A hollow spherical glass particle, comprising aluminum oxide Al.sub.2O.sub.3, silicon dioxide SiO.sub.2 and at least one metal oxide, wherein the metal oxide is selected from the group consisting of alkali metal oxides and alkaline earth metal oxides, wherein the ratio of aluminum atoms to alkali metal atoms is about 1:1 and the ratio of aluminum atoms to earth alkali atoms is about 2:1, with the proviso that the hollow spherical glass particle is free of boron.

The disclosure provides a process for making hollow inorganic particles comprising: providing a recyclable template particle in an aqueous dispersion, wherein the recyclable template particle is prepared from an organic monomer; coating the recyclable template particle with a solvent based silica precursor; maintaining the pH at about 7 to about 10 to form core/shell particles comprising a silica treatment on the recyclable template particle; removing the core/shell particles; and removing the recyclable template particle from the core/shell particles to form a hollow silica particle.