A method of removing chemical contaminants from a composition comprising an active, a solvent, and a contaminant can include providing an initial feed supply, wherein the initial feed supply comprises the active, the solvent, and the contaminant, wherein the contaminant can include 1,4 dioxane, dimethyl dioxane, or a combination thereof; including filtering the initial feed stock through a nanofilter and using reverse osmosis.

The invention is about a stabilized electromagnetic base liquid, as well as its preparation method and its application in the high-salt wastewater treatment. The raw material components of the electromagnetic base fluid include: 20-30 parts of alkali metal hydroxides(e.g., as sodium hydroxide); 20-30 parts of non-alkali metal (e.g., as silicon or phosphorus); 2-6 parts of ammonia; 31-140 parts of water; after treatment with a direct electrical current the parameters of the stabilized electromagnetic base liquid are: pH value: 12 to 14; oxidation reduction potential value: −1.0 to −1.8 v; with no corrosivity, confirming the presence of stabilized hydrated electrons (e.sub.aq−−). With the stabilized electromagnetic base liquid, the storage problem of the electromagnetic base liquid is solved, and the large-scale application in the industrial field can be realized, thereby achieving a large-scale high-salt wastewater treatment process with low cost, high recovery rate.

A contaminant-sequestering coating includes a network of hydrolyzed silane compounds. The hydrolyzed silane compounds include a hydrophilic polar head region, a hydrophobic linker, and an anchor region including a silicon atom. The network of hydrolyzed silane compounds is devoid or substantially devoid of fluorine atoms. Methods of destroying one or more perfluoroalkyl and/or polyfluoroalkyl (PFAS) compounds present in a contaminant-containing liquid are also provided.

Provided are a system for monitoring a hydroxyl radical scavenging index in water using a real-time multi-fluorescence analyzer and a parallel factor analysis apparatus and a method therefor, wherein the system monitors the hydroxyl radical scavenging index in water using the real-time multi-fluorescence analyzer and the parallel factor analysis apparatus, whereby it is possible to monitor the characteristics of an organic material in target water through a continuous flow analysis method without using an existing indicator material, rhodamine B. In addition, in a water treatment system having an advanced oxidation process (AOP) applied thereto in which ozone, ultraviolet rays, hydrogen peroxide, and the like are combined, it is possible to simply calculate the hydroxyl radical scavenging index in the target water through an organic material characteristic index for each component obtained by classifying the characteristic structure of the organic material in water using real-time fluorescence analysis by means of a parallel factor (PARAFAC) model. Accordingly, the amount of chemical injection and the amount of ultraviolet irradiation, which are process control variables, can be controlled, and under given operating variable conditions, the removal rate of a target material in water is predicted, whereby the system can also be used as a diagnostic tool for process evaluation in the advanced oxidation process. Furthermore, the system can provide operational convenience that enables process control while reducing the amount of power consumed in the advanced oxidation process even though the type of target material and the water quality characteristics of raw water change.

A system for generation of radicals in a liquid (e.g., OH and derivatively H.sub.2O.sub.2 in water) by a plasma reactor, including a first electrode having a rod shape or a tubular shape; a dielectric tubular housing coaxial with the first electrode and enclosing the first electrode, and having a gap to the first electrode of 0.3-30 mm; a second electrode on an outside of the dielectric tubular housing and coaxial with first electrode with a gap 0.3-30 mm; a high voltage power supply providing voltage oscillations or pulses of 0.5-30 kV and a frequency 1-50 kHz between the first and second electrodes; and a pump or a Venturi injector on an output of the plasma reactor and a chock valve on an input of reactor for generating a low water pressure in the gap between first and second electrodes so as to generate boiling in the gap.

A reactor system for decomposing at least one of a per- or polyfluoroalkyl substance (PFAS) is provided. The system includes a material having an interior surface that defines a compartment; a subaqueous liquid in the compartment; and an electron donor in the subaqueous liquid, the electron donor configured to release a hydrated electron upon ultraviolet (UV) irradiation. The reactor system is configured so that when the electron donor releases a hydrated electron into the subaqueous liquid, the hydrated electron has a longer lifespan relative to an electron released in normal bulk phase water, and when a PFAS is present within the subaqueous liquid, the hydrated electron is capable of reductively defluorinating the PFAS and to generate fluoride ions (F). A method of operating the system to decompose PFAS is also provided.

An oil-contaminated soil and groundwater treatment system, in which the polluted groundwater pumped into the electrocatalytic device uses a high-voltage electric field to change the structure of water molecules. After high voltage discharge, electrocatalysis and electrolysis, alkaline reduced water, acidic oxidized water and neutral water can be quickly produced. By the oxidation effect of electrocatalytic device anode, chloride ions and dissolved oxygen in water generate hypochlorous acid and superoxide ions, and the interaction between the two generates hydroxyl radicals and microbubbles with high oxidizing ability and long-lasting oxidation, thereby effectively remediating soil and groundwater polluted by total petroleum hydrocarbons.

A water treatment apparatus includes: a plurality of plate-shaped ground electrodes; a high-voltage electrode unit having counter electrode portions opposing the ground electrodes, support portions supporting the counter electrode portions, and a voltage receiving portion for receiving a high voltage; a water supply unit for supplying to-be-treated water to between the ground electrodes from above, insulating members each having a lower end portion fixed to a support structure fixing lower end portions of the ground electrodes, and an upper end portion connected to the voltage receiving portion of the high-voltage electrode unit. The lower ends of the support portions of the high-voltage electrode unit are held in a space between the ground electrodes, and a portion where each insulating member and the high-voltage electrode unit are connected to each other is located above the water supply unit, so that electric leak due to the to-be-treated water is inhibited.

Disclosed is a method for degrading antibiotics by aqueous phase transfer catalysis using an anionic liquid and hydrogen peroxide, including: adding hydrogen peroxide to a wastewater containing the antibiotics to obtain a first mixture, and adjusting a pH of the first mixture to 3-4 to form an aqueous phase, and adding a catalyst to a water-insoluble ionic liquid to obtain a second mixture, and stirring the second mixture to form an ionic liquid phase, wherein the catalyst is selected from the group consisting of ferrocene, iron dodecyl sulfonate, ferrous dodecyl sulfonate, and copper dodecyl sulfonate; and mixing the aqueous phase and the ionic liquid phase in a volume ratio of (8-11):1 to obtain a mixed phase, and stirring the mixed phase to degrade the antibiotics.

A water treatment device includes: an electrode structure installed in a storage space in which water is stored or in a flow space in which water flows so as to cause an underwater plasma discharge; and a gas supply module for supplying a gas to the storage space or the flow space such that bubbles are supplied underwater, as a discharge gas, to the electrode structure, wherein the electrode structure includes: a first electrode; a second electrode disposed opposite the first electrode; and a dielectric member disposed in a space between the first electrode and the second electrode.