The present disclosure provides for devices, systems, and methods of separating PFAS compounds from wastewater leachate. After separation, the PFAS compounds can be rendered less harmful. The present disclosure provides for devices, systems, and methods that uses aeration-induced foaming to isolate PFAS from landfill leachate into a concentrated, volume reduced liquid (coalesced foam), which can be separated and treated.

Methods of treating a waste stream containing perfluoroalkyl substances (PFAS) are disclosed. The methods include directing the waste stream to a dilution compartment of an electrochemical separation device, directing a treatment stream to a concentration compartment of the electrochemical separation device, and applying a voltage across the electrodes to produce a dilute stream substantially free of the PFAS and a concentrate stream. At least one of the waste stream and the treatment stream comprises a water miscible organic solvent. Methods of concentrating PFAS from a wastewater are also disclosed. PFAS concentration systems are also disclosed. The systems include a column comprising an ion exchange resin and an electrochemical separation device having a dilution compartment fluidly connected to an outlet of the column. Methods of facilitating treatment of a waste stream containing PFAS are also disclosed.

An electrochemical dechlorination of water method is provided. Dechlorination of water, containing chlorine or chloramine, is performed in an electrochemical reactor by passing electrons directly from an electrical grid to the chlorine or the chloramine via a cathode, where the dechlorination for the chlorine is defined by HOCl+2e.sup.−.fwdarw.Cl.sup.−+OH.sup.31, and wherein the dechlorination for the chloramine is defined by NH.sub.2Cl+H.sup.++2e.sup.−.fwdarw.Cl.sup.−+NH.sub.3. The cathode can be a stainless steel cathode. In one variation, the cathode and the anode are separated by a cation-exchange membrane. By means of this method, wastewater can be dechlorinated using power from the electric grid without the addition of external chemicals, thereby avoiding the cost of the chemicals, their transport, and the presence of their degradation products in the effluent water.

A water filter cartridge includes a sediment filter, a carbon filter, and a core having a tubular body with openings that allow water to flow through the core. The core defines an open central area, and the core supports the sediment filter and the carbon filter. A nanofiltration unit is arranged within the open central area of the core. The nanofiltration unit includes a tubular filter element defining a central volume, and a plurality of filaments arranged within the central volume.

A wastewater management system has a container with the first chamber and a second chamber therein, a diverter valve having an inlet and a first outlet, a holding tank interconnected to the first outlet of the diverter valve, and a controller connected to the diverter valve so as to move the diverter valve to the first position. The first outlet is directed to the first chamber. The inlet of the diverter valve is adapted to receive wastewater from a location remote from the container. The inlet is connected to the first outlet in the first position. The diverter valve can be a three-way valve having a first outlet directed to the first chamber and a second outlet directed to a second chamber. The controller moves the diverter valve between first and second outlets.

The present invention relates to the technical field of wastewater treatment, and discloses a method for enhanced bio-treatment of refractory organic pollutants with photo-excited holes as electron acceptors. The method comprises the following steps: 1) placing a composite semiconductor-coated carrier material into a reactor, introducing wastewater into the reactor inoculated with anaerobic sludge, and allowing the composite semiconductor-coated carrier material to be immersed in the wastewater, wherein the composite semiconductor-coated carrier material comprises a conductive carrier and composite semiconductor materials loaded on the conductive carrier; 2) carrying out habituated culture on the anaerobic sludge for a period of time, and loading a biological membrane on the surface of the composite semiconductor materials, to construct a photo-excited hole enhanced bioreactor; and 3) treating the refractory pollutants in the wastewater by utilizing the reactor under irradiation.

One aspect of the present invention relates to a carbonaceous material having a BET specific surface area calculated from a nitrogen adsorption isotherm by a BET method, of 750 m.sup.2/g or more and 1000 m.sup.2/g or less, a ratio of a pore volume of pores of 0.3875 to 0.9125 nm calculated from the nitrogen adsorption isotherm by a HK method to a total pore volume calculated from the nitrogen adsorption isotherm by the HK method, of 80% or more, and an average pore diameter obtained by the following formula using the BET specific surface area and the total pore volume calculated from the nitrogen adsorption isotherm by the HK method, of 1.614 nm or less: D=4000×V/S (wherein D represents the average pore diameter (nm), V represents the total pore volume (mL/g), and S represents the specific surface area (m.sup.2/g)).

A water treatment method including a removal step of removing a polymer (I) containing a polymerization unit (I) based on a monomer represented by the following general formula (I) from water containing the polymer (I):

CX.sup.1X.sup.3═CX.sup.2R(—CZ.sup.1Z.sup.2-A.sup.0).sub.m  (I)

wherein X.sup.1 and X.sup.3 are each independently F, Cl, H, or CF.sub.3; X.sup.2 is H, F, an alkyl group, or a fluorine-containing alkyl group; A.sup.0 is an anionic group; R is a linking group; Z.sup.1 and Z.sup.2 are each independently H, F, an alkyl group, or a fluorine-containing alkyl group; and m is an integer of 1 or more. Further, the number average molecular weight of the polymer (I) to 0.3×10.sup.4 or more. Also disclosed is a composition including the polymer (I) containing the polymerization unit (I) based on a monomer represented by general formula (I), and where the composition has a content of the polymer (I) of 250 ppm or less.

This disclosure relates to remediation processes and systems. Disclosed herein are processes and systems for remediation of material contaminated with one or more per- and polyfluoroalkyl substance (PFAS) compounds.

Methods for electrochemically oxidizing organic compounds in aqueous solution. The methods include contacting an aqueous solution comprising organic compounds with a first anode and electrochemically oxidizing at least a portion of the organic compounds to provide a first aqueous solution comprising oxidation products; and contacting the first aqueous solution comprising oxidation products with a first cathode and electrochemically reducing at least a portion of the oxidation products to provide a first aqueous solution comprising reduced products and residual oxidizable organic compounds. The first aqueous solution can be further treated to electrochemically oxidize at least a portion of the residual oxidizable organic compounds to provide a second aqueous solution comprising oxidation products, and the second aqueous solution can be further treated to electrochemically reduce at least a portion of the oxidation products to provide a third aqueous solution comprising reduced products and residual oxidizable organic compounds. Systems for electrochemically oxidizing organic compounds and effectively carrying out the methods are also provided.