A solar-thermal vapor-permeation membrane is provided. The solar-thermal vapor-permeation membrane includes a thermally conductive, microporous support layer having a feed surface, and an active separation layer adjacent the feed surface of the support layer. The support layer is capable of absorbing solar-thermal radiation. Utilization of solar energy for a membrane separation process replaces fossil-fuel derived energy with renewable energy as the driving force and does not involve the generation of undesirable greenhouse gas emissions. Therefore, the solar-thermal vapor-permeation process using the provided membrane is cost effective, energy efficient, and environmentally friendly.

A method for treating acrolein reactor wastewater, comprising the steps of: S1. mixing acrolein reactor wastewater and a carbonate aqueous solution to obtain a mixed solution, wherein the acrolein reactor wastewater has a pH value of less than 2 and contains 500 ppm to 3,000 ppm of acrolein, 50 ppm to 800 ppm of allyl alcohol, 40,000 ppm to 100,000 ppm of acrylic acid, 10,000 ppm to 30,000 ppm of formaldehyde, 3,000 ppm to 10,000 ppm of acetic acid and 3,000 ppm to 8,000 ppm of maleic acid; and the mixed solution has a pH value of 4 to 6, a COD concentration ranging from 7,500 ppm to 30,000 ppm, and a formaldehyde concentration ranging from 800 ppm to 4,000 ppm; S2. conveying the mixed solution obtained in step S1 to an anaerobic reactor (4) for biochemical treatment; and S3. conveying the solution treated in step S2 to an aerobic biochemical tank (5) for treatment; and reflowing at least one part of the solution treated in step S2 and/or S3 to step S2. Also provided is a device for treating acrolein reactor wastewater.

A membrane distillation (MD) system consisting of a membrane module and carbon nanotube immobilized membrane for organic solvent separation is disclosed. The MD module includes a feed inlet and outlet, a sweep gas inlet, and a sweep gas outlet. Thermostats are positioned at the feed inlet and outlet to measure the change in temperature. Preferential sorption of the organic on carbon nanotube immobilized membrane contributes to enhanced solvent removal of the MD system. A pervaporation (PV) system consisting of a membrane module and polyvinyl alcohol (PVA) mixed matrix membranes with graphene oxide (GO)—carbon nanotubes (CNTs) for enhanced purification of the alcohol solution after membrane distillation to remove trace amount of water is disclosed.

An air scrubber system including a system for creating an oxidation reduction potential (ORP) in water is disclosed. The system includes a pipe assembly for in-line mixing. The pipe assembly includes a first flow path for water to flow through. The first flow path includes one or more ozone intake ports that are fluidically coupled to one or more ozone output ports of an ozone supply unit. The pipe assembly further includes a second flow path fluidically coupled in parallel with the first flow path. The second flow path includes a control valve that selectively permits a portion of the water to flow through the second flow path to produce a negative pressure in the first flow path so that ozone is drawn into the first flow path through the one or more ozone intake ports and mixed into the water flowing through the first flow path.

The present invention is directed to systems and methods for removing trichloroethane (TCA), trichloroethene (TCE), and 1,4-dioxane (1,4-D) from contaminated water and wastewater. The system and methods relying on catalyst reduction of TCA and TCE, and the reduced products are degraded by microorganisms that are capable of biodegrading ethane and 1,4-D. In certain embodiments, a catalyst film comprises precious nanoparticles with diameters of 5-40 nm and a biofilm comprising microorganisms that are capable of degrading ethane and 1,4-D are used in a dual-reactor system to remove TCA, TCE, and 1,4-D from contaminated water and wastewater.

The present disclosure is a method of removing water and contaminants from an aqueous feed stream comprising a water soluble process liquid. Embodiments of the method may include splitting the method into stages, vaporising the process liquid by direct contact with a heated heating fluid, removing precipitated contaminants by chemical means, and treating the heating fluid to maintain or enhance its properties.

A method and apparatus for wastewater treatment using ultrafine bubbles, wherein bubbles of 200 nm or less are contacted with a wastewater volume in continuous flow conditions by means of an ultrafine bubble generator, a source of oxygen, a tank, a first and a second pump, a pipe system and connectors, the connectors being configured such that continuous flow conditions are maintained in the pipe system.

A method of reducing a concentration of hydrogen peroxide from wastewater includes diluting the wastewater with water having a lower concentration of hydrogen peroxide than the wastewater to produce a diluted wastewater, contacting the diluted wastewater with a dissolved iron compound at an acidic pH to form a partially treated wastewater having a lower concentration of hydrogen peroxide than the diluted wastewater, and precipitating iron solids from the partially treated wastewater by raising a pH of the partially treated wastewater to form a neutralized partially treated wastewater.

A process is disclosed for treating water, such as wastewater, with ozone under alkaline and acidic conditions to decompose and remove acrolein and acrolein byproducts from the water and/or wastewater. The process is able to lower the concentration of acrolein and acrolein byproducts from water to a sufficiently low level suitable for discharge to a municipal sewer collection system with reduced occurrence of the decomposition by-products of acrolein converting back to acrolein in the water. One embodiment of the process treats contaminated water containing acrolein with ozone by sparging or bubbling ozone through the contaminated water. The contaminated water can be treated with ozone where the contaminated water is initially adjusted to a pH greater than 7.0 for a time to convert at least a portion of the acrolein to 3-hydroxypropanal to obtain a partially treated water. The pH of the partially treated water is then adjusted to a pH below 7.0 while continuing the ozone treatment for a time sufficient to react with and decompose the 3-hydroxypropanal to inhibit the conversion of 3-hydroxypropanal back to acrolein.

The application belongs to the technical field of photocatalyst preparation, and specifically relates to a MOFs/COFs heterojunction composite photocatalyst and a preparation method and application thereof. The application uses melamine (MA), 1,3,5-trimethylphloroglucinol (Tp), 2-aminoterephthalic acid, and ferrous acetate as reaction raw materials, a catalyst is added, and a mechanical grinding method is used, to prepare the MOFs/COFs heterojunction composite photocatalyst. The catalyst is simple and green in preparation method, and has the better degradation efficiency for pollutants in water, especially carbamazepine.