The disclosure relates to modified wood pulp and methods using the same for removal for per- and polyfluoroalkyl substances (collectively “PFAS”) from contaminated water. Cationic-modified wood pulp can be used to adsorb anionic PFAS contaminants from water, and anionic-modified wood pulp can be used to adsorb cationic PFAS contaminants from water. The modified wood pulp has high adsorption efficiencies, rapid adsorption kinetics, and high adsorption efficiencies for a range of different PFAS contaminants.

The present disclosure provides systems and methods for degrading per- and poly-fluoroalkyl substances (PFAS) using hydrated electrons generated in an ultraviolet (UV)/sulfite system. These systems and methods may be used, e.g., to remediate wastewater by destroying PFAS and co-contaminants such as chlorinated volatile organic compounds (CVOCs).

Compositions made of laminate comprised of porous carbon nanotube (CNT) are disclosed. Uses of the Compositions, particularly for reducing a formation of a load of a microorganism or of a biofilm, are also disclosed.

An apparatus and methods to eliminate PFAS from wastewater biosolids through fluidized bed gasification. The gasifier decomposes the PFAS in the biosolids at temperatures of 900-1800° F. Synthesis gas (syngas) exits the gasifier which is coupled to a thermal oxidizer and is combusted at temperatures of 1600-2600° F. This decomposes PFAS in the syngas and creates flue gas. Heat can be recovered from the flue gas by cooling the flue gas to temperatures of 400-1200° F. in a heat exchanger that is coupled with the thermal oxidizer. Cooled flue gas is mixed with hydrated lime, enhancing PFAS decomposition, with the spent lime filtered from the cooled flue gas using a filter system that may incorporate catalyst impregnated filter elements. The apparatus and methods thereby eliminate PFAS from wastewater biosolids and control emissions in the resulting flue gas.

Apparatus is disclosed for separating and concentrating one or more PFAS compounds from contaminated water or wastewater using a combination of membrane filtration and foam fractionation. Water is processed through a membrane filter to produce a permeate and a reject using a Reverse Osmosis or a Nanofiltration membrane where the permeate produced is suitable for potable applications and the reject produced is sent to a foam fractionator for further treatment. Wastewater is processed through a membrane filter to produce a permeate and a reject using an Ultrafiltration or Microfiltration membrane where the permeate produced is sent to a foam fractionator for further treatment and the reject is contained within a wastewater treatment plant as activated sludge. Membrane reject or permeate sent to a foam fractionator is then processed to remove any surface active contaminates (PFAS) by injecting air to generate a foam that can be collected and removed for storage producing a clean effluent that is suitable for environmental discharge and a foam concentrated with PFAS.

An enhanced coagulation method for removing microplastics in water is provided. First, a certain amount of inorganic suspended particles are added to microplastic wastewater to increase the number of particles and thereby improve a collision probability among the particles; and then a natural polymer flocculant and a polysilicic acid are added. The polysilicic acid is used as coagulant aid, so that the three materials can comprehensively achieve the purpose of removing the microplastics in the wastewater. The enhanced coagulation method can combine respective characteristics and advantages of the three materials, so that the three materials can mutually complement each other and give full play to the role of charge neutralization and bridging and net capturing, strengthen the sedimentation performance and enhance the actual microplastic removal effect. Therefore, it is a green and environmentally-friendly enhanced coagulation technology.

Per- and polyfluoroalkyl substances (PFAS) are destroyed by oxidation in supercritical conditions. PFAS in water can be concentrated and prepared for destruction in a pretreatment phase. Following annihilation of the PFAS in supercritical conditions to levels below 5 parts per trillion (ppt), the water effluent can be used to recover heat, returned to sub-critical conditions, and then released back into the environment.

Per- and polyfluoroalkyl substances (PFAS) are destroyed by oxidation in supercritical conditions. PFAS in water is concentrated in a reverse osmosis step and salt from the resulting solution is removed in supercritical conditions prior to destruction of PFAS in supercritical conditions.

A two-stage treatment process for destroying per- and polyfluoroalkyl substances (PFAS) in an aqueous stream. The two-stage treatment process uses a combination of multifunctional crystalline molecular sieves, such as zeolites and zeotypes, to separate PFAS from the aqueous stream, catalytically decompose and defluorinate any PFAS molecules, and generate non-toxic waste products that are safe for disposal. The first stage includes adsorption of the PFAS within one of a pair of vessels containing porous, hydrophobic, hydrothermally stable molecular sieves, dehydration of the captured PFAS on the sieves, and catalytic ozonation of the captured PFAS molecules on the dried sieves. The second stage involves catalytic decomposition and neutralization of the ozonation results with one of a pair of vessels including a zeolite-supported CaO catalyst, catalytic oxidation of any toxic CO generated by the decomposition, and an acid wash for regeneration of the spent catalyst.

The present subject matter illustrates a zero-valent metal suspension in non-aqueous phase. The suspension comprises 41 wt. % of a plurality of zero-valent iron particles; 0.1 wt % of a surfactant; 36 wt. % of an oil; and 23 wt. % of a thickening agent.