C02F2103/36

Methods and systems for treating wastewater via forward osmosis

Embodiments disclosed herein are directed to methods and systems for treating wastewater via forward osmosis. By way of example, the methods and systems disclosed herein may be used to filter one or more precipitated salts and/or other particles from wastewater generated by power plants such as flue gas wastewater, oil and gas wastewater, and other industrial processes. For example, the methods and systems disclosed herein may be used to filter one or more precipitated salts from a wastewater feed concentrate formed during the forward osmosis process that is recirculated through at least one membrane module to continue the forward osmosis process. Filtering the one or more precipitated salts from the wastewater feed concentrate helps limit clogging of open channel feed spacer(s) of the at least one membrane module.

Process for preparing a catalyst and use thereof

The present invention provides a process for preparing a catalyst, wherein said process comprises:—(i) preparing a mixture of one or more aromatic alcohol monomers and/or non-aromatic monomers, solvent, polymerization catalyst, crosslinking agent, suspension stabilizing agent and one or more metal salts, under conditions sufficient to produce polymeric beads doped with one or more metals or salts thereof; (ii) carbonizing, activating and then reducing the polymeric beads produced in step (i) to produce metal nanoparticles-doped porous carbon beads; (iii) subjecting the metal nanoparticles-doped porous carbon beads produced in step (ii) to chemical vapour deposition in the presence of a carbon source to produce metal nanoparticles-doped porous carbon beads comprising carbon nanofibers; and (iv) doping the metal nanoparticles-doped porous carbon beads comprising carbon nanofibers produced in step (iii) with an oxidant; catalyst prepared by said process; and a process for treating waste water from an industrial process for producing propylene oxide, which process comprises subjecting the waste water to a catalytic wet oxidation treatment in the presence of said catalyst.

Method for reducing pollutant discharge in phenol and acetone production

A method for reducing pollutant discharge in phenol acetone production, comprising at least one of the following steps: (A) collecting phenolic wastewater generated by a phenol-acetone plant, adjusting the pH value to acidic, and performing extraction and recovery on the phenols in wastewater using cumene as an extracting agent; (B) reducing the acetone content in the wastewater from a column bottom by means of optimizing the process of an acetone refining column; (C) treating the wastewater from the column bottom of the acetone refining column by using a permselective membrane, and recovering alkali; (D) neutralizing the wastewater obtained from step (C), mixing the neutralized wastewater with a condensation liquid at the top of a cumene oxidation column, and carrying out a detoxification treatment; (E) carrying out an oil separation treatment on total discharged wastewater from the phenol-acetone plant, and recovering organic matters comprising hydrocarbons; and (F) carrying out a biological treatment, a coagulation sedimentation treatment and a reinforced degradation treatment on the wastewater after undergoing the oil separation treatment. The method has at least one of characteristics of being capable of recovering resources, increasing product yield, reducing pollutant discharge, having low cost in wastewater treatment, and having stable quality for water output.

METHOD AND DEVICE FOR TREATING ACROLEIN REACTOR WASTEWATER
20210107815 · 2021-04-15 ·

A method for treating acrolein reactor wastewater, comprising the steps of: S1. mixing acrolein reactor wastewater and a carbonate aqueous solution to obtain a mixed solution, wherein the acrolein reactor wastewater has a pH value of less than 2 and contains 500 ppm to 3,000 ppm of acrolein, 50 ppm to 800 ppm of allyl alcohol, 40,000 ppm to 100,000 ppm of acrylic acid, 10,000 ppm to 30,000 ppm of formaldehyde, 3,000 ppm to 10,000 ppm of acetic acid and 3,000 ppm to 8,000 ppm of maleic acid; and the mixed solution has a pH value of 4 to 6, a COD concentration ranging from 7,500 ppm to 30,000 ppm, and a formaldehyde concentration ranging from 800 ppm to 4,000 ppm; S2. conveying the mixed solution obtained in step S1 to an anaerobic reactor (4) for biochemical treatment; and S3. conveying the solution treated in step S2 to an aerobic biochemical tank (5) for treatment; and reflowing at least one part of the solution treated in step S2 and/or S3 to step S2. Also provided is a device for treating acrolein reactor wastewater.

Destruction of PFAS in the Presence of Silica
20210139354 · 2021-05-13 ·

We have discovered that heating PFAS in the presence of silica resulted in destruction of over 90% of PFAS under surprisingly mild conditions. Experimental results are presented showing that the reaction occurs along with etching of the silica glass, presumably caused by HF created during the reaction or in previous reactions. The methods of destroying PFAS are especially effective for treating relatively concentrated solutions such as those commonly encountered in AFFF waste stock and cleanup near fire-fighting training sites, as well as concentrated waste solutions from industrial sites involving the manufacture or application of PFAS.

PROCESS AND SYSTEM FOR SUBCRITICAL OXIDATION OF WATER-BORNE ORGANIC CONTAMINANTS
20210053852 · 2021-02-25 ·

A highly efficient and effective process for destroying organic contaminants in wastewater streams, without the need for supercritical oxidation conditions, is provided.

Modified bacterium useful for producing an organic molecule

The present invention provides for a genetically modified host cell or bacterium capable of producing an organic molecule, wherein the bacterium is capable of using hydrogen sulfide as an electron donor, carbon dioxide (CO.sub.2) as a carbon source, and/or nitrate as an electron acceptor. The present invention is useful in the wastewater treatment industry, in particular in municipal wastewater treatment plants (WWTP).

Process using ion exchange resins for the treatment of wastewater emanating from purified terephthalic acid production

A method for recovering water from purified terephthalic acid production wastewater includes: producing purified terephthalic acid comprising purified terephthalic acid feedstock and wastewater comprising impurities; separating the purified terephthalic acid feedstock from the wastewater comprising impurities; transferring the wastewater to a tank; adjusting the p H of the wastewater with a basic solution; adjusting the temperature of the wastewater; passing the wastewater to a column; contacting the wastewater with an ion exchange resin to remove the impurities; and recovering the water depleted of impurities.

PROCESS FOR RECOVERING AMIDE COMPOUNDS
20210039963 · 2021-02-11 ·

There is provided a method for efficiently recovering amide-based compounds such as N-methyl-2-pyrrolidone from a waste liquid containing amide-based compounds such as N-methyl-2-pyrrolidone generated, for example, in a production process of polyarylene sulfide.

Demulsification compound for oil separation from waste streams

A method for producing an additive for reclaiming oil from a fluid product stream and a treated silica with controlled hydrophobicity are disclosed. The method includes the steps of providing silica or silicate with a particle size of between 3.0 m to 20 m, the silica or silicates having an agglomerate size of between 10 m to 100 m and being chosen to achieve the desired particle-size range and with a controlled level of hydrophobicity; treating the silica or silicate with a silicone or silane to make it hydrophobic; and controlling the hydrophobicity of the silica or silicate by varying the temperature and treatment time of the silica or silicate, amount of a treating material used to treat the silica or silicate, and the molecular weight of the treating material. The additive improves oil extraction and concentration from a fluid product stream.