligand including at least one chemical group selected from the glyoxime groups.

The glyoxime groups have a strong affinity for the Ni(II) ions, as well as an excellent selectivity vis-à-vis metal ions of chemical properties similar to Ni(II) ions. This ligand thus allows a selective complexation of the Ni(II) ions by the polymeric compound, including in solutions of low concentrations of Ni(II) ions.

The polymeric compound according to at least one embodiment of the disclosure is particularly intended for capturing the Ni(II) ions during the electrogalvanising methods as well as for recycling material comprising nickel.

Systems and methods to separate water and remove solids from a pre-treated and unfiltered renewable feedstock at or separate from a refinery. Such systems and methods may be used to provide a reduced-contaminant and reduced-solid renewable feedstock for further refining.

An in-situ mycoremediation system and process is provided, including a device with a rod casing having a top end, a bottom end, and a sidewall with one or more perforations, the sidewall defining an internal channel that extends from an intake opening on the top end to the one or more perforations, a sleeve that extends around at least part of the rod casing and that is slidable between at least a first position that covers the one or more perforations and a second position that at least partly uncovers the one or more perforations, and a plumbing line linked to the intake opening and configured to facilitate forcible injection of one more fungal mixtures and/or air via the one or more perforations when the sleeve is in the second position.

Methods and compositions for remediating wastewater formed by water and contaminants, which may include per- and poly-flouroalkyl substances (PFAS), using a wastewater treatment system including a collecting unit, a dewatering unit, a drying unit, and a baking unit. Wastewater provided to the collecting unit is dosed by adding a compound to the wastewater in an amount that is sufficient to cause the contaminants to separate from the water and to form a sludge. The compound can include combinations of salts, glacial acetic acid, chitosan, and water. The sludge is dewatered with the dewatering from a first dryness level a second dryness level. The dewatered sludge is then dried in the drying unit from the first dryness level to a third dryness level. The dried sludge is then baked at a sufficiently high enough temperature that chemical bonds of at least a portion of the contaminants are destroyed.

Reactive treatment cells (RTCs) are described in combination with sediment capping systems as a means for environmental remediation. RTCs include an impermeable housing defining an interior, a permeable ceiling and floor typically including filtration materials such as geotextiles, and at least one interior compartment for treatment reagents. One RTC includes a gabion-like cage structure retaining a geomembrane-supported geosynthetic clay liner (GM-GCL) housing, while a second embodiment includes a hard, cylindrical shell as a replaceable reagent cartridge. RTCs may be employed in initial capping system installations or retrofitted into existing capping systems. RTCs may include optional baffles, flow restrictors, floating discs, sensor probes, and two or more serial reagent zones or compartments.

A method of separating and recovering a cobalt salt and a nickel salt includes a separation step of separating, by using a nanofiltration membrane, a cobalt salt and a nickel salt from a rare metal-containing aqueous solution containing at least both the cobalt salt and the nickel salt as rare metals, in which the nanofiltration membrane has a glucose permeability of 3 times or more a sucrose permeability, the sucrose permeability of 10% or less, and an isopropyl alcohol permeability of 50% or more when a 1,000 mg/L glucose aqueous solution, a 1,000 mg/L sucrose aqueous solution, and a 1,000 mg/L isopropyl alcohol aqueous solution, each having a pH of 6.5 and a temperature of 25° C., individually permeate through the nanofiltration membrane at an operating pressure of 0.5 MPa.

A gene ansB knockout mutant of Citrobacter werkmanii and an application thereof are provided. The gene ansB knockout mutant of the C. werkmanii is C. werkmanii with a gene ansB knocked out and a nucleotide sequence of the gene ansB is as shown in SEQ ID NO: 1. In the present invention, the acquired engineering bacteria with the gene ansB of the C. werkmanii knocked out are cultured in LB, TSB, NB and other media at 25° C. and 30° C., so that a biofilm formation capacity of the C. werkmanii on a polypropylene material is improved. Thus, the application scenarios and scopes of the C. werkmanii in heavy metal ion adsorption and construction of cellular protein synthesis micro-factories are broadened.